A kind of method that prepares fuel by water hyacinth
A technology of water hyacinth and fuel, which is applied in the field of preparing fuel from water hyacinth, can solve the problems of not effectively using water hyacinth, inhibiting the growth of plankton, destroying the ecological environment of rivers, etc., and is suitable for large-scale promotion and additional The effect of high value and short process
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Embodiment 1
[0037] Adopt co-precipitation method to prepare copper-zinc-aluminum catalyst, concrete method is: according to molar ratio, copper nitrate: aluminum nitrate: zinc nitrate: the ratio of sodium carbonate=68:9:23:15 will 200ml copper nitrate (0.69mol), 200ml nitric acid Add aluminum (0.09mol), 200ml zinc nitrate (0.23mol), 300ml sodium carbonate (0.15mol) into 200ml deionized water, stir vigorously at 60°C, maintain pH = 6-7, react for two hours, filter at 100 Dry at -120°C, and then calcinate in air at 600°C for 5 hours to finally obtain a copper-zinc-aluminum catalyst.
Embodiment 2
[0039] 1. Extract cellulose from water hyacinth:
[0040] 1. Mix toluene and ethanol solution (volume ratio 2:1), and keep the sample in the solution for 2.5 hours at 110 degrees Celsius.
[0041] 2. It is then treated with a 3% sodium hypochlorite solution, and kept at 80° C. for 2 hours.
[0042] 3. After treatment with a 1% sodium hydroxide solution, keep the temperature at 65° C. for 2 hours.
[0043] 4. After treatment with a 1% sodium hypochlorite solution, keep warm at 75° C. for 3 hours and stir.
[0044] 5. After treatment with hydrochloric acid with a mass concentration of 5%, keep it at 70°C for 6 hours.
[0045] 6. Filter, wash with distilled water, and dry to obtain cellulose.
[0046] 2. Hydrogenolysis process: Add 0.75g of cellulose, 0.5g of the catalyst prepared in Example 1, 50mL of methanol into a 100mL reactor, fill with nitrogen, keep warm at 320°C for 0.5-1H, and stir at 400rpm. After cooling to room temperature, the gaseous product was collected with ...
Embodiment 3
[0048] 1. Extract cellulose from water hyacinth:
[0049] 1. Mix toluene and ethanol solution (volume ratio 2:1), and keep the sample in the solution for 2.5 hours at 105 degrees Celsius.
[0050] 2. After treatment with a 3% sodium hypochlorite solution, keep the temperature at 75°C for 2 hours.
[0051] 3. After treatment with a 1% sodium hydroxide solution, keep the temperature at 60° C. for 2 hours.
[0052] 4. After treatment with a 1% sodium hypochlorite solution with a mass concentration, keep warm at 70° C. for 3 hours and stir.
[0053] 5. After treatment with hydrochloric acid with a mass concentration of 4%, keep it at 70°C for 6 hours.
[0054] 6. Filter, wash with distilled water, dry, and use Deo cellulose.
[0055] 2. Hydrogenolysis process: add 0.5g of cellulose, 0.5g of the catalyst prepared in Example 1, 30mL of methanol into a 100mL reactor, fill it with nitrogen, heat at 320°C for 0.5-1H, and stir at 400rpm. After cooling to room temperature, the gaseou...
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