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A kind of wood high-efficiency permeable silicone waterproofing agent and preparation method thereof

A silicone cross-linking agent and penetrating technology, which is applied in the field of wood high-efficiency permeable silicone waterproofing agent and its preparation, can solve the problems of high price, large environmental impact, and small chemical bond energy, and achieve long-term waterproof protection and penetrating power Strong and hydrophobic effect

Active Publication Date: 2018-02-06
HANGZHOU RUIJIANG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Wood waterproofing agents have been developed in the United States and other countries for nearly 60 years. Although my country has a long history of using tung oil to treat wood for waterproofing in ancient times, the use of more effective waterproofing agents for wood waterproofing is still in its infancy.
At present, the waterproofing agents used for wood on the market include paraffin wax emulsion, methyl silicate waterproofing agent, fluorine-based waterproofing agent, etc., but there are certain shortcomings, such as paraffin wax emulsion, due to the small chemical bond energy, the overall waterproof performance and durability poor performance; methyl silicate waterproofing agents such as potassium methyl silicate with strong alkalinity will affect the appearance of wood after use; and fluorine waterproofing agents (fluorine silicon, fluorocarbon) not only have a great impact on the environment during the production process, but also Poor permeability and very expensive

Method used

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  • A kind of wood high-efficiency permeable silicone waterproofing agent and preparation method thereof
  • A kind of wood high-efficiency permeable silicone waterproofing agent and preparation method thereof
  • A kind of wood high-efficiency permeable silicone waterproofing agent and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0028] A high-efficiency penetrating silicone waterproofing agent for wood, prepared from the following raw materials: 30% silicone resin prepolymer, 40% mixture of hydroxyl silicone oil and dimethyl silicone oil, 5% silicone crosslinking agent, long-chain alkyl silane 10%, organic silicon quaternary ammonium salt 2%, pH adjustment organic solution 1%, additives 10%, nano filler 2%, the silicone resin prepolymer is propyl and octyl silicone resin copolymer, propyl silicone resin The mass ratio to the octyl silicone resin is 2:1, and the percentages are all mass percentages. The mixture of hydroxy silicone oil and dimethyl silicone oil is formed by mixing hydroxy silicone oil with a viscosity of 50,000 and dimethyl silicone oil with a viscosity of 60,000 in a mass ratio of 4:1. The organosilicon crosslinking agent is ethyl orthosilicate. The long-chain alkylsilane is dodecyltriethoxysilane. The organosilicon quaternary ammonium salt is diethoxymethylsilylpropyloctadecyldimeth...

Embodiment 2

[0033] A high-efficiency penetrating silicone waterproofing agent for wood, prepared from the following raw materials: 40% silicone resin prepolymer, 35% mixture of hydroxyl silicone oil and dimethyl silicone oil, 10% silicone crosslinking agent, long-chain alkyl silane 5%, organic silicon quaternary ammonium salt 1%, pH adjustment organic solution 2%, additives 2%, nano filler 5%; the silicone resin prepolymer is propyl and octyl silicone resin copolymer, propyl silicone resin The mass ratio to the octyl silicone resin is 2:1, and the percentages are all mass percentages. The mixture of hydroxy silicone oil and dimethyl silicone oil is formed by mixing hydroxy silicone oil with a viscosity of 50,000 and dimethyl silicone oil with a viscosity of 60,000 in a mass ratio of 4:1. The organosilicon crosslinking agent is ethyl orthosilicate. The long-chain alkylsilane is dodecyltriethoxysilane. The organosilicon quaternary ammonium salt is diethoxymethylsilylpropyloctadecyldimethy...

Embodiment 3

[0038] A high-efficiency penetrating silicone waterproofing agent for wood, prepared from the following raw materials: 33% silicone resin prepolymer, 37% mixture of hydroxyl silicone oil and dimethyl silicone oil, 8% silicone crosslinking agent, long-chain alkyl silane 7%, organic silicon quaternary ammonium salt 1.5%, pH adjustment organic solution 1.5%, additives 8%, nano filler 4%; the silicone resin prepolymer is propyl and octyl silicone resin copolymer, propyl silicone resin The mass ratio to the octyl silicone resin is 2:1, and the percentages are all mass percentages. The mixture of hydroxy silicone oil and dimethyl silicone oil is formed by mixing hydroxy silicone oil with a viscosity of 50,000 and dimethyl silicone oil with a viscosity of 60,000 in a mass ratio of 4:1. The organosilicon crosslinking agent is ethyl orthosilicate. The long-chain alkylsilane is dodecyltriethoxysilane. The organosilicon quaternary ammonium salt is diethoxymethylsilylpropyloctadecyldime...

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Abstract

The invention relates to a high-efficiency permeable type organosilicon waterproofing agent for wood and a preparation method thereof, which is characterized in that: it is prepared from the following raw materials: 30-40% of silicone resin prepolymer, 35-40% of a mixture of hydroxy silicone oil and dimethyl silicone oil %, organosilicon crosslinking agent 5~10%, long chain alkyl silane 5~10%, organosilicon quaternary ammonium salt 1~2%, pH adjusting organic solution 1~2%, auxiliary agent 2~10%, nanofiller 2-5%; the silicone resin prepolymer is a propyl and octyl silicone resin copolymer, and the percentages are all mass percentages. The high-efficiency penetrating type organosilicon waterproofing agent for wood of the invention has the advantages of non-toxicity, non-polluting, non-corrosiveness, does not change the original appearance of wood, and has the advantages of low price and the like. Applying the waterproofing agent of the present invention to the surface of wood can provide long-term waterproof protection to the wood.

Description

technical field [0001] The invention relates to the technical field of wood waterproofing, in particular to a wood highly permeable silicone waterproofing agent and a preparation method thereof. Background technique [0002] Wood waterproofing agents have been developed in the United States and other countries for nearly 60 years. Although my country has a long history of using tung oil to treat wood for waterproofing in ancient times, the use of more effective waterproofing agents for wood waterproofing is still in its infancy. At present, the waterproofing agents used for wood on the market include paraffin wax emulsion, methyl silicate waterproofing agent, fluorine-based waterproofing agent, etc., but there are certain shortcomings, such as paraffin wax emulsion, due to the small chemical bond energy, the overall waterproof performance and durability poor performance; methyl silicate waterproofing agents such as potassium methyl silicate with strong alkalinity will affect...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/42C04B103/65
Inventor 余钢左伟超
Owner HANGZHOU RUIJIANG CHEM
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