Supporting sheet and composite sheet for protective film formation
A support sheet and protective film technology, applied in the direction of film/sheet adhesive, synthetic resin layered products, chemical instruments and methods, etc., can solve the problem that the adhesive layer is easy to vibrate and cannot obtain semiconductor wafers or semiconductor chips Check images, unclear printing and other problems to achieve the effect of inhibiting adhesion
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Embodiment 1
[0436] (Manufacture of thermosetting protective film-forming composition (III-1))
[0437] Polymer component (A)-1 (40 parts by mass), epoxy resin (B1)-1 (5 parts by mass), epoxy resin (B1)-2 (4 parts by mass), epoxy resin (B1)- 3 (10 parts by mass), thermosetting agent (B2)-1 (1 part by mass), curing accelerator (C)-1 (1 part by mass), filler (D)-1 (36 parts by mass), coupling Agent (E)-1 (1 part by mass) and colorant (I)-1 (2 parts by mass) were mixed, and then diluted with methyl ethyl ketone so that the concentration of the solid content reached 45 mass%, and a combination for forming a thermosetting protective film was obtained. substance (III-1). It should be noted that the compounding amounts of components other than methyl ethyl ketone shown here are all solid content amounts.
[0438] (Formation of film for protective film formation)
[0439] On the above-mentioned release-treated surface of a release film ("SP-PET381031" manufactured by Lintec Corporation, thickne...
Embodiment 2
[0448] In the formation of the adhesive layer, the application amount of the adhesive composition (I-4)-1 was changed to form a non-energy ray curable adhesive layer Ad2 with a thickness of 20 μm instead of 5 μm, and support was obtained. Sheet Ss2, and using the obtained support sheet Ss2, according to the method similar to Example 1, the composite sheet for protective film formation was manufactured.
[0449] That is, the protective film-forming composite sheet is laminated in the thickness direction of the substrate Bm1, the adhesive layer Ad2, the protective film-forming film Pf1, and the release film in the order of their thickness. The surface on one side of the agent layer Ad2 is a smooth surface, and the surface (exposed surface) on the opposite side to the side provided with the adhesive layer Ad2 of the base material Bm1 is an uneven surface. Table 1 shows the composition of the composite sheet for forming a protective film.
Embodiment 3
[0451] (manufacture of adhesive composition)
[0452] Adhesive resin (i)-2 (100 parts by mass) and toluene diisocyanate crosslinking agent ("BHS8515" manufactured by TOYOCHEM Co., Ltd.) (10 parts by mass) were mixed, and then diluted with methyl ethyl ketone so that the concentration of the solid content was 35 % by mass and a non-energy ray curable adhesive composition (I-4)-2 was obtained. It should be noted that the compounding amounts of components other than methyl ethyl ketone shown here are all solid content amounts.
[0453] (Formation of adhesive layer, production of support sheet)
[0454] Apply the adhesive composition (I-4)-2 obtained above on the smooth surface of the above-mentioned substrate Bm1 with a surface roughness of 0.05 μm, and dry at 100° C. for 1 minute to form a non-energy sheet with a thickness of 5 μm. The support sheet Ss3 was obtained from the line-curable adhesive layer Ad3.
[0455] (Manufacture of composite sheets for protective film formati...
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