Adhesives and Adhesive Sheets
An adhesive, polymer technology, applied in the direction of adhesive types, ester copolymer adhesives, adhesives, etc., can solve problems such as part peeling, and achieve excellent processability, low dielectric constant, and high adhesion. Effect
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Embodiment 1
[0142] [Manufacture of (meth)acrylic polymer]
[0143] 147 parts by mass of ethyl acetate and 0.05 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) were added to a reaction apparatus equipped with a stirrer, a reflux condenser, a sequential dropping device, and a thermometer. Next, 210 parts by mass of 2-ethylhexyl methacrylate (2EHMA) (35% by mass relative to the total structural units), 330 parts by mass of 2-ethylhexyl acrylate (2EHA) (relative to the total constituent units) were prepared in another container. 600 mass parts of a monomer mixture composed of 55% by mass of the total structural unit), 60 mass parts of 2 hydroxyethyl acrylate (2HEA) (10 mass % relative to the total structural unit), 150 mass parts of which are added to the reaction Heat in the apparatus and reflux at reflux temperature for 20 minutes. Next, under reflux temperature conditions, the remaining 450 parts by mass of the monomer mixture, 33 parts by mass of ethyl acetate and 0.03 parts by m...
Embodiment 2~ Embodiment 9、 comparative example 1~ comparative example 8
[0186] Regarding Example 2 to Example 9 and Comparative Example 1 to Comparative Example 8, as shown in Table 1 and Table 2, the composition of the (meth)acrylic polymer in the adhesive was changed. 1 Similarly, the production of (meth)acrylic polymer, the preparation of adhesive, and the preparation of test samples were carried out, and the relative dielectric constant, processability, and adhesion of the adhesive layer in the test samples were evaluated. Strength and heat and humidity whitening resistance. The results are shown in Table 1 or Table 2.
[0187] [Table 1]
[0188]
[0189] [Table 2]
[0190]
[0191] In addition, the abbreviations shown in Table 1 and Table 2 are as follows.
[0192] 2EHMA: 2-ethylhexyl methacrylate (alkyl methacrylate having a branched alkyl group having 8 carbon atoms)
[0193] 2EHA: 2-ethylhexyl acrylate (alkyl acrylate having a branched alkyl group having 8 carbon atoms)
[0194] ・iBMA: Isobutyl methacrylate (alkyl methacrylate h...
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