Consumer product compositions
A technology for consumer products, compositions for cleaning and/or bleaching surfaces
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[0332] Examples of photoactivators
[0333] The following are non-limiting examples of various water-soluble organic photoactivators of the present invention and their synthesis.
[0334] 9-Oxo-9H-thioxanthene-2-carboxylic acid chloride
[0335] A dry 500 mL 1-neck recovery flask containing 13.25 g of 9-oxo-9H-thioxanthene-2-carboxylic acid and a magnetic stir bar was equipped with a dry condenser connected to a Firestone valve (where the bubbler outlet was passed through the water to capture the released HCl). After adding 250 mL of thionyl chloride, the system was vacuum / nitrogen cycled 5 times and held under positive nitrogen pressure (suspended solids). After 5 hours at reflux, the thionyl chloride was removed under vacuum at 60°C using a rotary evaporator. The residual solid on the walls of the flask was scraped off and crushed, and placed under vacuum (0.3 mmHg) at room temperature overnight. The vacuum was broken while argon was introduced and the solids were cr...
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