A kind of hydrophobically modified phosphate and its preparation method and application in fireproof putty
A hydrophobic modification and phosphate technology, applied in the direction of filling slurry, etc., can solve the problems of expensive raw materials and complicated processes, and achieve the effect of good cohesion, small particle size and excellent hydrophobic effect
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[0046] Preparation of finished fireproof putty. Specifically, in the state of stirring, slowly add the hydrophobically modified phosphate and the blended grinding material (grinding material) of powder raw materials into the liquid mixed material, stir evenly, and grind with a grinder or a three-roller machine to obtain Fireproof putty. The fineness of the obtained fireproof putty is less than 50 microns.
[0047] In the present disclosure, the fireproof putty has the characteristics of high viscosity and low fluidity, which depends on the synergistic effect of each component and its content. The fluidity of the fireproof putty is satisfactory: the fireproof putty is placed in a beaker, the beaker is tilted at 45°, and the fireproof putty has no flow or deformation.
[0048] In the present disclosure, the coating obtained by using the fireproof putty on the wood board has good water resistance and fire resistance, the water resistance time is greater than 48 hours, and the f...
Embodiment 1
[0051] (1) Phosphate Hydrophobic Modification
[0052] Weigh 5.0 grams of ammonium polyphosphate powder (1), place it in a mortar, weigh 1.0 grams of tetraethyl orthosilicate (2) at the same time, add (2) to (1) powder in 10 times, Add 0.1 g each time, and grind for 15 minutes after each drop, until all (2) is added and (1) powder is evenly dispersed without agglomeration. The particle size of the obtained powder is less than 50 microns. The obtained modified phosphate powder is denoted as A1;
[0053] (2) Blending and grinding of powder raw materials
[0054] Weigh 3.0 grams of melamine, 2.5 grams of dipentaerythritol, 1.0 grams of titanium dioxide powder, and 0.5 grams of nano-silicon oxide powder, and grind them in a mortar for 3 hours until the particle size of the powder is less than 50 microns. The resulting mixed powder is recorded as A2 ;
[0055] (3) Mixing of liquid materials
[0056] Take by weighing 8.0 grams of acrylic acid emulsion, 3.0 grams of water, 0.1 g...
Embodiment 2
[0061] (1) Phosphate Hydrophobic Modification
[0062] Weigh 6.0 grams of aluminum phosphate powder, place it in a mortar, weigh 0.5 grams of hexamethyldisiloxane (2) at the same time, add (2) to (1) powder in 10 times, each time 0.05 g, grind for 5 minutes after each dropwise addition, until all (2) is added and (1) powder is evenly dispersed without agglomeration. The particle size of the obtained powder is less than 30 microns. The obtained modified phosphate powder is denoted as A1;
[0063] (2) Blending and grinding of powder raw materials
[0064] Weigh 3.0 grams of melamine, 2.5 grams of pentaerythritol, and 1.0 grams of nano-titanium oxide powder, place them in a mortar and grind for 1 hour until the particle size of the powder is less than 30 microns, and the resulting mixed powder is recorded as A2;
[0065] (3) Mixing of liquid materials
[0066] Weigh 5.0 grams of vinyl acetate-ethylene copolymer emulsion, 2.0 grams of water, 0.05 grams of sodium dodecylbenzene...
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