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A kind of method that prepares fuel by water hyacinth

A technology of water hyacinth and fuel, which is applied in the field of preparing fuel from water hyacinth, can solve the problems of not effectively using water hyacinth, inhibiting the growth of plankton, destroying the ecological environment of rivers, etc., and is suitable for large-scale promotion and additional The effect of high value and short process

Active Publication Date: 2018-06-26
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. Block waterways, affect shipping and excretion, and become the number one enemy of agriculture, water conservancy and environmental protection
[0004] 2. Restricting the flow of the water body, the water body is not exposed to sunlight and becomes stinky, which reduces the dissolved oxygen in the water body, inhibits the growth of plankton, and destroys the ecological environment of the river.
[0006] 4. Destruction of drinking water resources
[0007] 5. Water hyacinth covers the water surface and increases the evaporation of water, which is 8-10 times higher than that of open water surface, resulting in loss of water source
A large number of water hyacinths covering the water surface will reduce the PH value of the water; the concentration of CO2 will increase; the odor concentration and chroma of the water will increase; the acidity of the water will also increase, which will greatly reduce the use value of water resources until it is undrinkable
[0009] 7. The outbreak of water hyacinth and its decay stage will consume a large amount of dissolved oxygen in the water body at the same time, and underwater animals such as fish will have less activity and reproduction space, and even a large number of fish will die
[0010] At present, there are many ways to prevent the water hyacinth from flooding, mainly in the following categories: one is chemical control, which requires the addition of chemical reagents, which will destroy the ecological balance at the same time; the other is biological control, which maintains water hyacinth by introducing natural enemies The number of lotus, but the effect is slow, at least 3-5 years; the third is artificial and mechanical control methods, through manual or mechanical salvage treatment of water hyacinth, quick effect, but when the occurrence area is large, the labor intensity is high
In fact, these methods do not effectively use water hyacinth, but only limit its quantity. At most, water hyacinth is used as fertilizer or waste, and there is no technology related to the use of its bioenergy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Adopt co-precipitation method to prepare copper-zinc-aluminum catalyst, concrete method is: according to molar ratio, copper nitrate: aluminum nitrate: zinc nitrate: the ratio of sodium carbonate=68:9:23:15 will 200ml copper nitrate (0.69mol), 200ml nitric acid Add aluminum (0.09mol), 200ml zinc nitrate (0.23mol), 300ml sodium carbonate (0.15mol) into 200ml deionized water, stir vigorously at 60°C, maintain pH = 6-7, react for two hours, filter at 100 Dry at -120°C, and then calcinate in air at 600°C for 5 hours to finally obtain a copper-zinc-aluminum catalyst.

Embodiment 2

[0039] 1. Extract cellulose from water hyacinth:

[0040] 1. Mix toluene and ethanol solution (volume ratio 2:1), and keep the sample in the solution for 2.5 hours at 110 degrees Celsius.

[0041] 2. It is then treated with a 3% sodium hypochlorite solution, and kept at 80° C. for 2 hours.

[0042] 3. After treatment with a 1% sodium hydroxide solution, keep the temperature at 65° C. for 2 hours.

[0043] 4. After treatment with a 1% sodium hypochlorite solution, keep warm at 75° C. for 3 hours and stir.

[0044] 5. After treatment with hydrochloric acid with a mass concentration of 5%, keep it at 70°C for 6 hours.

[0045] 6. Filter, wash with distilled water, and dry to obtain cellulose.

[0046] 2. Hydrogenolysis process: Add 0.75g of cellulose, 0.5g of the catalyst prepared in Example 1, 50mL of methanol into a 100mL reactor, fill with nitrogen, keep warm at 320°C for 0.5-1H, and stir at 400rpm. After cooling to room temperature, the gaseous product was collected with ...

Embodiment 3

[0048] 1. Extract cellulose from water hyacinth:

[0049] 1. Mix toluene and ethanol solution (volume ratio 2:1), and keep the sample in the solution for 2.5 hours at 105 degrees Celsius.

[0050] 2. After treatment with a 3% sodium hypochlorite solution, keep the temperature at 75°C for 2 hours.

[0051] 3. After treatment with a 1% sodium hydroxide solution, keep the temperature at 60° C. for 2 hours.

[0052] 4. After treatment with a 1% sodium hypochlorite solution with a mass concentration, keep warm at 70° C. for 3 hours and stir.

[0053] 5. After treatment with hydrochloric acid with a mass concentration of 4%, keep it at 70°C for 6 hours.

[0054] 6. Filter, wash with distilled water, dry, and use Deo cellulose.

[0055] 2. Hydrogenolysis process: add 0.5g of cellulose, 0.5g of the catalyst prepared in Example 1, 30mL of methanol into a 100mL reactor, fill it with nitrogen, heat at 320°C for 0.5-1H, and stir at 400rpm. After cooling to room temperature, the gaseou...

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PUM

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Abstract

The invention relates to a method for preparing a fuel from eichhornia crassipes (mart.) solms. The method comprises: crushing eichhornia crassipes (mart.) solms into powder, drying until the water is completely lost, extracting the eichhornia crassipes (mart.) solms powder sequentially with a toluene-ethanol mixing solution, a high concentration sodium hypochlorite solution, a sodium hydroxide solution, a low concentration sodium hypochlorite solution and a hydrochloric acid solution to obtain cellulose, preparing an oxidized alloy catalyst, introducing a protection gas into a reactor kettle, and carrying out a hydrogenolysis reaction on the obtained cellulose and methanol under the effect of the oxidized alloy catalyst to obtain the fuel. Compared to the method of the present invention, the method of the present invention has the following characteristics that the cellulose is obtained from the eichhornia crassipes (mart.) solms by using the chemical treatment method, the oxidized alloy catalyst is prepared through self-preparation, and the obtained cellulose and the methanol are subjected to the hydrogenolysis reaction under the effect of the oxidized alloy catalyst, wherein the cellulose is prepared into the gas-state and liquid-state fuel, and the characteristic that the eichhornia crassipes (mart.) solms is adopted as the biological energy source is utilized; and the method has advantages of simple preparation, short process and high added value, and is suitable for large-scale popularization.

Description

technical field [0001] The invention belongs to the technical field of bioenergy, and in particular relates to a method for preparing fuel from hyacinth hyacinth. Background technique [0002] Water hyacinth, commonly known as water hyacinth, is a floating herb with well-developed fibrous roots. The flooding of water hyacinth will cause the following hazards: [0003] 1. Block waterways, affect shipping and excretion, and become the number one enemy of agriculture, water conservancy and environmental protection. [0004] 2. The flow of the water body is restricted, and the water body becomes stinky without sunlight, which reduces the dissolved oxygen in the water body, inhibits the growth of plankton, and destroys the ecological environment of the river. [0005] 3. It provides a breeding ground for germs such as schistosomiasis and encephalitis influenza, breeds mosquitoes and flies, and provides opportunities for mosquito larvae to breathe and reproduce. [0006] 4. Des...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G1/00C10J3/00C10J3/82
CPCC10G1/002C10J3/00C10J3/82C10J2300/092C10J2300/0986C10L2230/04C10L2290/22C10L2290/28C10L2290/544
Inventor 谈正中张禹诚顾若冰
Owner TONGJI UNIV