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scheelite phase dycro 4 Application in magnetoelectric sensor unit, magnetoelectric sensor unit and preparation method thereof

A magnetoelectric sensor, scheelite technology, applied in the field of sensors, can solve problems such as complex structure

Active Publication Date: 2021-04-27
INST OF PHYSICS - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the composite magnetoelectric coupling material has achieved a large response coefficient through the interaction between the magnetostrictive layer and the piezoelectric layer (such as Terfenol-D / PZT), but the composite material is composed of multiple active layers, so the structure is comparatively small. complex

Method used

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  • scheelite phase dycro  <sub>4</sub> Application in magnetoelectric sensor unit, magnetoelectric sensor unit and preparation method thereof
  • scheelite phase dycro  <sub>4</sub> Application in magnetoelectric sensor unit, magnetoelectric sensor unit and preparation method thereof
  • scheelite phase dycro  <sub>4</sub> Application in magnetoelectric sensor unit, magnetoelectric sensor unit and preparation method thereof

Examples

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Effect test

Embodiment 1

[0048] Deposit a layer of 10nm thick Au on the silicon dioxide substrate as the bottom electrode by vacuum evaporation technology;

[0049] DyCrO in the scheelite phase 4 As a target, a dielectric layer with a thickness of 200nm is formed on the lower electrode by pulsed laser deposition technology;

[0050] A layer of Au with a thickness of 10nm was deposited on the dielectric layer by vacuum evaporation technology as the upper electrode.

[0051] DyCrO in the scheelite phase of the dielectric layer in this example 4 Made by the following steps:

[0052] Dy(NO) with a purity higher than 99% 3 ) 3 and Cr(NO 3 ) 3 Mix according to the molar ratio of 1:1, and grind in the air for 30 minutes to obtain a mixture with a particle size of 200 mesh. The mixture was calcined in an air atmosphere at 600° C. for 1 hour, and the calcined product was ground for 30 minutes to obtain a powdery mixture. The mixture was calcined at 300° C. for 6 hours in a pure oxygen environment, and ...

Embodiment 2

[0060] A layer of 200nm thick Ag is deposited on the silicon dioxide substrate by magnetron sputtering technology as the lower electrode;

[0061] DyCrO in the scheelite phase 4 As a target, a dielectric layer with a thickness of 20 μm is formed on the lower electrode by pulsed laser deposition technology;

[0062] A layer of Ni with a thickness of 200nm is deposited on the dielectric layer by magnetron sputtering technology as the upper electrode.

[0063] DyCrO in the scheelite phase of the dielectric layer in this example 4 Made by the following steps:

[0064] Dy(NO) with a purity higher than 99% 3 ) 3 and Cr(NO 3 ) 3 Mix according to the molar ratio of 1:1, and grind in the air for 60 minutes to obtain a mixture with a particle size of 500 mesh. The mixture was calcined in an air atmosphere at 500° C. for 2 hours, and the calcined product was ground for 40 minutes to obtain a powdery mixture. The mixture was calcined at 350° C. for 4 hours in a pure oxygen environ...

Embodiment 3

[0067] in Al 2 o 3 Apply a layer of 10μm thick silver glue evenly on the substrate as the lower electrode;

[0068] Before the silver colloid is dry, the following steps will be used to obtain DyCrO in the scheelite phase 4 A thin sheet with a thickness of 200 μm that is polished to be smooth on both sides is used as a dielectric layer and covered on the lower electrode;

[0069] A layer of silver glue with a thickness of 10 μm was applied on the dielectric layer as the upper electrode.

[0070] DyCrO in the scheelite phase of the dielectric layer in this example 4 Made by the following steps:

[0071] Dy(NO) with a purity higher than 99% 3 ) 3 and Cr(NO 3 ) 3 Mix according to the molar ratio of 1:1, and grind in air for 2 hours to obtain a mixture with a particle size of 200 mesh. The mixture was calcined in an air atmosphere at 550° C. for 1.5 hours, and the calcined product was ground for 30 minutes to obtain a powdery mixture. The mixture was calcined at 250° C. ...

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Abstract

The invention provides a DyCrO of scheelite phase 4 Applications in magnetoelectric sensor units. The present invention also provides a magnetoelectric sensor unit, comprising: a substrate, a lower electrode on the substrate, a dielectric layer on the lower electrode, and an upper electrode on the dielectric layer; wherein the dielectric layer is made of scheelite Mineral phase of DyCrO 4 form. The present invention also provides a method for preparing the magnetoelectric sensor unit of the present invention, comprising the following steps: (1) forming a lower electrode on a substrate; (2) using DyCrO in a scheelite phase 4 As a target, a dielectric layer is formed on the lower electrode; (3) an upper electrode is formed on the dielectric layer. The magnetoelectric sensor unit provided by the present invention has a simple structure and is formed of a single-phase material. The present invention utilizes the method of high temperature and high pressure to process, so that DyCrO 4 It shows stable and effective multiferroic properties of magnetoelectric coupling, which provides a new way for the exploration and discovery of magnetoelectric coupling materials.

Description

technical field [0001] The invention relates to the field of sensors. In particular, the present invention relates to DyCrO in the scheelite phase 4 Application in magnetoelectric sensor unit, magnetoelectric sensor unit and preparation method thereof. Background technique [0002] Magnetic field sensors are closely related to people's production and life, and the application environment is rich and colorful. As one of the most sensitive magnetic field sensors, the superconducting quantum interferometer has the disadvantages of high cost and high requirements for shielding effect. However, the magnetic field sensor based on multiferroic magnetoelectric coupling materials has lower cost and smaller size, which has attracted widespread attention. In the multiferroic magnetoelectric coupling material, the magnetism of the material is highly correlated with the electric polarization, so it can respond to obvious external magnetic field changes, thereby outputting voltage and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01R33/06
CPCG01R33/06
Inventor 龙有文申旭东
Owner INST OF PHYSICS - CHINESE ACAD OF SCI