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A temperature-sensitive color-changing hydrogel with transiently encrypted information and its preparation method

A technology of encrypting information and hydrogel, which is applied in the field of temperature-sensitive color-changing hydrogel and its preparation, can solve the problems of unfavorable encrypted information transmission, information leakage, etc., and achieve broadened design range, excellent mechanical strength, and overcome the problems of low mechanical strength Effect

Active Publication Date: 2021-09-21
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although the structural color of most anisotropic structural hydrogels can be reversibly regulated by the application / release of stress / strain, so as to achieve the reproducibility of information for the transmission of specific information; however, such characteristics will also It causes security risks such as information leakage, which is not conducive to the transmission of encrypted information. The design and preparation of materials with transient encrypted information that burns after reading has important applications in the safe transmission of high-level secret information.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] 1.5 g glyceryl lauryl itaconate, 2.9 mg sodium dodecyl sulfate, 7 g acrylamide, 7.6 mg N,N'-methylenebisacrylamide, 11.1 mg 2-hydroxy-4-( 2-Hydroxyethoxy)-2-methylpropiophenone was added to 100 g deoxygenated deionized water, and stood in a water bath at 50 °C for 4 h to obtain a stable and transparent solution 1. Keep the syringe and mold at 50 °C Fully preheated at C, inhaled solution 1 into a preheated syringe, then injected it into a transparent mold at a rate of 4 cm / s and sealed it well, placed it at 45 °C, initiated by 200nm ultraviolet light, polymerized for 4 hours, and obtained Hydrogel 1; 10 g N-isopropylacrylamide, 1.4 mg N,N'-methylenebisacrylamide and 10 mg 2-hydroxy-4-(2-hydroxyethoxy)-2-methanol Add phenylpropiophenone to 100 g of deoxygenated deionized water, completely dissolve to obtain solution 2, put hydrogel 1 in solution 2, soak at 15 °C for 16 h, take it out, put it into a transparent mold and seal it , cover a layer of mask with a specific patt...

Embodiment 2

[0041] 1.5 g glyceryl lauryl itaconate, 7.3 mg sodium lauryl sulfate, 14.2 g acrylamide, 15.5 mg N,N'-methylenebisacrylamide, 22.2 mg 2-hydroxy-4- (2-Hydroxyethoxy)-2-methylpropiophenone was added to 100g of deoxygenated deionized water, and allowed to stand in a water bath at 60 °C for 6 h to obtain a stable and transparent solution 1, and the syringe and the transparent mold were placed in the Fully preheat at 60 °C, inhale solution 1 into a preheated syringe, inject it into a transparent mold at a rate of 5 cm / s and seal it well, place it at 55 °C, trigger with 365 nm ultraviolet light, Polymerized for 6 h to obtain hydrogel 1; 22.63 g N-isopropylacrylamide, 3.1 mg N,N'-methylenebisacrylamide and 22.5 mg 2-hydroxy-4-(2-hydroxyethoxy) -2-Methylpropiophenone was added to 100 g deoxygenated deionized water, and solution 2 was obtained after completely dissolving, and hydrogel 1 was placed in solution 2, soaked at 20 °C for 12 h, and then put into a transparent In the mold and...

Embodiment 3

[0043] 1.5 g glyceryl lauryl itaconate, 14.6 mg sodium dodecyl sulfate, 21 g acrylamide, 46 mg N,N'-methylenebisacrylamide, 33.3 mg 2-hydroxy-4-( 2-Hydroxyethoxy)-2-methylpropiophenone was added to 100 g of deoxygenated deionized water, and allowed to stand in a water bath at 55 °C for 5 h to obtain a stable and transparent solution 1. Fully preheat at 55 °C, inhale solution 1 into a preheated syringe, inject it into a transparent mold at a rate of 5 cm / s and seal it, place it at 50 °C, and trigger it with 400 nm ultraviolet light, Polymerize for 5 h to obtain hydrogel 1; 35 g N-isopropylacrylamide, 4.8 mg N,N'-methylenebisacrylamide and 34.8 mg 2-hydroxy-4-(2-hydroxyethoxy )-2-Methylpropiophenone was added to 100 g deoxygenated deionized water, and solution 2 was obtained after complete dissolution. Put hydrogel 1 in solution 2, soak at 15°C for 12 h, take it out and put it into a transparent In the mold and sealed, a layer of mask with specific pattern and information is co...

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PUM

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Abstract

The invention discloses a temperature-sensitive color-changing hydrogel with transient encryption information and a preparation method thereof. The hydrogel is composed of polydodecyl itaconate / polyacrylamide first layer network and poly N ‑Isopropylacrylamide second temperature-sensitive network composition, prepared by a two-step method; by regulating N - The amount of isopropylacrylamide controls the cross-link density of the second re-temperature-sensitive network within a suitable window range to obtain the temperature-sensitive color-changing hydrogel with transiently encrypted information. The temperature-sensitive color-changing hydrogel with transiently encrypted information prepared by the present invention can temporarily display specific patterns and information at a specific temperature, can be used for the transmission of high-level secret information, and has the effect of burning after reading ; and due to the orientation structure of the bilayer in the gel, the gel has excellent mechanical strength, overcomes the shortcomings of low mechanical strength of traditional hydrogels, and can be applied to the field of mechanical visualization sensors.

Description

technical field [0001] The invention relates to the field of temperature-sensitive color-changing hydrogel intelligent materials, in particular to a temperature-sensitive color-changing hydrogel with transiently encrypted information and a preparation method thereof. Background technique [0002] Biological tissues contain a lot of water, exist in the state of soft wet gel, and usually have an anisotropic structure from the molecular level to the macroscopic level. The anisotropic architecture of these biological tissues enables organisms to perform highly elaborate functions. For example, actin and myosin exhibit liquid-crystalline anisotropic structures in muscle sarcomeres, which contribute to smooth movement of muscle fibers and muscle contraction in one direction while leaving the other unchanged. Liquid crystal materials with anisotropic or unidirectional orientation are crucial for artificial muscles. In contrast, most commonly used synthetic soft and wet hydrogels ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J3/075C08L33/24C08L33/26C08F220/56C08F222/38C08F222/20C08F220/54G01B11/16G01L1/24
CPCC08F220/54C08F220/56C08J3/075C08J2333/24C08J2433/26G01B11/16G01L1/24C08F222/385
Inventor 王涛张超杨述瑞廖洪芳孙尉翔童真
Owner SOUTH CHINA UNIV OF TECH
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