A kind of waste power battery environment-friendly recycling method

A power battery and waste technology, which is applied in the direction of battery recycling, recycling technology, waste collector recycling, etc., can solve the problems that cannot meet the urgent needs of waste power batteries, small scale, low efficiency, etc., and achieve a reliable recycling process , harm reduction, and high efficiency

A power battery and waste technology, which is applied in the direction of battery recycling, recycling technology, waste collector recycling, etc., can solve the problems that cannot meet the urgent needs of waste power batteries, small scale, low efficiency, etc., and achieve a reliable recycling process , harm reduction, and high efficiency

CN109244586BActive Publication Date: 2021-03-30BEIJING UNIV OF TECH

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  • A kind of waste power battery environment-friendly recycling method

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Embodiment 1

[0031] Such as figure 1 As shown, the process route of the environmentally friendly recovery and reuse method for waste power batteries in this embodiment includes the following steps:

[0032] a) Fully discharge the battery through safety pretreatment. The discharge device is a high-current charge-discharge instrument. First discharge to 2.5V at a discharge rate of 1C, and then discharge to 0.2V at a rate of 0.2C;

[0033] b) The discharged battery is placed in a nitrogen atmosphere in a sealed box, and the battery is cut along the 3mm below the top groove by the method of local liquid nitrogen spot spraying and cold cutting. Open the battery, take out the battery cell, and the battery terminal Collect directly with shell;

[0034] c) The battery cell taken out in step b) is placed in the DMC replacement solution and soaked for 0.5h under the protective atmosphere condition in the sealed box, so that the electrolyte in the battery cell is fully absorbed;

[0035] d) The cel...

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Abstract

A method for recycling and reusing waste power battery belongs to that field of recycling waste battery. The battery is completely discharged and placed under a sealed and protective gas atmosphere, and the battery pole head, the shell and the battery cell are collected by cold cutting; the obtained cell is immersed and cleaned in the replacement solution. And the positive electrode, the negativeelectrode and the diaphragm are separated by unwinding; The positive and negative electrode pieces are respectively soaked in distilled water and ultrasonicated to obtain positive and negative electrode materials, aluminum foil and copper foil; The electrolyte volatile in the process of cell disassembly is absorbed by absorption tower. Distillation, condensation, filtration and drying are used forrecycling of the replacement liquid used in the cell immersion process, and the harmful substances are recovered through a neutralization sedimentation tank and a tail gas absorption tank. The ultrasonic liquid is recycled after being precipitated by adding demulsifier, filtered and treated by biological contact oxidation. The invention realizes the recovery and regeneration of the waste lithiumion battery, the process is safe, harmless, the automation degree is high, the treatment is efficient and convenient, and the secondary pollution to the environment is not generated.

Description

technical field [0001] The invention belongs to the recycling process of waste batteries, and in particular relates to a safe, harmless and recyclable recovery process of waste power batteries and the regeneration and recovery treatment of various parts. Background technique [0002] Lithium-ion batteries have the advantages of high energy density, high voltage, long life, low self-discharge rate, no memory effect, good cycle performance and wide temperature range. The main power source for electronic equipment. According to statistics, the global production of lithium-ion batteries exceeded 580 million in 2000, and the domestic production was about 100 million. In 2003, the global production reached 1.255 billion. In 2008, the output reached 2.71 billion. In 2010, the global production exceeded 3 billion. . With the increasingly mature manufacturing technology of lithium-ion batteries, its use is becoming wider and wider, especially in recent years with the vigorous devel...

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Application Information

Patent Timeline
30 Mar 2021
Publication
CN109244586B
IPC
H01M10/54
CPC
H01M10/54; Y02W30/84
Inventors
赵煜娟; 肖湘