PVC (Polyvinyl Chloride) modifying material for curtains and preparation method thereof

A modified material, PVC resin technology, applied in the field of PVC modified material for curtains and its preparation, can solve the problems of poor fluidity, easy discoloration, poor thermal stability, etc., to improve bending strength, bending modulus of elasticity and thermal deformation Temperature and dimensional stability, compatibility improvement, and stability improvement effect

Inactive Publication Date: 2017-07-25
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0003] However, the existing PVC materials for curtains have defects such as poor waterproof and anti-aging performance, and easy to change color, which limits its use to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] A PVC modified material for curtains, comprising the following raw materials in parts by weight:

[0060] High degree of polymerization PVC resin 80 parts

[0061] 45 parts plasticizer

[0062] 5 parts heavy calcium carbonate

[0063] Light calcium carbonate 10 parts

[0064] Stabilizer 2 parts

[0065] 1 part waterproofing agent

[0066] Modifier 0.5 parts

[0067] Anti-ultraviolet agent 0.6 parts

[0068] Antioxidant 0.3 parts

[0069] Anti-tarnish agent 0.3 parts

[0070] 0.4 parts of external lubricant.

[0071] The high degree of polymerization PVC resin is a SG-0 type PVC resin with a degree of polymerization of 1800; the plasticizer is composed of epoxy soybean oil, synthetic vegetable ester and cyclohexane 1,2-diisononyl dicarboxylate A mixture composed of a weight ratio of 1:0.8:1.

[0072] The heavy calcium carbonate has a particle size of 100nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size of 10n...

Embodiment 2

[0092] A PVC modified material for curtains, comprising the following raw materials in parts by weight:

[0093] High degree of polymerization PVC resin 90 parts

[0094] Plasticizer 50 parts

[0095] 8 parts of heavy calcium carbonate

[0096] Light calcium carbonate 11 parts

[0097] Stabilizer 2.5 parts

[0098] Waterproofing agent 1.5 parts

[0099] Modifier 0.8 parts

[0100] Anti-ultraviolet agent 0.7 parts

[0101] Antioxidant 0.4 parts

[0102] Anti-tarnish agent 0.4 parts

[0103] 0.5 parts of external lubricant.

[0104] The high degree of polymerization PVC resin is a SG-0 type PVC resin with a degree of polymerization of 1850; the plasticizer is made of epoxy soybean oil, synthetic vegetable ester and cyclohexane 1,2-diisononyl dicarboxylate A mixture composed of a weight ratio of 1.2:0.9:1.

[0105] The heavy calcium carbonate has a particle size of 200nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size ...

Embodiment 3

[0125] A PVC modified material for curtains, comprising the following raw materials in parts by weight:

[0126] High degree of polymerization PVC resin 100 parts

[0127] Plasticizer 55 parts

[0128] 10 parts of heavy calcium carbonate

[0129] Light calcium carbonate 12 parts

[0130] Stabilizer 3 parts

[0131] Waterproofing agent 2 parts

[0132] Modifier 1 part

[0133] Anti-ultraviolet agent 0.8 parts

[0134] Antioxidant 0.5 part

[0135] Anti-tarnish agent 0.5 parts

[0136] 0.6 parts of external lubricant.

[0137] The high degree of polymerization PVC resin is a SG-0 type PVC resin with a degree of polymerization of 1900; the plasticizer is composed of epoxy soybean oil, synthetic vegetable ester and cyclohexane 1,2-diisononyl dicarboxylate A mixture composed in a weight ratio of 1.5:1:1.

[0138] The heavy calcium carbonate has a particle size of 300nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size of 5...

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Abstract

The invention relates to the technical field of PVC (Polyvinyl Chloride) materials, in particular to a PVC (Polyvinyl Chloride) modifying material for curtains and a preparation method thereof. The PVC modifying material for the curtain is prepared from the following raw materials in parts by weight: 80 to 120 parts of high-polymerization-degree PVC resin, 45 to 65 parts of plasticizer, 5 to 15 parts of ground calcium carbonate, 10 to 15 parts of light calcium carbonate, 2 to 4 parts of stabilizer, 1 to 3 parts of water-proofing agent, 0.5 to 1.5 parts of modifying agent, 0.6 to 1.0 part of anti-ultraviolet agent, 0.3 to 0.7 part of antioxidant, 0.3 to 0.7 part of anti-blushing agent and 0.4 to 0.8 part of outer lubricant. The PVC modifying material for curtains disclosed by the invention has the advantages of good water-proofing and anti-aging effects, environmental friendliness, excellent temperature resistance and weather resistance, high strength, excellent impact resistance, good flame retarding effect, excellent machining performance and superior comprehensive performance.

Description

technical field [0001] The invention relates to the technical field of PVC materials, in particular to a PVC modified material for curtains and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardancy, corrosion resistance, excellent comprehensive performance, low price and wide source of raw materials; but also There are the following disadvantages: 1. The toughness is poor, and it is easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of general PVC products is -15°C. The lower limit of use of PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C, and the melting tempera...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/00C08K13/06C08K9/04C08K9/06C08K3/26C08K5/098B29B9/06B29C47/92B29C48/92
CPCC08L27/06B29B9/06B29C48/92B29C2948/92704C08K2201/003C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L2205/025C08L2205/035C08L91/00C08K13/06C08K9/04C08K9/06C08K2003/265C08K5/098
Inventor 宁建华
Owner 广东祺龙科技有限公司
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