A kind of preparation method of semiconductive polyolefin slurry

A polyolefin slurry and semi-conductive technology, which is applied in the direction of power cables, circuits, and power cables with shielding layers/conductive layers, can solve the problems of reducing the conductivity of materials, polluting materials, and reducing the surface smoothness of material products. Avoid agglomeration, enhance dispersion, and ensure the effect of dispersion

Active Publication Date: 2019-02-22
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During this process, the wind will bring dust particles in the air into the material system, pollute the material, and seriously affect the smoothness of the surface of the material product; the particle size of the conductive carbon black used exceeds 100nm, and the carbon black filler of this particle size not only reduces the The electrical conductivity of the material, but also greatly reduces the surface smoothness of the material product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The preparation method of semiconductive polyolefin slurry in the present embodiment is carried out according to the following steps:

[0029] All raw materials in the examples were subjected to -0.09MPa high negative pressure dust removal treatment before opening the package for use, and all steps were implemented in an ultra-clean environment with a cleanliness level of 100.

[0030] (1) Under a liquid nitrogen environment, ethylene-vinyl acetate (vinyl acetate content is 18%) polymer is frozen for 2 hours, pulverized and ground into fine particles, then screened and refined with a 300-mesh standard sieve, and dried. Gather spares.

[0031] (2) Vacuum-dry the superconducting carbon black at 120°C for 24 hours, grind it with a ball mill for 30 minutes, and then sieve it with a 300-mesh standard sieve. Take 3Kg of superconducting carbon black after screening and add it to 27Kg of micropores with a pore size of 0.2 μm. In the isopropanol solvent after membrane purificat...

Embodiment 2

[0035] The preparation method of semiconductive polyolefin slurry in the present embodiment is carried out according to the following steps:

[0036] All raw materials in the examples were subjected to -0.09MPa high negative pressure dust removal treatment before opening the package for use, and all steps were carried out in an ultra-clean environment with a cleanliness level of 100.

[0037] (1) In a liquid nitrogen environment, the ethylene-ethyl acrylate (16% ethyl acrylate content) polymer was frozen for 2 hours, crushed and ground into fine particles, then sieved and refined with a 300-mesh standard sieve, and dried. Gather spares.

[0038] (2) Superconducting carbon black and carbon nanotubes were vacuum-dried at 120°C for 24 hours, ground for 30 minutes with a ball mill, and then screened with a 300-mesh standard sieve, and 2.5Kg of superconducting carbon black and carbon nanotubes after screening were taken respectively. Tube 0.5Kg, add 12Kg of isopropanol solvent pur...

Embodiment 3

[0042] The preparation method of semiconductive polyolefin slurry in the present embodiment is carried out according to the following steps:

[0043] All raw materials in the examples were subjected to -0.09MPa high negative pressure dust removal treatment before opening the package for use, and all steps were carried out in an ultra-clean environment with a cleanliness level of 100.

[0044] (1) Under a liquid nitrogen environment, the ethylene-butyl acrylate (butyl acrylate content is 27%) polymer was frozen for 2 hours, crushed and ground into fine particles, then sieved and refined with a 300-mesh standard sieve, and dried. Gather spares.

[0045](2) Superconducting carbon black and graphene sheets were vacuum-dried at 120° C. for 24 hours respectively, ground for 30 minutes with a ball mill, and then screened with a 300-mesh standard sieve to get superconducting carbon black 2.5Kg and graphene sheets after screening. Add 0.5Kg to 7Kg ​​of isopropanol solvent purified and...

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Abstract

The invention relates to a preparation method of semiconductive polyolefin slurry. The preparation method comprises preparing polyolefin particles in a liquid nitrogen environment, preparing a conductive filler dispersion liquid through an ultrasonic method and mixing the polyolefin particles and the conductive filler dispersion liquid according to a ratio to obtain the semiconductive polyolefin slurry. The semiconductive polyolefin slurry has the advantages of full dispersity of a conductive filler, improves conductive filler dispersibility in later production and improves cable shield material surface smoothness.

Description

technical field [0001] The invention relates to a preparation method of a semiconductive polyolefin slurry, in particular to a preparation method of a polyolefin slurry which can be used to prepare an ultra-smooth high-voltage semiconductive shielding material. Background technique [0002] The use practice of medium-voltage to extra-high-voltage cables shows that ultra-smooth semi-conductive shielding materials play an extremely important role in the successful and stable operation of power cables. At present, the market of semi-conductive shielding materials with a voltage level of 110KV and above is mainly occupied by foreign companies such as Borealis and Dow Chemical. There are a large number of domestic literature and patent research reports on semi-conductive shielding materials, but so far most manufacturers of cable shielding materials can only produce Shielding material for 35kV and below XLPE cables. The performance requirements of semi-conductive shielding mater...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C08L23/08C08K3/04C08K7/24H01B9/02
CPCC08K3/04C08K7/24C08K2201/001C08K2201/011C08K2201/014C08L2205/025H01B9/027C08L23/0853C08L23/0869
Inventor杨青兰逢涛何州文刘辉陈新
OwnerSTATE GRID CORP OF CHINA