A device and method for electromagnetic ultraviolet collaborative treatment of organic wastewater

A technology of organic wastewater and collaborative treatment, applied in chemical instruments and methods, magnetic/electric field water/sewage treatment, water/sewage treatment, etc., can solve the problem of failure to reach the optimal working temperature of the magnetic excitation electrodeless ultraviolet lamp and the reduction of photoelectric conversion efficiency , Microwave magnetron short life and other problems, to achieve the effect of compact reactor structure, improved photoelectric conversion efficiency, and high photoelectric conversion efficiency

Active Publication Date: 2019-06-14
SUZHOU ZHANQING ENVIRONMENT PROTECTION TECHCO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the microwave electrodeless ultraviolet lamp is used for wastewater treatment, there are two major problems: the first is that the microwave magnetron used to excite ultraviolet light has a very short life span, only 2000-3000 hours, so the entire reaction system still needs to be replaced continuously. The cost increases; the second is that most of the microwaves used to excite ultraviolet rays are directly absorbed by the waste water to generate heat, which greatly reduces the photoelectric conversion efficiency
[0008] 1) Only use ultraviolet light for oxidation. In addition to the direct decomposition of ultraviolet light during the reaction process, it is also oxidized by catalyzing dissolved oxygen to generate ozone. However, the oxidation efficiency of these two types of oxidation methods is lower than that of hydroxyl radicals, so it is only applicable to For the treatment of low-concentration organic wastewater;
[0009] 2) The reaction is carried out at normal temperature, which does not reach the optimal working temperature of the magnetically excited electrodeless ultraviolet lamp, so the oxidation efficiency is low;
[0010] 3) The structural material of the reactor is plexiglass, which will be damaged due to ultraviolet radiation and oxidation after long-term use;
[0011] 4) Sequencing batch static structure is adopted, the surface of the lamp tube is easy to scale during use, resulting in a decrease in UV transmittance, which further leads to a decrease in oxidation efficiency

Method used

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  • A device and method for electromagnetic ultraviolet collaborative treatment of organic wastewater
  • A device and method for electromagnetic ultraviolet collaborative treatment of organic wastewater
  • A device and method for electromagnetic ultraviolet collaborative treatment of organic wastewater

Examples

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Embodiment 1

[0046] 300W rectangular magnetically excited electrodeless ultraviolet lamp and stainless steel sealed reactor are used to treat 20 liters of high-concentration dyeing wastewater with a COD concentration of 4500mg / L. During the reaction, adjust the pH of the wastewater to 3-6 and maintain the temperature at 40-50 ℃, add 27.5% hydrogen peroxide in total 200ml, after 2 hours of circulation reaction, COD is treated to 250mg / L, and the removal rate reaches 95%.

Embodiment 2

[0048] A 100W annular magnetically excited electrodeless ultraviolet lamp is used, glass is used as the reactor shell, and polytetrafluoroethylene is used for the sealing part, which is used to treat 10 liters of electroless nickel plating waste liquid with a COD concentration of 70000mg / L. During the reaction process, the pH of the waste water is adjusted to 4 Between -5, keep the temperature at 60-80°C, add 27.5% hydrogen peroxide for a total of 2 liters, after 3 hours of circulation reaction, COD is reduced to 3000mg / L, and the removal rate is 95%.

Embodiment 3

[0050] Two 500W rectangular magnetically excited electrodeless ultraviolet lamps are used, respectively placed in stainless steel sealed reactors, and the two reactors are connected in parallel to treat 200L electroplating zinc-nickel alloy wastewater. During the reaction, adjust the pH to 10-11 and maintain the temperature At 30-40°C, add a total of 2 liters of 10% sodium hypochlorite solution, and after 4 hours of circular reaction, the COD is reduced from 2600 mg / L to less than 100 mg / L, and the removal rate is 96%.

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Abstract

An electromagnetism and ultraviolet ray cooperated organic wastewater treatment device comprises a reaction tank with a heating tube, wherein pretreated wastewater is fed into the reaction tank, a pH probe and a temperature probe are arranged in the reaction tank, the reaction tank is connected with an electromagnetism and ultraviolet ray cooperated reactor through a water pump and a pipeline so that the wastewater is circulated between the reaction tank and the electromagnetism and ultraviolet ray cooperated reactor, an oxidizing agent storage tank is connected to the pipeline through a dosing pump. The invention further provides an electromagnetism and ultraviolet ray cooperated organic wastewater treatment method. The device is high in photoelectric conversion efficiency and oxidation efficiency and long in service life, the replacement times are few, and the maintenance cost and operating cost are low.

Description

technical field [0001] The invention belongs to the technical field of waste water treatment in the environmental protection industry, and in particular relates to a device and method for electromagnetic ultraviolet cooperative treatment of organic waste water. Background technique [0002] Advanced oxidation technology is a type of wastewater treatment technology that produces hydroxyl radicals (OH) with strong oxidation ability under high temperature, high pressure, electricity, sound, light, catalyst and other reaction conditions to oxidize organic matter. With the advantages of non-selectivity and complete oxidation, it has been more and more widely researched and applied in the field of high-concentration organic wastewater treatment. [0003] Ultraviolet light oxidation, which uses ultraviolet light as the basic reaction condition, has the advantages of mild reaction conditions and strong oxidation ability, so it has become one of the most rapidly developing advanced o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/72C02F1/74C02F1/76C02F1/78C02F1/32C02F1/48C02F101/30
CPCC02F1/32C02F1/48C02F1/722C02F1/74C02F1/76C02F1/763C02F1/78C02F2101/30C02F2201/3227C02F2201/483C02F2209/02C02F2209/06
Inventor 王磊李星桥叶小兵
Owner SUZHOU ZHANQING ENVIRONMENT PROTECTION TECHCO LTD
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