Novel compound and organic electroluminescent divice including the same
A technology for organic light-emitting devices and compounds, applied in the field of novel compounds and organic light-emitting devices containing them, can solve the problems of high driving voltage, short life, low efficiency, etc., and achieve the effects of long life, recrystallization prevention, and high efficiency
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[0108] intermediate synthesis
[0109]
[0110] In order to synthesize the target compound, the intermediate IM was synthesized through the above reaction.
Synthetic example 1
[0111] Synthesis Example 1: Synthesis of Intermediate (IM1)
[0112]
[0113] In a round bottom flask, 8.5 g of (9,9-dimethyl-9H-fluoren-2-yl)boronic acid ((9,9-dimethyl-9H-fluoren-2-yl)boronic acid), 1-bromo -4-iodobenzene (1-bromo-4-iodobenzene) 10.0g dissolved in 1,4-dioxane (1,4-dioxan) 200ml, put into K 2 CO 3 (2M)50ml and Pd(PPh 3 ) 4 After 1.3 g, reflux stirring was performed. The reaction was confirmed by thin layer chromatography (TLC), and after adding water, the reaction was terminated. The organic layer was extracted with methylcellulose (MC), and filtered under reduced pressure, followed by column purification to obtain 8.27 g (yield 67%) of IM1-1.
[0114] In a round bottom flask, the above IM1-1 8.0g, aniline (aniline) 2.4g, t-BuONa3.3g, Pd 2 (dba) 3 0.85g, (t-Bu) 3 After 1.0 ml of P was dissolved in 110 ml of toluene, stirring was performed under reflux. The reaction was confirmed by thin layer chromatography (TLC), and after adding water, the re...
Embodiment 1
[0169] ultrasonication of distilled water The thickness of the glass substrate coated with indium tin oxide (ITO) as a thin film is washed. When the distilled water washing is completed, use a solvent such as isopropanol, acetone, methanol, etc. to perform ultrasonic cleaning, and after drying, transfer to a plasma cleaner, and then use oxygen plasma to clean the above-mentioned substrate for 5 minutes. The upper part of the substrate uses a thermal vacuum depositor (thermal evaporator) as a hole injection layer to HI01 for film production, the The HATCN film is used as a hole transport layer to BPA for film formation, as a luminescent auxiliary layer will After compound 1 was formed into a film, as the above-mentioned light-emitting layer doped with 3% of BH01:BD01, to Make a film. Next, as the electron transport layer will After the ET01:Liq (1:1) was used to make the film, the of LiF, Aluminum (Al) was used to form a film, and the device was sealed (Encap...
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