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A new superconducting thermal ceramic film composite material and its preparation method

A technology of super thermal conductivity and new material, applied in the field of wave absorbing functional materials, can solve problems such as affecting the safe operation of boilers, reducing boiler thermal efficiency, corroding metal tube walls, etc., achieving low thermal expansion coefficient, remarkable wave absorbing performance, and corrosion resistance. Good results

Active Publication Date: 2022-03-18
上海欧尔塔特种印刷科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The wear and corrosion of these boilers also revealed the degree of damage to the surface of the water wall of the boiler. During the operation, due to the variety and quality of the fuel, the high temperature corrosion and wear of the boiler caused the tube wall to be significantly thinned, and a tube burst accident occurred. Seriously affect the safe operation of the boiler, and the thermal efficiency of the boiler will also be significantly reduced after long-term use, especially when the flue gas with a large concentration directly washes the tube wall, the pyrite powder in the fuel will stick together with the unburned fuel. On the pipe wall, it is decomposed by heat to generate elemental sulfur and iron sulfide. Hydrogen sulfide and sulfur dioxide adhere to the pipe wall, which will sulfide the metal pipe wall and severely corrode the metal pipe wall.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A new superconducting thermal ceramic film composite material, prepared from the following raw materials in parts by weight: 22 parts of instant sodium silicate, 30 parts of crystalline silicon, 5 parts of nano-magnesia, 15 parts of carbon fiber, 3 parts of boron fiber, silicon 3 parts of acid fiber, 10 parts of alumina powder, 25 parts of deionized water.

[0021] The particle size of the alumina powder is 150-180 mesh.

[0022] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0023] (1) Add deionized water to instant sodium silicate to dilute, stir at 75°C to obtain a transparent solution, dilute to 60% concentration, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0024] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new composite material of ...

Embodiment 2

[0030] A new superconducting ceramic film composite material, prepared from the following raw materials in parts by weight: 20 parts of instant sodium silicate, 32 parts of crystalline silicon, 8 parts of nano-magnesium oxide, 17 parts of carbon fiber, 5 parts of boron fiber, silicon 5 parts of acid fiber, 12 parts of alumina powder, 23 parts of deionized water.

[0031] The particle size of the alumina powder is 150-180 mesh.

[0032] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0033] (1) Add deionized water to instant sodium silicate to dilute, stir at 75°C to obtain a transparent solution, dilute to 60% concentration, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0034] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new composite material of s...

Embodiment 3

[0037] A new superconducting thermal ceramic film composite material, prepared from the following raw materials in parts by weight: 25 parts of instant sodium silicate, 28 parts of crystalline silicon, 4 parts of nano-magnesia, 13 parts of carbon fiber, 2 parts of boron fiber, silicon 2 parts of acid fiber, 8 parts of alumina powder, 28 parts of deionized water.

[0038] The particle size of the alumina powder is 150-180 mesh.

[0039] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0040] (1) Add deionized water to the instant sodium silicate for dilution, stir at 75°C to obtain a transparent solution, dilute to a concentration of 60%, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0041] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new composite m...

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Abstract

The invention discloses a new superconducting ceramic film composite material and a preparation method thereof, belonging to the technical field of wave-absorbing functional materials. The composite material is prepared from the following raw materials in parts by weight: 20-25 parts of instant sodium silicate , 28-32 parts of crystalline silicon, 4-8 parts of nano-magnesia, 13-17 parts of carbon fiber, 2-5 parts of boron fiber, 2-5 parts of silicate fiber, 8-12 parts of alumina powder, 23-23 parts of deionized water 28 servings. The obtained material is covered on the metal surface and isolated from the external medium to block the external high-temperature oxygen and corrosive substances, effectively protect the metal pipe wall, and has remarkable wave-absorbing performance, generates infrared radiation, and has a good energy-saving effect. It is used in boilers In the field of energy saving and environmental protection, the boiler can operate safely, reduce the friction and explosion of the boiler, reduce the coking of the boiler furnace, and prolong the service life of the boiler.

Description

technical field [0001] The invention relates to the technical field of wave-absorbing functional materials, in particular to a new superconducting heat-conducting porcelain film composite material and a preparation method thereof. Background technique [0002] With the continuous development of society, the types of boilers are also increasing rapidly, such as coal-fired boilers in power plants, fluidized bed boilers, cracking furnaces in Sinopec, steam injection boilers in PetroChina, vacuum heating furnaces, etc. The wear and corrosion of these boilers also revealed the degree of damage to the surface of the water wall of the boiler. During the operation, due to the variety and quality of the fuel, the high temperature corrosion and wear of the boiler caused the tube wall to be significantly thinned, and a tube burst accident occurred. Seriously affect the safe operation of the boiler, and the thermal efficiency of the boiler will also be significantly reduced after long-t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/26
CPCC04B28/26C04B2111/763C04B2111/00525C04B22/02C04B22/066C04B14/386C04B14/38C04B14/303
Inventor 张帅韩锋
Owner 上海欧尔塔特种印刷科技有限公司
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