A kind of high-efficiency self-compensating hydration heat regulator and preparation method and application thereof

A technology of self-compensation and heat of hydration, which is applied in the field of functional additives for building materials, can solve the problems that the cleavage of massive aggregates affects the strength of concrete, the location of cracks, the time is different, and cannot be fully released, so as to improve the mechanical properties, Ease of use, high efficiency, and the effect of preventing temperature stress

Active Publication Date: 2022-07-19
CHINA STATE CONSTR READY MIXED CONCRETE CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Patent CN106008771B discloses a cement hydration heat control material and its preparation method. A polymer compound with a small molecular sugar structure is obtained by polymerizing a small molecular sugar styrene monomer. Although glycogen molecules are introduced, each in the concrete structure The temperature of the location is different, and the location and time of the cracks are also different. The introduction of glycogen in a single deposit will reduce the hydration process of the entire system and affect the progress of the project.
[0005] Patent CN105271912A discloses a preparation method of a starch-based cement hydration heat control material. After mixing dextrin, starch, and dibasic acid anhydride, it is melted and extruded. The material is easy to agglomerate during the melting process, and it is lumpy when added to concrete, especially After being mixed with mixing water, it cannot be fully released to play a regulating role, and the cleavage of its massive aggregates will also affect the strength of concrete

Method used

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  • A kind of high-efficiency self-compensating hydration heat regulator and preparation method and application thereof
  • A kind of high-efficiency self-compensating hydration heat regulator and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] A high-efficiency self-compensating hydration heat regulator, its components and the mass fraction of each component are:

[0035] 85 parts of starch, 10 parts of phase change material, 3 parts of amylase;

[0036] The starch is a mixture of wheat starch, corn starch, potato starch and tapioca starch with a mass ratio of 1:1:1:1;

[0037] The phase change material is a paraffin type phase change material, the number of carbon atoms is 30-40, the melting point is 65-80°C, and it is in powder form;

[0038] Amylase is α-amylase and saccharification enzyme at 65℃, and the ratio of enzyme amount is 1:2~1:3;

[0039] The specific preparation steps are:

[0040] Weigh starch, phase change material and amylase in proportion;

[0041] Add a small amount of hydrogen peroxide, starch mixture, a small amount of sodium hydroxide diluent, a certain amount of water, and 10% borax solution into the reaction kettle in turn, stir for 30 minutes, and refrigerate the gelatinized starch...

Embodiment 2

[0045] A high-efficiency self-compensating hydration heat regulator, its components and the mass fraction of each component are:

[0046] 80 parts of starch, 12 parts of phase change material, 4 parts of amylase;

[0047] The starch is a mixture of wheat starch, corn starch, potato starch and tapioca starch with a mass ratio of 1:1:1:1;

[0048] The phase change material is a paraffin type phase change material, the number of carbon atoms is 30-40, the melting point is 65-80°C, and it is in powder form;

[0049] Amylase is α-amylase and saccharification enzyme at 65℃, and the ratio of enzyme amount is 1:2~1:3;

[0050] The specific preparation steps are:

[0051] Weigh starch, phase change material and amylase in proportion;

[0052] Add a small amount of hydrogen peroxide, starch mixture, a small amount of sodium hydroxide diluent, a certain amount of water, and 10% borax solution into the reaction kettle in turn, stir for 30 minutes, and refrigerate the gelatinized starch...

Embodiment 3

[0056] A high-efficiency self-compensating hydration heat regulator, its components and the mass fraction of each component are:

[0057]75 parts of starch, 15 parts of phase change material, 5 parts of amylase;

[0058] The starch is a mixture of wheat starch, corn starch, potato starch and tapioca starch with a mass ratio of 1:1:1:1;

[0059] The phase change material is a paraffin type phase change material, the number of carbon atoms is 30-40, the melting point is 65-80°C, and it is in powder form;

[0060] Amylase is α-amylase and saccharification enzyme at 65℃, and the ratio of enzyme amount is 1:2~1:3;

[0061] The specific preparation steps are:

[0062] Weigh starch, phase change material and amylase in proportion;

[0063] Add a small amount of hydrogen peroxide, starch mixture, a small amount of sodium hydroxide diluent, a certain amount of water, and 10% borax solution into the reaction kettle in turn, stir for 30 minutes, and refrigerate the gelatinized starch;...

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Abstract

The invention discloses a high-efficiency self-compensating hydration heat regulator, which, in parts by mass, comprises the following components: 70-85 parts of starch, 10-15 parts of phase change material, and 3-5 parts of amylase; a preparation method, the steps of which are As follows: S100: add hydrogen peroxide, starch, sodium hydroxide diluent, water, borax solution in sequence to the reactor, stir, and cold gelatinize starch; S200: mix the phase change material and amylase evenly, and add it to the paste The starch is mixed evenly; S300: the mixture obtained in step S200 is vacuum-cooled and dried to obtain a high-efficiency self-compensating hydration heat regulator. The application of the high-efficiency self-compensating hydration heat regulator in the regulation of hydrothermalization, the mixing amount thereof is 1% to 5% of the total amount of the externally mixed rubber material. It can respond quickly and play its regulating function in the position where the temperature is too high, and continuously control the hydration temperature, effectively prevent the generation of temperature stress, and improve the mechanical properties and durability of concrete.

Description

technical field [0001] The invention relates to the field of building material functional additives, in particular to an efficient self-compensating hydration heat regulator and a preparation method and application thereof. Background technique [0002] With the continuous advancement of infrastructure construction in my country, the demand for concrete strength and durability is also increasing. Concrete is composed of cementitious materials, aggregates, admixtures and water. The key to strength requirements is to reduce the water-binder ratio. The glue ratio will cause the cement hydration rate to speed up, generate a lot of heat in a short time, and the internal temperature of the concrete will rise sharply. Due to the poor thermal conductivity of concrete, the internal heat cannot be released, and the external heat dissipation is fast, which is prone to thermal stress cracks, destroying the integrity of the concrete structure, and seriously affecting the strength and dura...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/38
CPCC04B40/0039C04B24/38C04B24/14C04B24/36C04B22/062C04B22/0013
Inventor 余昆王军赵日煦郑涛高飞熊龙李兴邢菊香周博儒包明
Owner CHINA STATE CONSTR READY MIXED CONCRETE CO LTD
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