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Method of using shells to prepare high activity porous superfine Ca(OH)2

A high-activity, CO2 technology, applied in the direction of calcium/strontium/barium oxide/hydroxide, etc., can solve the problems of poor activity, whiteness and BET performance, and it is difficult to obtain high activity, so as to achieve the effect of performance improvement

Active Publication Date: 2019-04-19
厦门山俊水杰科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Calcium oxide is also fired from shells. The method follows the traditional method of firing CaO from limestone, and it is difficult to obtain highly active Ca(OH) 2 pink
And the Ca(OH) obtained by burning CaO with traditional limestone 2 The reactivity, whiteness and BET performance of Ca(OH) are relatively poor, therefore, those skilled in the art are badly in need of highly active porous ultrafine Ca(OH) 2 The preparation method makes further improvement research

Method used

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  • Method of using shells to prepare high activity porous superfine Ca(OH)2
  • Method of using shells to prepare high activity porous superfine Ca(OH)2
  • Method of using shells to prepare high activity porous superfine Ca(OH)2

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Weigh shells and KOH with a weight ratio of 50:1, add water to dissolve, the weight ratio of shells and water is 1:3, heat and cook until the phosphorus-containing membrane on the inner wall of the shell is destroyed, wash the shells, perform centrifugal dehydration, and dry ;

[0036] Then put the alkali-washed shells into the HCl solution with a mass concentration of 1%-5%, the weight ratio of the shells to the HCl solution with a mass concentration of 1%-5% is 1:1.7, and stir until the impurities on the outer wall of the shell are removed Finally, the shells are washed, centrifugally dehydrated, and then dried;

[0037] The shells after alkali washing and acid washing are coarsely crushed to 1-3mm as required, and then the coarsely crushed shells are ultrafinely crushed to 800nm ​​by airflow mill as required, and the obtained ultrafine crushed shell powder is subjected to vertical airflow calcination method Calcination, using the airflow from bottom to top to suspen...

Embodiment 2

[0040] The difference from Example 1 is that the material temperature in the vertical airflow calcination decomposition zone in the preparation step is 30°C.

Embodiment 3

[0042] The difference from Example 1 is that the material temperature in the vertical airflow calcination decomposition zone in the preparation step is 150°C.

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Abstract

The invention belongs to the field of shell recovery and utilization, relates to a method of using shells to prepare high activity porous superfine Ca(OH)2, and solves the problem that high activity porous Ca(OH)2 powder is hard to prepare by a conventional limestone burning method for preparing CaO. According to the method, shells are washed by an acid and an alkali, then shells are coarsely grinded and finely grinded to obtain shell powder; the shell powder is burned by a vertical air flow burning method; hot air flow that goes upwards is utilized to suspend shell powder during the burning process, CO2 generated in shell decomposition is separated and discharged, at the same time, organic substances are discharged too, high activity porous CaO powder is obtained; in a CO2-free enclosed space, the humidity is maintained to make obtained high activity porous CaO powder carry out high activity porous superfine Ca(OH)2 slow reactions to prepare high activity porous superfine Ca(OH)2. Theactivity, whiteness and BET of prepared high activity porous superfine Ca(OH)2 are all improved; the activity is greater than 400; the whiteness is greater than 80; and the BET is greater than 25 m<2> / g.

Description

technical field [0001] The invention belongs to the field of shell recycling and relates to a method for preparing highly active porous ultrafine Ca(OH) from shells. 2 The method and obtained highly active porous ultrafine Ca(OH) 2 . Background technique [0002] Calcium hydroxide is a white powdery solid. Chemical formula Ca(OH) 2 , commonly known as slaked lime, slaked lime, and the aqueous solution is called clarified lime water. Calcium hydroxide has alkaline properties and is a strong base. Calcium hydroxide is a strong binary base, but it is only slightly soluble in water. Calcium hydroxide is widely used in industry; it can be used to make bleaching powder, hard water softener, improve soil acidity, tap water disinfection clarifier and construction industry, etc. The main component of 95% of the shell is calcium carbonate, and a small amount of amino acids and polysaccharides. Shell preparation Ca(OH) 2 It is one of the new applications of shell powder, and na...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F11/02
CPCC01F11/02C01P2002/72C01P2006/12C01P2006/60
Inventor 王平谢亮黄徐亮朱创国周毅李晓晴
Owner 厦门山俊水杰科技有限公司