Preparation method of cuprous sulfide/carboxylated chitosan/glass fiber composite conductive fiber
A technology of carboxylated chitosan and glass fiber, which is applied in the chemical characteristics of fibers, conjugated rayon, textiles and papermaking, etc., can solve the problems of inability to obtain conductive properties, low adsorption fastness, and excellent conductive fibers, etc. Achieve the effect of less loss of fiber properties, reliable quality and simple operation
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Embodiment 1
[0016] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, its steps are as follows:
[0017] (1) Immerse 10 grams of cleaned alkali-free glass fiber into 200 grams of hydrochloric acid aqueous solution with a concentration of 1mol / L, soak for 0.5 hour at 50° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fiber;
[0018] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution of 0.5% in mass concentration, soaks 3 hours at 30 ℃, after immersion finishes taking out, immerse mass concentration is the glutaraldehyde of 0.05% Solution, soaked at 30°C for 2 hours, fully rinsed with water after taking out, dried to obtain carboxylated chitosan surface-modified glass fibers;
[0019] (3) the carboxylated chitosan surface-modified glass fiber prepared by step (2) is placed in 150 grams of mass concentration in the copper sulfate pentahydrate aque...
Embodiment 2
[0021] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, the steps are as follows:
[0022] (1) Immerse 10 grams of cleaned alkali-free glass fibers into 150 grams of hydrochloric acid aqueous solution with a concentration of 2 mol / L, soak for 2 hours at 20° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fibers;
[0023] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution that mass concentration is 2%, soaks 1 hour at 30 ℃, after immersion finishes taking out, immerse mass concentration is 1% glutaraldehyde Solution, soaked at 50°C for 0.5 hour, fully rinsed with water after taking out, dried to obtain glass fiber with carboxylated chitosan surface modification;
[0024] (3) the carboxylated chitosan surface modification glass fiber prepared by step (2) is placed in 5% copper sulfate pentahydrate aqueous solution with a mass concent...
Embodiment 3
[0026] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, the steps are as follows:
[0027] (1) Immerse 10 grams of cleaned alkali-free glass fibers into 150 grams of hydrochloric acid aqueous solution with a concentration of 3 mol / L, soak for 1 hour at 30° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fibers;
[0028] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution that mass concentration is 1%, soaks 1 hour at 50 ℃, after soaking completes taking out, immersion mass concentration is the glutaraldehyde of 0.06% Solution, soaked at 40°C for 1 hour, fully rinsed with water after taking out, dried to obtain carboxylated chitosan surface-modified glass fibers;
[0029] (3) the carboxylated chitosan surface-modified glass fiber prepared by step (2) is placed in 150 grams of mass concentration in the copper sulfate pentahydrate aque...
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