Vehicle spraying-free composite material and preparation method thereof

A composite material, spray-free technology, applied in the field of automotive materials, can solve the problems of welding lines, flow marks, affecting the injection molding performance of materials, affecting the thermal processing performance of materials, etc., to reduce flow marks, improve hardness, and good thermal processability. Effect

Pending Publication Date: 2019-10-15
SUZHOU RUNJIA ENGINEER PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, there are still some shortcomings in the spray-free materials for vehicles at present: for example, after the material is injected into a finished product, there will be appearance problems such as weld lines and flow marks on the surface; at the same time, the hardness of the spray-free material is still much worse than that of metallic paint. The current solution The method is to add a cross-linking agent; but the addition of a cross-linking agent greatly affects the thermal processing performance of the material, thereby affecting the injection molding performance of the material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The present invention provides a spray-free composite material for vehicles. The raw materials for preparing the material are composed of 70 parts by mass of polypropylene resin, 20 parts by mass of filler, 2 parts by mass of metal powder, and 4 parts by mass of potassium cetylsulfonate. , 2 parts by mass of cyclopentadiene, 2 parts by mass of antioxidant.

[0027] Among them: polypropylene resin has a flow rate of 35-50g / min under a load of 2.16kg at a temperature of 230°C.

[0028] The filler is talc powder coated with epoxy resin. The modified talc powder is more compatible with polypropylene resin. The particle size of talc powder is 10-15μm.

[0029] The metal powder is aluminum powder and is wrapped in double layers; the inner layer is coated with phenolic resin, and the outer layer is coated with silica nano powder. The inner layer is used to improve the thermal conductivity of aluminum powder, thereby reducing the appearance of weld lines; the outer layer of silica na...

Embodiment 2

[0040] The invention provides a spray-free composite material for vehicles. The raw materials for preparing the material are composed of 80 parts by mass of polypropylene resin, 15 parts by mass of filler, 8 parts by mass of metal powder, and 6 parts by mass of sodium stearyl carboxylate. , 2 parts by mass of cyclopentadiene, 3 parts by mass of antioxidant.

[0041] Among them: the properties and functions of polypropylene resin, filler, cyclopentadiene, and antioxidant are the same as in Example 1.

[0042] The metal powder is also aluminum powder, which is wrapped in double layers; the inner layer is coated with polyacrylate resin, and the rest is the same as in Example 1.

[0043] The addition of sodium octadecyl carboxylate is beneficial to improve the compatibility of the powder and the polypropylene substrate and reduce the generation of flow marks.

[0044] The spray-free composite material for this vehicle is prepared by the following steps:

[0045] (1) Add aluminum powder to ...

Embodiment 3

[0051] The present invention provides a spray-free composite material for vehicles. The raw materials for preparing the material are composed of: 75 parts by mass of polypropylene resin, 20 parts by mass of filler, 5 parts by mass of metal powder, and 2 parts by mass of sodium eicosyl sulfonate , 5 parts by mass of cyclopentadiene, 1 part by mass of antioxidant.

[0052] Among them: polypropylene resin, filler, metal powder, cyclopentadiene, and antioxidant have the same properties and functions as in Example 1.

[0053] The addition of sodium eicosyl sulfonate is beneficial to improve the compatibility of the powder and the polypropylene substrate and reduce the generation of flow marks.

[0054] The spray-free composite material for this vehicle is prepared by the following steps:

[0055] (1) Add aluminum powder to the organic solution of phenolic resin with a concentration of 35wt% (the mass ratio of aluminum powder to organic solution of phenolic resin is 1:4), stir at high speed...

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Abstract

The invention relates to a vehicle spraying-free composite material. The vehicle spraying-free composite material comprises the following raw materials: polypropylene resin, fillers, metal powder, straight-chain alkyl acid salt, cyclopentadiene and an antioxidant, wherein the metal powder adopts double-layer wrapping; the inner layer is wrapped with thermosetting resin; and the outer layer is wrapped with silicon dioxide nanopowder. Meanwhile, the invention also relates to a method for preparing the method. Aluminum powder is wrapped by double layers; the inner is used for reducing the heat conductivity coefficient of the metal powder, so that occurrence of a welding line is reduced; and the outer layer of silicon dioxide nanopowder can prevent physical or chemical change of the metal powder and the inner layer during high-temperature treatment. Due to addition of the straight-chain alkyl acid salt, the compatibility of the powder and the polypropylene base material is improved and occurrence of current ripple is reduced; and due to addition of the cyclopentadiene, crosslinking effect can be achieved and the integral hardness of the material is increased; meanwhile, due to the high-temperature depolymerization characteristic of the cyclopentadiene, the high-temperature processing property of the polypropylene resin is not influenced.

Description

Technical field [0001] The invention relates to the field of materials for vehicles, in particular to a spray-free composite material for vehicles and a preparation method thereof. Background technique [0002] With the continuous development of the automotive industry, the application of new materials and technologies provides new ideas for the development of parts. The interior and exterior plastic products of automobiles are usually sprayed with paint, which not only involves complicated procedures, but also causes great pollution to the environment. Spray-free materials are materials that add metal powder to plastic raw materials and directly inject them to make the products show the appearance of spraying. Nowadays, some interior and exterior decoration free spray parts have gradually replaced spray paint parts into the market. The application of spray-free materials simplifies the molding process of automotive interior and exterior parts to a certain extent, enhances prod...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K13/06C08K9/10C08K3/08C08K5/098C08K3/36C08K3/34C08K5/42C08F255/02C08F232/06
CPCC08K13/06C08K9/10C08K3/08C08K5/098C08K3/36C08K3/34C08K5/42C08F255/02C08K2003/0812C08K2201/011C08L23/12C08F232/06
Inventor 汪理文李庆贵周明张辉牛国增翁永华
Owner SUZHOU RUNJIA ENGINEER PLASTIC
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