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Pressure swing catalytic method and device for catalytic oxidation reaction

A catalytic oxidation and catalytic device technology, applied in chemical instruments and methods, pressure vessels used in chemical processes, chemical/physical processes, etc., can solve problems such as limiting the scope of catalytic oxidation technology, unfavorable safety hazards, and limited heating methods , to achieve the effects of small footprint, reduced cost and space, and small equipment volume

Active Publication Date: 2018-06-08
BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional heating methods inevitably use large-volume, high-energy-consuming heating equipment, especially in industrial catalytic applications, and electric heating limits the scope of application of catalytic oxidation technology to a certain extent, such as the petroleum industry, flammable and explosive spaces, etc. , is not conducive to the safety hazards caused by electric heating
In addition, the existing catalytic oxidation technology is limited to the heating method, and does not act on the reaction atmosphere in other ways to promote the reaction.

Method used

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  • Pressure swing catalytic method and device for catalytic oxidation reaction
  • Pressure swing catalytic method and device for catalytic oxidation reaction
  • Pressure swing catalytic method and device for catalytic oxidation reaction

Examples

Experimental program
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Effect test

Embodiment 1

[0024] A kind of pressure swing catalytic method for catalytic oxidation reaction, reference figure 2 , including: increasing the pressure of the reaction atmosphere in the reaction chamber at the beginning of the catalytic oxidation reaction, generating heat, and promoting the reaction; reacting for a period of time, reducing pressure instantaneously, and completely reacting the remaining reactants under the action of the remaining heat; After several cycles, the reactants are completely oxidized and gas is emitted.

[0025] The pressure of the reaction atmosphere is set according to the heat required for catalytic oxidation, ranging from 1 to 20 atmospheres, generally preferably 1 to 5 atmospheres, and the reaction time is related to the heat generated and the concentration of reactants, generally preferably 1 to 60 minutes.

[0026] Here, the pressure of the reaction atmosphere, the period of time of reaction and the number of cycles can be determined by those skilled in t...

Embodiment 2

[0028] Such as figure 2 As shown, a pressure swing catalytic device for catalytic oxidation reaction implements the method described in Embodiment 1, which specifically includes a pressure swing catalytic oxidation reaction chamber externally connected with an air inlet 6 and an air outlet 7 . The variable pressure catalytic oxidation reaction chamber has a built-in catalyst layer 8; the variable pressure catalytic oxidation reaction chamber changes the pressure in the variable pressure catalytic oxidation reaction chamber through variable pressure control, and opens the inlet 6 valve and closes the gas outlet 7 valve during operation. Adjust the variable pressure to increase the pressure so that the reactants and the participating reaction atmosphere enter the variable pressure catalytic oxidation reaction chamber in large quantities, generate heat, promote the reaction and close the 6 valves of the air inlet; The reactant reacts completely under the action of the remaining ...

Embodiment 3

[0033] Such as figure 2 As shown, a pressure swing catalytic device for catalytic oxidation reaction implements the method described in Embodiment 1, which specifically includes a pressure swing catalytic oxidation reaction chamber externally connected with an air inlet 6 and an air outlet 7 . The variable pressure catalytic oxidation reaction chamber has a built-in catalyst layer 8; the variable pressure catalytic oxidation reaction chamber changes the pressure in the variable pressure catalytic oxidation reaction chamber through variable pressure control, and opens the inlet 6 valve and closes the gas outlet 7 valve during operation. Adjust the variable pressure to increase the pressure so that the reactants and the participating reaction atmosphere enter the variable pressure catalytic oxidation reaction chamber in large quantities, generate heat, promote the reaction and close the 6 valves of the air inlet; The reactant reacts completely under the action of the remaining ...

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PUM

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Abstract

The invention discloses a pressure-variable catalyzing method and device for a catalytic oxidation reaction. The method comprises the steps that the reaction atmosphere pressure in a reaction chamber is increased when the catalytic oxidation reaction starts, and heat is generated to promote the reaction; after the reaction is conducted for a period of time, the pressure is instantaneously decreased, and the residual reactants thoroughly react under the action of the remaining heat; through several cycles of pressure-variable operation, the reactants are thoroughly oxidized, and gas is exhausted. The specific device comprises the pressure-variable catalytic oxidation reaction chamber, a catalyst layer (8) arranged in the pressure-variable catalytic oxidation reaction chamber, an external gas inlet (6) and a gas outlet (7). According to the method and device, a pressure-variable catalyzing technique is adopted, the equipment size is small, the occupied space is small, and the cost and space for transforming and upgrading an old technology are conveniently reduced; the heating effect is generated and the molecular properties are changed through pressure variation, therefore, the catalytic reaction is conveniently conducted, and the heat utilization rate is high; direct electric heating is not adopted in the technique, therefore, the safety problem is avoided, and the applicability is higher.

Description

technical field [0001] This patent relates to the technical field of chemical machinery structure, in particular to a pressure swing catalytic method and device for catalytic oxidation reaction. Background technique [0002] For gas-phase catalytic oxidation reactions, such as figure 1 As shown, the principle is that the reactant uses the surface of the catalyst as the medium for the gas-solid phase oxidation reaction, and burns flamelessly under heating conditions, and oxidizes and decomposes the organic compound into a harmless product CO 2 and H2O. At present, heating is an indispensable condition, and resistance furnaces or electric heating jackets are usually used. In addition, electrocatalysis requires direct power supply. [0003] In the prior art, heating has always been an indispensable condition for gas-phase catalytic oxidation, which can provide the required energy for the reaction. So far, the means used for heating are generally heating holding furnaces or h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/02B01J3/04
CPCB01J3/04B01J8/02B01J8/025B01J2208/00539
Inventor 王亚飞刘铭陈世豪崔想安冉尹成艳
Owner BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY