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Combination method of catalytic diesel hydroconversion and catalytic gasoline selective hydrogenation

A technology for catalyzing gasoline and hydroconversion, applied in hydrotreating process, petroleum industry, processing hydrocarbon oil, etc., to achieve the effect of reducing hydrogen consumption, reducing carbon deposition and prolonging operation period

Active Publication Date: 2017-08-22
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the existing problems in the production process of high-octane gasoline, the present invention provides a combined method of catalytic diesel hydrogenation conversion and catalytic gasoline selective hydrogenation to improve the production process of high-octane gasoline

Method used

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  • Combination method of catalytic diesel hydroconversion and catalytic gasoline selective hydrogenation
  • Combination method of catalytic diesel hydroconversion and catalytic gasoline selective hydrogenation
  • Combination method of catalytic diesel hydroconversion and catalytic gasoline selective hydrogenation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-3

[0040] Embodiment 1-3 adopts flow process of the present invention as figure 1 .

[0041] In the present invention, the pretreatment catalyst used in the partial refining section of catalytic diesel hydroconversion is FF-36 hydrogenation pretreatment catalyst widely used in this field. The non-noble metal catalyst generally exists in an oxidized state before use, and needs to be presulfurized so that the non-noble metal oxide can be converted into a sulfide to be reactive. Therefore, non-noble metal catalysts should remain in a sulfurized state during use. The bulk phase method catalyst that adopts in embodiment 1-3 is the FTX catalyst of industrial application, and cracking agent is the cracking catalyst that adopts conventional method to prepare, and in embodiment 1-3, carry out gradient mixing filling to hydrocracking reactor, in the reactor A total of 3 mixed catalyst beds with the same packing volume are included. According to the order of contact with the reaction mate...

Embodiment 4

[0043] use figure 2 process shown. Feedstock oil, and catalyst used are the same as embodiment 3. Wherein a gas extraction pipeline is set between the second and third cracking catalyst beds, and the others are the same as in Embodiment 3. The amount of gas phase material drawn from the gas phase extraction pipeline is 30% of the amount of circulating hydrogen.

[0044] The process conditions and results of the examples are listed in Table 3 and Table 4 respectively.

[0045] Table 1 Composition and main properties of the cracking catalyst of the example.

[0046]

[0047] Table 2 Raw oil properties.

[0048]

[0049] Table 3 Operating conditions used in Examples 1-4.

[0050]

[0051] Table 4 Evaluation results of Examples 1-4.

[0052] Example 1 Example 2 Example 3 Example 4 Catalytic Diesel Hydroconversion Section Product distribution, wt% Naphtha fraction fraction ( 39 38 52 54 Diesel Distillate (>21...

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Abstract

The invention discloses a combination method of catalytic cracking diesel oil hydrogenation conversion and catalytic gasoline hydrogenation. Catalytic cracked diesel oil mixed with hydrogen enters the hydrogenation pretreatment reactor for hydrofining reaction; the refined effluent directly enters the cracking reactor, and contacts with the catalyst bed layer loaded in the cracking reactor; the cracking reactor is equipped with at least For the two hydrocracking catalyst beds, according to the flow direction of the reaction materials, the hydrogenation activity of the hydrocracking catalyst beds tends to decrease. The hydrocracking effluent enters the hot fraction for separation, and the liquid phase part is decompressed and mixed with catalytic cracking gasoline and new hydrogen, and directly enters the gasoline hydrogenation reactor without heating for hydrodesulfurization reaction. The method of the invention avoids further cracking of the cracked naphtha, increases the selectivity of the naphtha, improves the octane number of the gasoline, and simultaneously increases the yield of liquid products of hydrocracking.

Description

technical field [0001] The invention relates to a hydrocarbon hydrogenation treatment method, in particular to a combined method of catalytic diesel hydrogenation conversion and catalytic gasoline selective hydrogenation. Background technique [0002] Since the beginning of the new century, with the increasing awareness of environmental protection, the stricter national environmental protection regulations and the rapid development of the national economy, the demand for clean motor fuels has been increasing all over the world. Catalytic cracking (FCC) technology is one of the main technological means for lightening heavy oil, and it occupies a relatively important position in oil refining enterprises all over the world. The annual processing capacity of catalytic cracking units in my country has exceeded 100 million tons, second only to the United States. In the composition of gasoline and diesel products, catalytic cracking gasoline accounts for about 80%, and catalytic d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/00
Inventor 柳伟杜艳泽王凤来秦波张晓萍曹均峰
Owner CHINA PETROLEUM & CHEM CORP
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