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Preparation method for three-dimensional porous composite material

A composite material, three-dimensional porous technology, applied in the direction of chemical instruments and methods, electrolytic coatings, carbon compounds, etc., can solve the problems of low conductivity, large internal resistance, poor strength, etc., to increase the specific surface area, eliminate contact resistance, The effect of improving electrical conductivity

Active Publication Date: 2018-11-23
TSINGHUA UNIV +1
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AI Technical Summary

Problems solved by technology

Although the nanoporous metal material unit has superior physical and chemical properties, the traditionally assembled macro-sized electrodes usually have a large internal resistance, which inhibits the high service performance of the nano-active material; and because the nanoporous metal composite material itself It is very brittle and does not have self-supporting properties, so that the obtained nanoporous metal composites still have problems of poor stability, low electrical conductivity and poor strength, which affect their applications

Method used

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  • Preparation method for three-dimensional porous composite material
  • Preparation method for three-dimensional porous composite material
  • Preparation method for three-dimensional porous composite material

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preparation example Construction

[0029] see image 3 , the present invention further provides a method for preparing the above-mentioned three-dimensional porous composite material, which mainly includes the following steps:

[0030] Step S10, providing a salt solution of an inert metal and a salt solution of an active metal;

[0031] The salt solution of the inert metal is used as the plating solution A for use, and the salt solution of the active metal is the plating solution B for use. The active metal can be any one of potassium, calcium, sodium, magnesium, aluminum, zinc, iron, tin and nickel. The inert metal can be any one of copper, mercury, silver, platinum and gold. Compared with the inert metal, the active metal is more likely to react with acid and alkali. Preferably, the salt solution of the inert metal is fully stirred with the glucose, so as to refine the subsequently formed inert metal coating. In this embodiment, the salt solution of the active metal is ZnSO 4 Solution, the salt solution ...

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Abstract

The invention relates to a preparation method for a three-dimensional porous composite material. The method comprises the following steps that an inert metal salt solution and an active metal salt solution are provided; a substrate is provided, the surface of the substrate is electroplated with the inert metal salt solution, and a coating film M is formed; a carbon nanotube structure is arranged on the surface of the coating film M; the surface of the carbon nanotube structure is electroplated with the active metal salt solution, a coating film N is formed, the substrate is peeled, and a composite structure is obtained; the composite structure is subjected to high temperature annealing, and an alloy is formed by active metal and inert metal in the composite structure, and a preform is obtained; and the preform is etched into a porous structure, and the three-dimensional porous composite material is obtained.

Description

technical field [0001] The invention relates to a method for preparing a three-dimensional porous composite material, in particular to a method for preparing a three-dimensional porous composite material based on carbon nanotubes. Background technique [0002] At present, due to the high specific surface area, specific modulus and other characteristics of nanoporous metal materials, as well as the high thermal conductivity and high electrical conductivity of metal materials, they are widely used in catalysis, energy storage and conversion, biosensing, molecular It has broad application prospects in the fields of detection, noise reduction and vibration absorption, shielding, heat exchange, and electrochemistry. [0003] However, in the application process, the existing technology generally combines nanoporous metal materials themselves with other structures to obtain nanoporous metal composite materials. For example, the traditional assembly method of electrodes in devices i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C26/00C22C1/08C25D5/10C23F1/44C25F3/02
CPCC22C1/08C22C26/00C23F1/44C25D5/10C25F3/02C22C2026/002C25D5/54C23F1/02C25D1/08C25D1/10C25D3/12C25D3/38C25D3/42C25D5/50C25D15/00C01B32/158C25D3/50B82Y40/00C01B2202/08C25D3/20C25D3/22C25D3/30C25D3/44C25D3/46C25D3/48C01B32/168B32B9/007B32B15/043C25D5/48C23F1/16B32B2305/026B32B2260/02
Inventor 付红颖李文珍
Owner TSINGHUA UNIV
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