A temperature-sensitive color-changing hydrogel with transiently encrypted information and its preparation method
A technology of encrypting information and hydrogel, which is applied in the field of temperature-sensitive color-changing hydrogel and its preparation, can solve the problems of unfavorable encrypted information transmission, information leakage, etc., and achieve broadened design range, excellent mechanical strength, and overcome the problems of low mechanical strength Effect
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Embodiment 1
[0039] 1.5 g glyceryl lauryl itaconate, 2.9 mg sodium dodecyl sulfate, 7 g acrylamide, 7.6 mg N,N'-methylenebisacrylamide, 11.1 mg 2-hydroxy-4-( 2-Hydroxyethoxy)-2-methylpropiophenone was added to 100 g deoxygenated deionized water, and stood in a water bath at 50 °C for 4 h to obtain a stable and transparent solution 1. Keep the syringe and mold at 50 °C Fully preheated at C, inhaled solution 1 into a preheated syringe, then injected it into a transparent mold at a rate of 4 cm / s and sealed it well, placed it at 45 °C, initiated by 200nm ultraviolet light, polymerized for 4 hours, and obtained Hydrogel 1; 10 g N-isopropylacrylamide, 1.4 mg N,N'-methylenebisacrylamide and 10 mg 2-hydroxy-4-(2-hydroxyethoxy)-2-methanol Add phenylpropiophenone to 100 g of deoxygenated deionized water, completely dissolve to obtain solution 2, put hydrogel 1 in solution 2, soak at 15 °C for 16 h, take it out, put it into a transparent mold and seal it , cover a layer of mask with a specific patt...
Embodiment 2
[0041] 1.5 g glyceryl lauryl itaconate, 7.3 mg sodium lauryl sulfate, 14.2 g acrylamide, 15.5 mg N,N'-methylenebisacrylamide, 22.2 mg 2-hydroxy-4- (2-Hydroxyethoxy)-2-methylpropiophenone was added to 100g of deoxygenated deionized water, and allowed to stand in a water bath at 60 °C for 6 h to obtain a stable and transparent solution 1, and the syringe and the transparent mold were placed in the Fully preheat at 60 °C, inhale solution 1 into a preheated syringe, inject it into a transparent mold at a rate of 5 cm / s and seal it well, place it at 55 °C, trigger with 365 nm ultraviolet light, Polymerized for 6 h to obtain hydrogel 1; 22.63 g N-isopropylacrylamide, 3.1 mg N,N'-methylenebisacrylamide and 22.5 mg 2-hydroxy-4-(2-hydroxyethoxy) -2-Methylpropiophenone was added to 100 g deoxygenated deionized water, and solution 2 was obtained after completely dissolving, and hydrogel 1 was placed in solution 2, soaked at 20 °C for 12 h, and then put into a transparent In the mold and...
Embodiment 3
[0043] 1.5 g glyceryl lauryl itaconate, 14.6 mg sodium dodecyl sulfate, 21 g acrylamide, 46 mg N,N'-methylenebisacrylamide, 33.3 mg 2-hydroxy-4-( 2-Hydroxyethoxy)-2-methylpropiophenone was added to 100 g of deoxygenated deionized water, and allowed to stand in a water bath at 55 °C for 5 h to obtain a stable and transparent solution 1. Fully preheat at 55 °C, inhale solution 1 into a preheated syringe, inject it into a transparent mold at a rate of 5 cm / s and seal it, place it at 50 °C, and trigger it with 400 nm ultraviolet light, Polymerize for 5 h to obtain hydrogel 1; 35 g N-isopropylacrylamide, 4.8 mg N,N'-methylenebisacrylamide and 34.8 mg 2-hydroxy-4-(2-hydroxyethoxy )-2-Methylpropiophenone was added to 100 g deoxygenated deionized water, and solution 2 was obtained after complete dissolution. Put hydrogel 1 in solution 2, soak at 15°C for 12 h, take it out and put it into a transparent In the mold and sealed, a layer of mask with specific pattern and information is co...
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