Technology for removing tetrabromobisphenol A in wastewater based on iron-carbon micro-electrolysis technology

A technology of iron-carbon micro-electrolysis and tetrabromobisphenol is applied in water pollutants, water/sewage treatment, water/sewage multi-stage treatment, etc. The problem of low packing density, etc., can achieve the effect of good filtration and adsorption effect, improved removal effect, and improved electrical conductivity.

Active Publication Date: 2021-06-18
中日友好环境保护中心 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The iron-carbon filler density of the current iron-carbon micro-electrolysis method is low, the contact area between the formed fill layer and the pollutants in the wastewater is small, and the removal efficiency of the pollutants is low, and the current fillers are basically flat fillers. The formed fill layer has a short removal path, which will also lead to low removal efficiency of the fill layer for pollutants, and the current iron-carbon electrolysis method is expensive and not suitable for widespread promotion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A process based on iron microelectronic solution removal of tetrabromobutphenol A in wastewater, specifically according to the following steps:

[0034] S1: Termacear filler preparation

[0035] The iron carbon filler used in this process mainly includes the following weight materials: 35 parts of iron, 15 graphite, 20 activated carbon, 5 parts of the phenolic adhesive, melting the iron filings into the vacuum smelting furnace into liquid iron, will The liquid iron after smelting is sprayed in the cooling chamber through the atomizing nozzle, and the pressure is arranged: the discharged liquid iron instantly cools, and forms a spherical powder between 100 μm, the surface of the prepared iron films passes through The laser punch is hit by a plurality of well grooves having a hole diameter of 10 μm, and the depth of the hole is 40 μm, and the graphite and activated carbon are placed in a pulverizer and pulverized a mixed powder having a particle diameter of 3 μm, and the mixe...

Embodiment 2

[0049] Unlike the first example 1

[0050] A process based on iron microelectronic solution removal of tetrabromobutphenol A in wastewater, specifically according to the following steps:

[0051] S1: Termacear filler preparation

[0052] The iron carbon filler used in this process mainly includes the following weight of the following weight material: 40 iron filings, 16 graphite, 7 activated carbon, 7 parts of the phenolic adhesive, melting iron filings into the vacuum smelting furnace into liquid iron, will After the liquid iron after smelt, the liquid iron is sprayed in the cooling chamber, and the pressure is arranged: the discharged liquid iron instantly cools, and forms the spherical powder between the particle size between 60 μm, and the surface of the prepared iron films passes The laser punch is hit by a pore groove having a pore size of 7 μm, and the depth of the hole is 20 μm, and the graphite and activated carbon are placed in a pulverizer and pulverized a mixed powder ...

Embodiment 3

[0066] It is different from the second embodiment.

[0067] A process of removing tetrachromobutphenol A in wastewater based on iron microelectronic solution techniques, characterized in that specifically, according to the following steps:

[0068] S1: Termacear filler preparation

[0069] The iron carbon fillers used in this process mainly include the following weight materials: 45 pieces of iron filings, 18 graphite, activated carbon, 8 phenolic adhesives, add iron filings to the vacuum smelting furnace to melt into liquid iron, will The liquid iron after smelting is sprayed in the cooling chamber, and the pressure is arranged: the discharge of the discharged liquid is instantly cooled, and the spherical powder of the particle size is 50 μm, and the surface of the prepared iron shin is passed The laser punch is hit by a pore groove having a hole diameter of 5 μm, and the hole groove depth is 20 μm, and the graphite and activated carbon are placed in a pulverizing machine and pul...

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PUM

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Abstract

The invention discloses a process for removing tetrabromobisphenol A in wastewater based on an iron-carbon micro-electrolysis technology, which is specifically carried out according to the following steps: preparing a spherical iron-carbon filler which mainly comprises the following raw materials in parts by weight: 35-45 parts of scrap iron, 15-18 parts of graphite, 20-25 parts of activated carbon and 5-8 parts of a phenolic adhesive, adding the scrap iron into a vacuum smelting furnace for smelting, spraying the smelted liquid iron out through an atomizing nozzle, conducting cooling to form spherical powder, punching hole grooves in the surface of the iron scrap spherical powder, smashing and mixing graphite and activated carbon, then adding the mixture, the iron scrap spherical powder and a phenolic adhesive into a centrifugal machine together, and preparing an iron-carbon filler; introducing the wastewater into a purification tank, and adjusting the pH value of the wastewater to 3-4; enabling the wastewater to pass through the filler in an electrolytic purification pipe; and adding sodium hydroxide into a purification cylinder to enable the pH value of the purified water to be 6-10, conducting stirring, standing and precipitating, and taking supernate of the purified water. The method is simple in process, low in cost and suitable for wide popularization.

Description

Technical field [0001] The present invention relates to the field of sewage treatment, and more particularly to a process of removing tetraromobutphenol A in wastewater based on ferrous microelectronic solution. Background technique [0002] Tetabromobisphenol A is a large amount of use and has a wide range of persistent organic pollutants in the environment. It has long-term residual property, bio-accumulating, half volatility, high toxicity and carcinogenic, teratogenic and migration, can be migrated in the atmosphere and deposited back to the earth, causing atmosphere, water, sediments and Environmental media and related ecosystem pollution in soil. The concentration of tetrabromide bisphenol A in the environment is generally low, stable in chemical properties, with high organisms, can cause serious damage to ecosystems and human health through the food chain. [0003] Typically, tetraromobisphenol A is low in contaminated water, and it is difficult to remove through direct ad...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/06C02F1/461C02F101/36
CPCC02F9/00C02F1/46176C02F1/001C02F1/58C02F1/66C02F2101/36C02F2303/14
Inventor 魏东洋白洁琼安坤寇蓉蓉叶晔王龙乐魏良良
Owner 中日友好环境保护中心
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