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Copper-vanadium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof

A technology of austenitic stainless steel and heat treatment method, which is applied in the field of austenitic stainless steel and can solve the problems of increased contact resistance and inability to meet the requirements of bipolar plate materials, etc.

Inactive Publication Date: 2019-02-19
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The passivation layer formed by 316L stainless steel without surface treatment in the fuel cell environment will lead to an increase in contact resistance, which cannot meet the requirements of bipolar plate materials

Method used

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  • Copper-vanadium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof
  • Copper-vanadium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof
  • Copper-vanadium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, 304 stainless steel scrap, pure copper block, pure cobalt sheet, metal vanadium as raw materials, and the stainless steel composition is as follows: C=0.03, Ni=9.0, Cr=19.0, V= 0.12, Cu=0.2, Co=0.1, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=surplus.

[0052] After weighing the corresponding raw materials according to the composition requirements, arc smelting with argon protection. The temperature of the molten pool is kept at 1720 °C during smelting; the molten steel is sedated for 10 minutes before pouring, and the molten steel is poured at 1600 °C under argon protection.

[0053] The plate is hot rolled by a flat roll mill. The hot rolling plan is to heat the cast slab to 1290°C, hold it for 5 hours, and roll it out of the furnace. The starting temperature of hot rolling is 1190°C and the final rolling temperature is 950°C. The total amount of hot rolling of the sheet is 60%.

[0054] The plate is def...

Embodiment 2

[0059] 304L stainless steel scrap, pure copper block, pure cobalt sheet, and ferrovanadium are selected as raw materials, and the stainless steel composition is as follows: C=0.014, Ni=10.0, Cr=20.0, V=0.25, Cu=0.3, Co=0.5, Mn= 1.2, Si=0.7, P≤0.035, S≤0.030, Fe=surplus.

[0060] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is kept at 1680 ℃ during smelting; the molten steel is sedated for 5 minutes before pouring, and the molten steel is vacuum poured at 1500 ℃.

[0061] The plate is hot rolled by a flat roll mill. The hot rolling plan is to heat the cast slab to 1270°C, hold it for 5 hours, and roll it out of the furnace. The starting temperature of hot rolling is 1160°C, and the final rolling temperature is 1000°C. The total reduction in hot rolling of the sheet is 65%.

[0062] The plate is deformed by cold rolling, and the total reduction of cold ro...

Embodiment 3

[0066]Select electrical pure iron, metal chromium sheet, metal nickel plate, pure copper block, pure cobalt sheet, vanadium iron, graphite block as raw materials, and the stainless steel composition is as follows: C=0.025, Ni=9.6, Cr=18.0, V=0.24 , Cu=0.4, Co=0.2, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=surplus.

[0067] After weighing the corresponding raw materials according to the composition requirements, induction melting is carried out under argon protection, and the temperature of the molten pool is kept at 1700 ℃ during smelting; the molten steel is sedated for 7 minutes before pouring, and the molten steel is poured at 1550 ℃ under argon protection.

[0068] The plate is hot rolled by a flat roll mill. The hot rolling plan is to heat the cast slab to 1280°C, hold it for 4 hours, and roll it out of the furnace. The starting temperature of hot rolling is 1180°C, and the final rolling temperature is 980°C. The total amount of hot rolling of the sheet is 70%.

[0069] The p...

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Abstract

The invention provides copper-vanadium-cobalt modified austenitic stainless steel and a processing and heat treatment method thereof. The modified austenitic stainless steel is prepared from, by mass,smaller than or equal to 0.03% of C, 8.0%-12.0% of Ni, 18.0%-20.0% of Cr, smaller than or equal to 0.43% of V, 0.2%-0.8% of Cu, 0.1%-0.5% of Co, smaller than or equal to 2.0% of Mn, smaller than or equal to 1.0% of Si, smaller than or equal to 0.035% of P, smaller than or equal to 0.030% of S and the balance Fe, wherein V is larger than or equal to 4.24*C and smaller than or equal to 4.24*C+0.3.The processing and heat treatment method comprises the steps of hot-deformation cogging, cold deformation, VC crushing and dispersing, high temperature solution treatment and grain coarsening. Under the oxygen feeding condition, the corrosion current density in a 0.5 mol / L H2SO4 electrolyte containing 5*10<-6> F<-1> at 80 DEG C ranges from 1.09 microamperes / cm<2> to 1.78 microamperes / cm<2>, and the corrosion current density is equal to that of a stainless steel bipolar plate material with a surface coating. The austenitic stainless steel has the advantages of being low in hardness and high inextension, and forming of a bipolar plate runner is facilitated.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to the composition design, processing and heat treatment method of high corrosion-resistant austenitic stainless steel, and can be widely used in the fields of energy, electric power, chemical industry and daily life. technical background [0002] A fuel cell is a device that converts the chemical energy between hydrogen fuel and oxidant directly into electrical energy through electrode reactions. Because of its high efficiency, low pollution, short construction time, good reliability and maintenance, it is the fourth generation of power generation technology after hydropower, thermal power and nuclear power. Among the many fuel cells, the proton exchange membrane fuel cell is a new type of fuel cell developed relatively late, but its development is the fastest. [0003] In a fuel cell, the conductive separators that support, collect, divide the oxidant and the reductant, and gu...

Claims

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Application Information

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IPC IPC(8): C21D1/18C21D1/26C21D1/74C21D1/773C21D8/02C21D8/06C21D8/10C22C33/06C22C38/02C22C38/04C22C38/42C22C38/46C22C38/52C22C38/58
CPCC21D1/18C21D1/26C21D1/74C21D1/773C21D8/0226C21D8/0236C21D8/065C21D8/105C21D2211/001C22C33/06C22C38/002C22C38/02C22C38/04C22C38/42C22C38/46C22C38/52C22C38/58Y02P10/20
Inventor 罗丰华王宸陶洪亮魏伟伍中华罗硕
Owner CENT SOUTH UNIV