Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of cuprous sulfide/carboxylated chitosan/glass fiber composite conductive fiber

A technology of carboxylated chitosan and glass fiber, which is applied in the chemical characteristics of fibers, conjugated rayon, textiles and papermaking, etc., can solve the problems of inability to obtain conductive properties, low adsorption fastness, and excellent conductive fibers, etc. Achieve the effect of less loss of fiber properties, reliable quality and simple operation

Inactive Publication Date: 2017-11-24
ZHONGYUAN ENGINEERING COLLEGE
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, which solves the problem that the fiber has low adsorption fastness to metal sulfur compounds in the prior art and cannot obtain conductive fibers. Problems with Conductive Fibers with Excellent Properties

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, its steps are as follows:

[0017] (1) Immerse 10 grams of cleaned alkali-free glass fiber into 200 grams of hydrochloric acid aqueous solution with a concentration of 1mol / L, soak for 0.5 hour at 50° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fiber;

[0018] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution of 0.5% in mass concentration, soaks 3 hours at 30 ℃, after immersion finishes taking out, immerse mass concentration is the glutaraldehyde of 0.05% Solution, soaked at 30°C for 2 hours, fully rinsed with water after taking out, dried to obtain carboxylated chitosan surface-modified glass fibers;

[0019] (3) the carboxylated chitosan surface-modified glass fiber prepared by step (2) is placed in 150 grams of mass concentration in the copper sulfate pentahydrate aque...

Embodiment 2

[0021] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, the steps are as follows:

[0022] (1) Immerse 10 grams of cleaned alkali-free glass fibers into 150 grams of hydrochloric acid aqueous solution with a concentration of 2 mol / L, soak for 2 hours at 20° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fibers;

[0023] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution that mass concentration is 2%, soaks 1 hour at 30 ℃, after immersion finishes taking out, immerse mass concentration is 1% glutaraldehyde Solution, soaked at 50°C for 0.5 hour, fully rinsed with water after taking out, dried to obtain glass fiber with carboxylated chitosan surface modification;

[0024] (3) the carboxylated chitosan surface modification glass fiber prepared by step (2) is placed in 5% copper sulfate pentahydrate aqueous solution with a mass concent...

Embodiment 3

[0026] The preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fiber, the steps are as follows:

[0027] (1) Immerse 10 grams of cleaned alkali-free glass fibers into 150 grams of hydrochloric acid aqueous solution with a concentration of 3 mol / L, soak for 1 hour at 30° C., after soaking, fully rinse with water and dry to obtain hydroxylated glass fibers;

[0028] (2) the hydroxylated glass fiber that step (1) obtains is immersed in the carboxylated chitosan aqueous solution that mass concentration is 1%, soaks 1 hour at 50 ℃, after soaking completes taking out, immersion mass concentration is the glutaraldehyde of 0.06% Solution, soaked at 40°C for 1 hour, fully rinsed with water after taking out, dried to obtain carboxylated chitosan surface-modified glass fibers;

[0029] (3) the carboxylated chitosan surface-modified glass fiber prepared by step (2) is placed in 150 grams of mass concentration in the copper sulfate pentahydrate aque...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides a preparation method of cuprous sulfide / carboxylation chitosan / glass fiber composite conductive fiber. An alkali-free glass fiber is immersed in an aqueous hydrochloric acid solution, and is sufficiently rinsed with water and dried to obtain a hydroxylated glass fiber after soaking; the hydroxylated glass fiber is immersed in a carboxylation chitosan aqueous solution, and then is taken out after soaking and the taken hydroxylated glass fiber is immersed into a glutaraldehyde solution, is taken out and is sufficiently rinsed with water and dried to obtain carboxylation chitosan surface modified glass fiber; the carboxylation chitosan surface modified glass fiber is put into a copper sulfate pentahydrate aqueous solution, and is added into a sodium thiosulfate aqueous solution after soaking, then the soaked carboxylation chitosan surface modified glass fiber is taken out and rinsed with water and dried after reaction to obtain the cuprous sulfide / carboxylation chitosan / glass fiber composite conductive fiber. The process is used for preparing the conductive glass fiber, the equipment investment expense is low, the operation is simple, the reaction condition is mild, the applicability is strong, the treatment effect is good, the fiber performance loss is low, the fiber quality is reliable, the environment pollution is alleviated and the method is suitable for industrial production.

Description

technical field [0001] The invention relates to the field of preparation of composite conductive fibers, in particular to a preparation method of cuprous sulfide / carboxylated chitosan / glass fiber composite conductive fibers. Background technique [0002] In recent years, with the rapid development and popularization of computers, telecommunications, microwave ovens, etc., the electromagnetic radiation in the living and working environment of human beings has become increasingly serious. The resulting electromagnetic wave interference has brought many negative effects to the normal operation of electronic equipment and human physical health. influences. In order to prevent electrostatic interference and electromagnetic wave interference, various antistatic and electromagnetic shielding materials have been developed since the middle of the 20th century. In recent decades, the focus of research has shifted more to conductive fibers. The antistatic effect of conductive fibers i...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/18C03C25/00C03C25/66C03C25/42
CPCC03C25/00C03C25/42C03C25/66D01F8/18
Inventor 郭正潘玮张一风高艳菲
Owner ZHONGYUAN ENGINEERING COLLEGE
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products