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Preparation method of rare earth complex doped silica microsphere solution and modified solar cell

A technology of solar cells and silicon dioxide, applied in circuits, photovoltaic power generation, electrical components, etc., can solve problems such as low efficiency of solar cells

Active Publication Date: 2019-07-23
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The purpose of the present invention is to improve the low efficiency of solar cells, by spin-coating the rare earth complex doped silicon dioxide microsphere solution with fluorescent properties on the PET substrate of solar cells, utilizing the fluorescent properties of rare earth complexes and The characteristics of silicon dioxide to increase scattering increase the light absorption intensity of solar cells and improve the photoelectric conversion efficiency of solar cells

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  • Preparation method of rare earth complex doped silica microsphere solution and modified solar cell
  • Preparation method of rare earth complex doped silica microsphere solution and modified solar cell
  • Preparation method of rare earth complex doped silica microsphere solution and modified solar cell

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preparation example Construction

[0018] The preparation method of rare earth complex doped silica microsphere solution comprises the following steps:

[0019] (1) Two kinds of organic conjugated small molecules are used as the first ligand and the second ligand respectively, and the first ligand and the second ligand are mixed and reacted with the rare earth chloride solution to obtain the rare earth complex solution ;

[0020] (2) Add silicate ester dropwise to the rare earth complex solution to react to obtain a rare earth complex doped silica microsphere solution.

[0021] In step (1), the rare earth chloride solution is one of europium chloride solution, terbium chloride solution, thulium chloride solution and gadolinium chloride solution, preferably europium chloride solution, and europium chloride has excellent Luminescent properties, reflected in red light; the first ligand is 2-thienoyl trifluoroacetone, and the second ligand is 1-10 phenanthroline; the first ligand and the second ligand are typical ...

Embodiment 1

[0048] The preparation method of the rare earth complex doped silica microsphere solution of the present embodiment comprises the following steps:

[0049] (1) 2-thienoyltrifluoroacetone is used as the first ligand, 1-10 phenanthroline is used as the second ligand, the first ligand and the second ligand are mixed with europium chloride solution, europium chloride , 2-thiophenoyltrifluoroacetone, and 1-10 phenanthroline in a molar ratio of 1:3:1, and reacted at room temperature for 2 hours to obtain a rare earth complex solution;

[0050] Among them, the preparation process of europium chloride solution: a certain amount of europium oxide and excess hydrogen chloride aqueous solution are reacted for a period of time under the condition of stirring to make it fully dissolved, and the solution is moved to a 70°C oil bath to evaporate the excess solvent until the solvent Disappeared, the remaining reactants were crystals, dried to obtain EuCl 3 ∙ H 2 0, then the crystal is disso...

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Abstract

The invention discloses a preparation method of a rare earth complex doped silica microsphere solution and a modified solar cell. The preparation method of the rare earth complex doped silica microsphere solution comprises the following steps: (1) Two kinds of organic conjugated small molecules are used as the first ligand and the second ligand respectively, and the first ligand and the second ligand are mixed with the rare earth chloride solution to obtain the rare earth complex solution; (2) in the rare earth complex Silicate is added dropwise into the product solution for reaction to obtain a solution of rare earth complex doped silica microspheres. The preparation method of the modified solar cell comprises spin-coating the rare earth complex doped silica microsphere solution on the PET substrate of the solar cell to prepare a modified solar cell with the rare earth complex doped silica microsphere . Utilize the fluorescence characteristics of rare earth complexes and the characteristics of increased scattering of silicon dioxide to increase the light absorption intensity of solar cells and improve the photoelectric conversion efficiency of solar cells.

Description

technical field [0001] The invention relates to the cross field of hybrid material technology and solar cell preparation technology, in particular to a rare earth complex doped silicon dioxide microsphere solution and a preparation method of a modified solar cell. Background technique [0002] As a material with excellent and unique optical, electrical and magnetic properties, rare earth materials have very important application value. Its unique electronic layer structure is unmatched by general materials. The advantages of high fluorescence intensity and narrow luminescence range make rare earths have incomparable natural advantages in the field of luminescence. As a result, rare earth materials are widely used in the three major fields of lighting, display and detection. With the maturity of rare earth material technology, the scale of industrial production and consumption related to rare earth is growing. The research on the function and application technology of rare ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/48H01L51/42
CPCH10K71/12H10K85/10H10K30/50Y02E10/549Y02P70/50
Inventor 王薇李磊唐建国王瑶黄林军沈文飞刘继宪焦吉庆王彦欣王久兴杜中林王世超李国鹏李付霞
Owner QINGDAO UNIV
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