The invention discloses an electrolytic solution of a
platinum-
rhodium alloy, a preparation method and a preparation method of a plating layer of the
platinum-
rhodium alloy, and belongs to the technical field of precise
electroplating. The electrolytic solution comprises a
platinum salt, a
rhodium salt, a first additive, a second additive, a first complexing agent, a second complexing agent, a first stabilizer and a second stabilizer, the first additive is a
sulfamic acid compound containing 3-4 hydroxyalkyl groups, the second additive is
sulfamic acid salt containing 3-4 hydroxyalkyl groups, and the first complexing agent and the second complexing agent are a platinum salt and a
rhodium salt. The first complexing agent is a mixture of
dicarboxylic acid and
dicarboxylic acid containing amino or hydroxyl, the second complexing agent is a salt corresponding to the
dicarboxylic acid, and the first stabilizer is a mixture of
alkyl sulfonic acid and
alkyl sulfonate. Through the synergistic effect of the additive, the complexing agent and the stabilizer, the additive, the complexing agent and the stabilizer form a five-membered to seven-membered heterocyclic
coupling structure with platinum ions and rhodium ions, and the stability of the electrolytic solution is remarkably improved. And the obtained platinum-rhodium
alloy coating is compact and uniform, and has excellent
nitric acid steam and
mixed gas corrosion resistance.