Short-cut denitrification coupled anaerobic ammonia oxidation composite particle as well as preparation method and application thereof

A technology of anammox and composite particles, which is applied in the field of short-range denitrification-coupled anammox composite particles and its preparation, can solve the problems of easy loss of activity of anammox bacteria, slow growth of anammox bacteria, pollution Poor mud settlement performance and other problems to achieve the effect of increasing the ability to resist adverse environments, improving biological efficiency, and reducing loss

Active Publication Date: 2020-07-17
GUANGDONG UNIV OF TECH
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  • Claims
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Problems solved by technology

The denitrification process can be adjusted through the influent water quality and operating parameters, and the accumulation of NO2--N can be stably realized as the electron acceptor of the anammox reaction, but the anaerobic Ammonia oxidizing bacteria grow slowly and have a long generation cycle. They need to survive in a high concentration of ammonia nitrogen environment, and their activity is easily affected by dissolved oxygen, temperature and pH. The N2 produced during the reaction process is easy to pollute Mud suspension, resulting in poor sludge settling performance, resulting in sludge loss
[0005] Therefore, it is necessary to solve the problems that the anammox bacteria in the anammox process are easy to lose and have low activity in a low-concentration ammonia-nitrogen environment

Method used

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  • Short-cut denitrification coupled anaerobic ammonia oxidation composite particle as well as preparation method and application thereof
  • Short-cut denitrification coupled anaerobic ammonia oxidation composite particle as well as preparation method and application thereof
  • Short-cut denitrification coupled anaerobic ammonia oxidation composite particle as well as preparation method and application thereof

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Embodiment 1

[0045] This embodiment provides a composite particle of short-range denitrification coupled with anammox, such as figure 1 As shown, it includes a core layer 11, a first shell layer 12 and a second shell layer 13 arranged in sequence from the inside to the outside; the core layer 11 is a zeolite, and the first shell layer 12 is a biofilm containing anammox bacteria. The second shell layer 13 is a hydrogel layer containing short-range denitrifying bacteria.

[0046] The preparation method of the composite particle is as follows:

[0047] S1. choose the relatively consistent zeolite of size, wash with clear water, place in the hydrochloric acid of 15% (mass), the sodium hydroxide of 5% (mass) and the sodium chloride of 1% (mass) respectively soak for 48 hours, soak Then rinse twice with deionized water for later use. Put the treated zeolite into an anammox reactor with a sludge concentration of 4000-6000mg / L, and cultivate it with water for 10-20 days under the conditions of 3...

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Abstract

The invention discloses a short-cut denitrification coupled anaerobic ammonia oxidation composite particle as well as a preparation method and application thereof. The composite particle comprises a core layer, a first shell layer and a second shell layer which are sequentially arranged from inside to outside, wherein the core layer is zeolite, the first shell layer is a biological membrane containing anaerobic ammonia oxidizing bacteria, and the second shell layer is a hydrogel layer containing short-cut denitrifying bacteria. According to the composite particles provided by the invention, zeolite is used as a carrier, and short-cut denitrifying bacteria and anaerobic ammonia oxidizing bacteria are co-immobilized and cultured, so that the loss of the anaerobic ammonia oxidizing bacteria in a wastewater treatment process is effectively reduced; the adsorption performance of zeolite on ammonia nitrogen in water is combined with the microbial action, the biological efficiency of short-cut denitrifying bacteria and anaerobic ammonia oxidizing bacteria is improved, nitrate in the wastewater is reduced into nitrite in combination with the short-cut denitrifying bacteria, and coordinatedoperation of short-cut denitrification reaction and anaerobic ammonia oxidizing reaction is realized. In addition, the preparation method of the composite particle is simple, and the preparation process is easy to control.

Description

technical field [0001] The invention relates to the technical field of sewage biological denitrification treatment, and more specifically relates to a composite particle of short-range denitrification coupled with anaerobic ammonium oxidation and its preparation method and application. Background technique [0002] At present, due to the accelerated process of industrialization and urbanization in our country, the problem of excessive nitrogen in water has aroused people's great attention. In aquatic ecosystems, the removal of total nitrogen mostly depends on the traditional nitrification-denitrification denitrification technology. The traditional denitrification technology requires aeration and the addition of additional organic matter to meet the needs of denitrification, resulting in high operating costs and energy consumption. It consumes a lot. [0003] The anaerobic ammonium oxidation process is currently known as a relatively cost-effective nitrogen removal method, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F101/16
CPCC02F3/34C02F3/282C02F1/281C02F2101/16Y02W10/10
Inventor 胡颖斌李宁王桢江进许燕滨潘汉平曹节
Owner GUANGDONG UNIV OF TECH
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