A kind of yellow acid dye composition and its dyeing application on fiber
A technology for acid dyes and dye compounds, which is applied to acid dye compositions and their dyeing application fields, can solve the problems of insufficient brightness, solubility and dye depth, influence popularization and application, etc., and achieve the effect of excellent dyeing improvement rate.
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[0064] The synthetic method of dyestuff 1-3 thus comprises the following operating steps:
[0065] Add 24.2 parts of 2,5-dichloro-4-aminobenzenesulfonic acid to 240ml of water, and add 30 parts of 30% hydrochloric acid, maintain the temperature at 0-5°C, add 23 parts of 30% sodium nitrite aqueous solution dropwise for diazotization Reaction, after the diazonium reaction is completed, add a small amount of sulfamic acid to eliminate a small amount of unreacted sodium nitrite.
[0066] Add 44.2 parts of 2-N,N-dibutylamino-4-(4'-sulfonic acid phenethylamino)-6-methylpyrimidine directly into the diazonium reaction liquid, adjust and maintain pH = 6 with aqueous sodium carbonate -7 for coupling reaction, the reaction temperature is 5-10°C.
[0067] After the coupling reaction is completed, filter and wash to obtain the dye I-3.
[0068] The synthetic reaction formula is:
[0069]
[0070] The general formula (I) represents the same kind of structural general formula or the sy...
Embodiment 1-10 and comparative example 1-2
[0077] The types of dyes and their dosages shown in Table 1 below were used to uniformly mix various dye components according to conventional methods in the art to prepare various yellow acid dye compositions of Examples 1-10 of the present invention.
[0078] "%" in Table 1 means % by weight, based on the total weight of the dye composition.
[0079] Component and component content thereof of the dye composition of table 1 embodiment 1-10
[0080]
[0081]
[0082] Two, the various test data of embodiment
[0083] Test objects: use the yellow acid dye compositions prepared in Examples 1-10 as dye compositions A-J, and use the yellow acid dye compositions prepared in Comparative Examples 1-2 as reference dyes X-Y.
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