Heat-resistant crack-resistant organic glass and preparation method thereof

A plexiglass and heat-resistant technology, which is applied in the field of heat-resistant and crack-resistant plexiglass and its preparation, can solve problems affecting the use of plexiglass, poor mechanical properties, and poor heat resistance, so as to prevent uneven shrinkage and improve Radiation protection, heat resistance, good compatibility

CN107057254AInactive Publication Date: 2017-08-18蚌埠承永玻璃制品有限公司
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2017-08-18
Estimated Expiration
Not applicable · inactive patent
Patent Text Reader

Abstract

The invention discloses heat-resistant crack-resistant organic glass and a preparation method thereof; the heat-resistant crack-resistant organic glass comprises, by weight, methyl methacrylate, polycyclic norbornene methacrylate, butanediol diacrylate, epoxidized soybean oil acrylate, an impact modifier, 1-dodecanethiol, polyacrylamide, rubber particles, poly(butyl acrylate), nylon terpolymer, rare earth, azobisisobutyronitrile, dicumyl peroxide, diisobutyl phthalate, and ethyl 4-hydroxybenzoate. The heat-resistant crack-resistant organic glass and the preparation method thereof are provided herein; the organic glass has high glass transition temperature, good heat resistance and good mechanical properties, rarely cracks and has good economic benefit.
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Description

technical field

[0001] The invention relates to the technical field of glass, in particular to a heat-resistant and crack-resistant organic glass and a preparation method thereof. Background technique

[0002] Polymethyl methacrylate, commonly known as plexiglass, has excellent optical properties, weather resistance and chemical corrosion resistance, good electrical insulation and biocompatibility, easy to process and shape, high mechanical strength silicate inorganic glass, widely used in aviation , navigation, architecture and everyday life. The current plexiglass still has brittle texture, poor mechanical properties, poor heat resistance, and is prone to cracking during production and use, and these all seriously affect the use of plexiglass. Contents of the invention

[0003] Based on the technical problems existing in the background technology, the present invention proposes a heat-resistant and crack-resistant organic glass and its preparation method. The organic gl...

Examples

Embodiment 1

[0015] A heat-resistant and anti-crack organic glass proposed by the present invention, its raw materials include by weight: 120 parts of methyl methacrylate, 15 parts of polycyclic norbornyl methacrylate, 7 parts of butanediol dipropylene, epoxy 9 parts of soybean oil acrylate, 6 parts of impact modifier, 4 parts of dodecanethiol, 3 parts of polyacrylamide, 12 parts of rubber particles, 1 part of polybutyl acrylate, 6 parts of ternary copolymerized nylon, 1.5 parts of rare earth , 0.9 parts of azobisisobutyronitrile, 0.2 parts of dicumyl peroxide, 4 parts of diisobutyl phthalate, and 1 part of ethyl p-hydroxybenzoate.

[0016] A method for preparing heat-resistant and crack-resistant plexiglass proposed by the present invention is prepared according to the following process: methyl methacrylate, azobisisobutyronitrile, dicumyl peroxide, and polycyclic norbornene methacrylate Ester, butanediol dipropylene ester, and epoxy soybean oil acrylate were mixed evenly, stirred and rea...

Embodiment 2

[0018] A heat-resistant and anti-crack organic glass proposed by the present invention, its raw materials include by weight: 150 parts of methyl methacrylate, 10 parts of polycyclic norbornyl methacrylate, 12 parts of butanediol dipropylene ester, epoxy 6 parts of soybean oil acrylate, 10 parts of impact modifier, 2 parts of dodecyl mercaptan, 5 parts of polyacrylamide, 8 parts of rubber particles, 2 parts of polybutyl acrylate, 4 parts of ternary copolymer nylon, 3 parts of rare earth , 0.4 parts of azobisisobutyronitrile, 0.7 parts of dicumyl peroxide, 2 parts of diisobutyl phthalate, and 3 parts of ethyl p-hydroxybenzoate.

[0019] A method for preparing heat-resistant and crack-resistant plexiglass proposed by the present invention is prepared according to the following process: methyl methacrylate, azobisisobutyronitrile, dicumyl peroxide, and polycyclic norbornene methacrylate Ester, butanediol dipropylene ester, and epoxy soybean oil acrylate were mixed evenly, stirred ...

Embodiment 3

[0021] A heat-resistant and anti-crack organic glass proposed by the present invention, its raw materials include by weight: 135 parts of methyl methacrylate, 12.5 parts of polycyclic norbornyl methacrylate, 9.5 parts of butanediol dipropylene ester, epoxy 7.2 parts of soybean oil acrylate, 8.4 parts of impact modifier, 3.2 parts of dodecyl mercaptan, 4 parts of polyacrylamide, 10 parts of rubber particles, 1.6 parts of polybutyl acrylate, 4.8 parts of ternary copolymer nylon, 2.3 parts of rare earth , 0.6 parts of azobisisobutyronitrile, 0.45 parts of dicumyl peroxide, 3.2 parts of diisobutyl phthalate, and 2.2 parts of ethyl p-hydroxybenzoate.

[0022] Wherein, the impact modifier is ABS impact modifier;

[0023] The particle size of the rubber particles is 10 μm;

[0024] The particle size of the rare earth is 80nm.

[0025] A method for preparing heat-resistant and crack-resistant plexiglass proposed by the present invention is prepared according to the following process...