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Photocured 3D printing resin material and preparation method thereof

A technology of 3D printing and resin materials, applied in the direction of additive processing, etc., can solve the problems affecting the dimensional accuracy and surface state of cured materials, the reduction of material performance and stability, and the difficulty of releasing internal stress, etc., to improve printing efficiency, Effects of reduced volume shrinkage and improved tensile strength and impact strength

Active Publication Date: 2019-06-21
HANGZHOU LEYI NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology relates to making three dimensional objects that can be cured into hardened plastics through UV laser radiation or other means like sterilization techniques such as heating them under pressure during manufacturing processes. By adding certain chemical agents (PB) together it becomes possible to make these objects stronger without losing their shape after curing due to increased molecular orientation between different polymers within each object's structure. These technical improvements improve mechanical properties over traditional methods while reducing volumetric shrinking rates caused by thermal expansion.

Problems solved by technology

This patented describes different ways for making precise three dimensions with an improved process called Digital Projection Technology (DP). These techniques involve projecting images onto special surfaces or layers formed from photosensitive compositions containing photoinitiators such as diazaphthoquinones. By controllably adjusting how much each pixel reacts during exposure, these processes allow for creation of highly accurate models without requiring expensive equipment like LSZ™ machines. Additionally, there have also developed methods for reducing residue curl after being exposed to heat while still maintaining flexibility and resistance against damage due to external forces. Overall, this new technique improves the quality control and efficiency of producing precision objects through quick prototype manufacturings.

Method used

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  • Photocured 3D printing resin material and preparation method thereof
  • Photocured 3D printing resin material and preparation method thereof
  • Photocured 3D printing resin material and preparation method thereof

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preparation example Construction

[0025] Correspondingly, the present invention also provides a method for preparing the photocurable 3D printing resin material described in the above technical solution, which comprises the following steps in parts by weight: mixing 1-10 parts of polyvinyl butyral and 30-70 parts Mix the active diluent at room temperature, heat to 50-80°C, keep it warm for 30-90 minutes, then stir at high speed for 30-60 minutes at room temperature to obtain a mixed solution; add 20-50 parts of acrylate, 1- 10 parts of free radical photoinitiator and 0.5-5 parts of additives, stirred at high speed for 60-90 minutes, after being uniformly dispersed, ultrasonically oscillated until defoaming, and a light-cured 3D printing resin material was obtained.

[0026] As a preferred solution, the polyvinyl butyral is preferably 3-7 parts, and the reactive diluent is preferably 40-60 parts. In the step of obtaining the mixed solution, the heating temperature is preferably 70° C.; the time for standing at ...

Embodiment 1-6

[0032] A photocurable 3D printing resin material based on digital projection technology, which is composed of polyurethane acrylate, polyvinyl butyral, tricyclodecane dimethanol diacrylate, hydroxyethyl acrylate, bis(2,4,6- Trimethylbenzoyl) phenyl phosphine oxide, defoamer, leveling agent mixed. Wherein each raw material and its weight percentage are shown in Table 1.

[0033] The preparation method of described photocuring 3D printing resin material comprises the following steps:

[0034] (1) Take polyvinyl butyral and tricyclodecane dimethanol diacrylate respectively, mix them at room temperature, heat to 70°C, keep the temperature for 60 minutes, and then stir at room temperature for 60 minutes at high speed to obtain a transparent and uniform liquid.

[0035](2) Add polyurethane acrylate, hydroxyethyl acrylate, 2-benzyl-2-dimethylamino-1-(morpholine phenyl) butanone-1, defoamer, leveling agent in the obtained liquid, After mixing at room temperature, stir at a high spee...

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Abstract

The invention provides a photocured 3D printing resin material and a preparation method thereof. The photocured 3D printing resin material is prepared from raw materials in parts by weight as follows:20-50 parts of acrylate, 1-10 parts of PVB (polyvinyl butyral), 30-70 parts of a reactive diluent, 1-10 parts of a free radical photoinitiator and 0.5-5 parts of an auxiliary. Compared with the priorart, PVB is added to a 3D printing material by premixing, so that tensile strength and impact strength of the photocured 3D printing material are improved, volume shrinkage of the printing material is reduced, and the problem of high probability of warping of a printed piece with larger bottom area is solved; further, PVB has good adhesion to metal, thus, exposure time of a bottom layer of the printed piece is reduced obviously, and printing efficiency is increased. Therefore, the prepared 3D printing material has higher tensile strength, impact strength and elongation at break and small volume shrinkage and is applicable to DPL type 3D printing.

Description

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Claims

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Application Information

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Owner HANGZHOU LEYI NEW MATERIAL TECH CO LTD
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