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Method and device for improving water quality of reclaimed water

A technology for reclaimed water and water quality, applied in water/sewage treatment, chemical instruments and methods, multi-stage water/sewage treatment, etc. Solve the problems such as the increase in the amount of chemical used to achieve the effect of prolonging the maintenance cycle and service life, reducing the degree of corrosion and scaling, and simple structure

Pending Publication Date: 2020-01-14
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The COD, conductivity, turbidity, iron ion, chloride ion and other water quality indicators of reclaimed water are higher than those of new water. After reclaimed water is reused as circulating water, the content of various impurities and soluble salts increases, the water quality deteriorates, and the sewage of the system The increase in the amount of water treatment chemicals and the increase in the use of water treatment chemicals will cause abnormal control indicators of circulating water and cause difficulties in the operation and management of circulating water
[0006] Second, increase the risk of corrosion and scaling in the circulating water system
After the reclaimed water reuses the circulating water, the corrosive and scaling ions in the system will increase, and the concentration will increase with the evaporation and concentration of the circulating water, which will increase the risk of corrosion and scaling in the system
In addition, the concentration of bacteria, inorganic salt ions and nutrients introduced by reclaimed water is gradually increasing. The suitable temperature, pH and sufficient dissolved oxygen of the circulating water system lead to the rapid growth and reproduction of microorganisms in the circulating water system, which is easy to cause system slime fouling, fouling

Method used

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  • Method and device for improving water quality of reclaimed water
  • Method and device for improving water quality of reclaimed water
  • Method and device for improving water quality of reclaimed water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0088] To improve the water quality of reclaimed water in a refining and chemical enterprise, the parameters of the reclaimed water are shown in Table 1.

[0089] In this embodiment, the reclaimed water of refining and chemical enterprises is treated as follows:

[0090] 1) Ozone oxidation treatment is carried out on the reclaimed water to be treated in refining and chemical enterprises to obtain oxidized reclaimed water;

[0091] Among them, the output of the ozone generator is 5g / h, and the ozone oxidation treatment time is 45min;

[0092] 2) Perform electrodialysis treatment on the oxidized reclaimed water to obtain desalted reclaimed water and salt-enriched reclaimed water;

[0093] Wherein, the working voltage of the electrodialysis treatment is 60V.

[0094] It is calculated that when reclaimed water is treated in this embodiment, the energy consumption per ton of water is 0.06KW·h.

[0095] The desalted reclaimed water was collected, and the COD, conductivity, salt r...

Embodiment 2

[0108] To improve the water quality of reclaimed water in a refining and chemical enterprise, the parameters of the reclaimed water are shown in Table 2.

[0109] In this embodiment, the reclaimed water of refining and chemical enterprises is treated as follows:

[0110] 1) Ozone oxidation treatment is carried out on the reclaimed water to be treated in refining and chemical enterprises to obtain oxidized reclaimed water;

[0111] Among them, the output of the ozone generator is 5g / h, and the ozone oxidation treatment time is 45min;

[0112] 2) Perform electrodialysis treatment on the oxidized reclaimed water to obtain desalted reclaimed water and salt-enriched reclaimed water;

[0113] Wherein, the working voltage of the electrodialysis treatment is 50V.

[0114] It is calculated that when reclaimed water is treated in this embodiment, the energy consumption per ton of water is 0.06KW·h.

[0115] The desalted reclaimed water was collected, and the COD, electrical conductiv...

Embodiment 3

[0122] To improve the water quality of reclaimed water in a refining and chemical enterprise, the parameters of the reclaimed water are shown in Table 3.

[0123] In this embodiment, the reclaimed water of refining and chemical enterprises is treated as follows:

[0124] 1) Ozone oxidation treatment is carried out on the reclaimed water to be treated in refining and chemical enterprises to obtain oxidized reclaimed water;

[0125] Among them, the output of the ozone generator is 5g / h, and the ozone oxidation treatment time is 45min;

[0126] 2) Perform electrodialysis treatment on the oxidized reclaimed water to obtain desalted reclaimed water and salt-enriched reclaimed water;

[0127] Wherein, the working voltage of the electrodialysis treatment is 60V.

[0128] It is calculated that when reclaimed water is treated in this embodiment, the energy consumption per ton of water is 0.06KW·h.

[0129] The desalted reclaimed water was collected, and the COD, conductivity, salt r...

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Abstract

The invention provides a method and device for improving the water quality of reclaimed water. The method includes the following steps: (1) the to-be-treated reclaimed water is subjected to ozone oxidation treatment to obtain oxidized reclaimed water; and (2) the oxidized reclaimed water is subjected to electrodialytic treatment to obtain desalted reclaimed water and salt-rich reclaimed water. Themethod and device for improving the water quality of the reclaimed water is used for reclaimed water treatment in refinery enterprises by combining ozone oxidation and electrodialytic desalting processes, the COD, conductivity, alkalinity, hardness, chloride ion concentration, sulfate ion concentration and the like of the reclaimed water in the refinery enterprises are reduced, the problems of corrosion and scaling in the process of reclaimed water recycling for circulating water are relieved, and the concentration ratio of the circulating water in the refinery enterprises is increased.

Description

technical field [0001] The invention relates to a water treatment process, in particular to a method and device for improving the quality of reclaimed water, belonging to the technical field of water treatment. Background technique [0002] Reclaimed water is considered as an important non-drinking water resource and is gradually applied to industrial fields. It is an important measure to alleviate the shortage of water resources in my country and improve the efficiency of water use in my country by reusing reclaimed water instead of fresh water in the circulating cooling system. Many enterprises in our country use reclaimed water as the supplementary water of the circulating cooling system, and have achieved good results, achieving a win-win situation of environmental and economic benefits. [0003] Among them, the oily sewage of refining and chemical enterprises mainly includes low-concentration production sewage discharged from newly-built refinery units, ethylene units ...

Claims

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Application Information

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IPC IPC(8): C02F9/06
CPCC02F1/78C02F1/4693
Inventor 王伟康强利宋宇辉孔朝辉刘宏伟朱翠杨海燕吕倩何丽丽
Owner PETROCHINA CO LTD
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