Step-by-step pre-lithiation method of lithium-ion battery negative plate
A lithium-ion battery and pre-lithiation technology, applied in the field of lithium-ion batteries, can solve the problems of unsatisfactory accuracy and uniformity environmental control, low efficiency, etc., to improve the efficiency and safety of pre-lithiation, and easily control the process conditions. , the effect of stable performance
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Embodiment 1
[0061] This embodiment provides a step-by-step pre-lithiation method for a silicon-carbon negative electrode sheet. The step-by-step pre-lithiation method of the silicon carbon negative plate comprises the following steps:
[0062] Pass the silicon carbon negative electrode sheet to be treated sequentially through such as image 3 The shown pre-lithiation unit 1, pre-lithiation unit 2, pre-lithiation unit 3, pre-lithiation unit 4, pre-lithiation unit 5, and pre-lithiation unit 6 are respectively subjected to infiltration treatment and charging treatment,
[0063] Wherein, the composition that the electrolytic solution that pre-lithiation unit 1 comprises comprises is as follows:
[0064] Lithium salt: LiPF 6 0.9mol / L;
[0065] Film-forming additive: a mixture of fluoroethylene carbonate (FEC) and lithium difluorooxalate borate (LiODFB) with a mass ratio of 1:1, with a total content of 3%;
[0066] Solvent: a mixture of ethylene carbonate (EC) and propylene carbonate (PC) ...
Embodiment 2
[0084] This embodiment provides a step-by-step pre-lithiation method for a silicon-carbon negative electrode sheet. The step-by-step pre-lithiation method of the silicon carbon negative plate comprises the following steps:
[0085] Pass the silicon carbon negative electrode sheet to be treated sequentially through such as image 3 The shown pre-lithiation unit 1, pre-lithiation unit 2, pre-lithiation unit 3, pre-lithiation unit 4, pre-lithiation unit 5, and pre-lithiation unit 6 are respectively subjected to infiltration treatment and charging treatment,
[0086] Wherein, the composition that the electrolytic solution that pre-lithiation unit 1 comprises comprises is as follows:
[0087] Lithium salt: LiPF 6 0.5mol / L;
[0088] Film-forming additive: a mixture of fluoroethylene carbonate (FEC) and lithium difluorooxalate borate (LiODFB) with a mass ratio of 1:1, with a total content of 6%;
[0089] Solvent: a mixture of ethylene carbonate (EC) and propylene carbonate (PC) ...
Embodiment 3
[0106] This embodiment provides a step-by-step pre-lithiation method for a silicon-carbon negative electrode sheet. The step-by-step pre-lithiation method of the silicon carbon negative plate comprises the following steps:
[0107] Pass the silicon carbon negative electrode sheet to be treated sequentially through such as image 3 The shown pre-lithiation unit 1, pre-lithiation unit 2, pre-lithiation unit 3, pre-lithiation unit 4, pre-lithiation unit 5, and pre-lithiation unit 6 are respectively subjected to infiltration treatment and charging treatment,
[0108] Wherein, the composition that the electrolytic solution that pre-lithiation unit 1 comprises comprises is as follows:
[0109] Lithium salt: LiPF 6 1.2mol / L;
[0110] Film-forming additive: a mixture of fluoroethylene carbonate (FEC) and lithium difluorooxalate borate (LiODFB) with a mass ratio of 3:1, with a total content of 0.2%;
[0111] Solvent: a mixture of ethylene carbonate (EC) and propylene carbonate (PC...
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