A kind of copper ion antibacterial fiber and antibacterial fabric

An antibacterial fiber and copper ion technology, applied in the field of fiber manufacturing, can solve the problem of high cost and achieve good mechanical properties

Active Publication Date: 2022-04-26
杭州宝雅丝绸有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of the invention has the advantages of simple operation, high efficiency, and long-lasting effect, but it also has obvious shortcomings. For example, in order to achieve a higher antibacterial rate, the amount of copper in the mesoporous zirconium phosphate is relatively large. 0.5~7.6%, so its cost is higher

Method used

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  • A kind of copper ion antibacterial fiber and antibacterial fabric
  • A kind of copper ion antibacterial fiber and antibacterial fabric
  • A kind of copper ion antibacterial fiber and antibacterial fabric

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A copper ion antibacterial fiber, said fiber comprises the following components in parts by weight: 100 parts of polylactic acid slices, 5 parts of copper-loaded phosphorus-containing nanoporous phosphorus-containing borosilicate ceramic powder, maleic anhydride modified polyvinyl alcohol ( 5 parts of maleic anhydride grafted (1.5 wt%), 1 part of silane-terminated polyethylene glycol, 1 part of triethylene glycol acrylate, and 0.01 part of initiator 1173.

[0044] The preparation method of copper-loaded phosphorus-containing nanoporous phosphorus-containing borosilicate ceramic powder is as follows:

[0045] (1) Preparation of precursor: Weigh raw materials according to the following mass ratio: phenyltrimethoxysilane: trimethylolphosphine oxide: diphenyldimethoxysilane: boric acid: hexamethyldisiloxane: water : Concentrated hydrochloric acid=100:5:10:10:5:15:3, stirred at room temperature for 1 hour, then refluxed for 3 hours, and finally removed water and oligomers fo...

Embodiment 2

[0054] A copper ion antibacterial fiber, said fiber comprises the following components in parts by weight: 100 parts of polylactic acid slices, 15 parts of copper-loaded phosphorus-containing nano-porous phosphorus-containing borosilicate ceramic powder, maleic anhydride modified polyvinyl alcohol ( Maleic anhydride grafting amount is 3.5wt%) 10 parts, 5 parts of silane-capped polyethylene glycol, 3 parts of diethylene glycol methacrylic acid acrylate, 0.5 part of initiator 9070 and heat stabilizer calcium stearate 3 parts share.

[0055] The preparation method of copper-loaded phosphorus-containing nanoporous phosphorus-containing borosilicate ceramic powder is as follows:

[0056] (1) Preparation of precursor: Weigh raw materials according to the following mass ratio: phenyltrimethoxysilane: trimethylolphosphine oxide: diphenyldimethoxysilane: boric acid: hexamethyldisiloxane: water : Concentrated hydrochloric acid = 100: 10: 30: 15: 10: 20: 5, stirred at room temperature f...

Embodiment 3

[0065] A copper ion antibacterial fiber, said fiber comprises the following components in parts by weight: 100 parts of polylactic acid slices, 10 parts of copper-loaded phosphorus-containing nanoporous phosphorus-containing borosilicate ceramic powder, maleic anhydride modified polyvinyl alcohol ( Maleic anhydride grafting amount is 2wt%) 5-10 parts, 2 parts of silane-capped polyethylene glycol, 2 parts of triethylene glycol dimethacrylate, 6590.03 parts of initiator and heat stabilizer stearic acid 2 parts lead.

[0066] The preparation method of copper-loaded phosphorus-containing nanoporous phosphorus-containing borosilicate ceramic powder is as follows:

[0067] (1) Preparation of precursor: Weigh raw materials according to the following mass ratio: phenyltrimethoxysilane: trimethylolphosphine oxide: diphenyldimethoxysilane: boric acid: hexamethyldisiloxane: water : Concentrated hydrochloric acid=100:8:20:12:8:18:4, stirred at room temperature for 2 hours, then refluxed ...

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Abstract

The present invention relates to the field of fiber manufacturing, in particular to a copper ion antibacterial fiber and an antibacterial fabric. The fiber includes the following components in parts by weight: 100 parts of polylactic acid slices, 5~ 15 parts, 5-10 parts of hydrophobically modified polyvinyl alcohol, 1-5 parts of silane-capped polyethylene glycol, 1-3 parts of cross-linking agent, 0.01-0.05 parts of initiator and 0-3 parts of functional additives; The amount of copper loaded in the copper-loaded nano borosilicate ceramic powder is 0.01-0.1 wt%. The present invention overcomes the defect that antibacterial polylactic acid fibers in the prior art need to add more antibacterial agents in order to achieve a higher antibacterial effect, and the present invention combines copper particles with nanoporous phosphorus-containing borosilicate having far-infrared emission capabilities The combination of ceramic powder makes it possible to achieve effective antibacterial effect under the premise of extremely low copper particle loading, and the copper ion antibacterial fiber prepared by the present invention has good mechanical properties and water washing resistance, so it can be effectively applied in the field of medical care.

Description

technical field [0001] The invention relates to the field of fiber manufacturing, in particular to a copper ion antibacterial fiber and an antibacterial fabric. Background technique [0002] Polylactic acid fiber is made from starch-containing agricultural products such as corn, wheat, and sugar beet. After fermentation to generate lactic acid, it is made by polycondensation and melt spinning. It can be decomposed into carbon dioxide and water by microorganisms in soil or seawater. When burned, it will not emit poisonous gas and cause pollution. It is a sustainable ecological fiber. The fabric has good handle and drapability, anti-ultraviolet radiation, low flammability and excellent processing performance. It is suitable for various fashion, casual wear, sporting goods and sanitary products, etc., and has broad application prospects. [0003] Existing polylactic acid fibers usually do not have antibacterial effect, and in order to make polylactic acid fiber have antibacter...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/92D01F1/10D03D15/50D03D15/47D03D15/225D03D15/283D04B1/16D04B21/00D02G3/04D02G3/44
CPCD01F6/92D01F1/10D01F1/103D03D15/00D04B1/16D04B21/00D02G3/045D02G3/449
Inventor 俞国年郑雪梅周旭亮徐国娣
Owner 杭州宝雅丝绸有限公司
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