Nano-antibacterial coating material, preparation method and internal plant based on nano-gold clusters
A nano-gold cluster and antibacterial coating technology, which is applied in the field of medical materials, can solve problems such as adverse reactions and copper ion allergies, and achieve the effect of improving antibacterial performance, good antibacterial performance, and avoiding copper ion allergy
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Embodiment 1
[0034] The preparation method of nanometer antibacterial coating material based on gold nanoclusters comprises the following steps:
[0035] (1) Preparation of nano-gold cluster liquid:
[0036] According to the molar ratio of 1:2, take tetrachloroauric acid and p-mercaptobenzoic acid, mix them in ultrapure water, stir, and then add sodium hydroxide aqueous solution until the precipitate is dissolved again, and add 2 times the mole of tetrachloroauric acid. amount of sodium tetrahydroborate, stirring;
[0037] Hydrochloric acid was added to separate out all the nano-gold clusters, and after centrifugation, washed with ultrapure water, dried, dissolved in methanol, and used for later use.
[0038] (2) Preparation of nano antibacterial coating
[0039] Take the nano-gold cluster methanol solution, add vitamin C magnesium phosphate, ultrasonic treatment, add TiCl 4 and ZnCl 2 , ultrasonic treatment to obtain the nano-antibacterial coating material based on nano-gold clusters....
Embodiment 2
[0042] The preparation method of nanometer antibacterial coating material based on gold nanoclusters comprises the following steps:
[0043] (1) Preparation of nano-gold cluster liquid:
[0044] According to the molar ratio of 1:2, take tetrachloroauric acid and p-mercaptobenzoic acid, mix them in ultrapure water, stir, and then add sodium hydroxide aqueous solution until the precipitate is dissolved again, and add 2 times the mole of tetrachloroauric acid. amount of sodium tetrahydroborate, stirring;
[0045] Hydrochloric acid was added to separate out all the nano-gold clusters, and after centrifugation, washed with ultrapure water, dried, dissolved in methanol, and used for later use.
[0046] (2) Preparation of nano antibacterial coating
[0047] Take the methanol solution of gold nanoclusters, add sodium vitamin C phosphate, ultrasonically treat, and add TiCl 4 and ZnCl 2 , ultrasonic treatment to obtain the nano-antibacterial coating material based on nano-gold clust...
Embodiment 3
[0050] The preparation method of nanometer antibacterial coating material based on gold nanoclusters comprises the following steps:
[0051] (1) Preparation of nano-gold cluster liquid:
[0052] According to the molar ratio of 1:2, take tetrachloroauric acid and p-mercaptobenzoic acid, mix them in ultrapure water, stir, and then add sodium hydroxide aqueous solution until the precipitate is dissolved again, and add 2 times the mole of tetrachloroauric acid. amount of sodium tetrahydroborate, stirring;
[0053] Hydrochloric acid was added to separate out all the nano-gold clusters, and after centrifugation, washed with ultrapure water, dried, dissolved in methanol, and used for later use.
[0054] (2) Preparation of nano antibacterial coating
[0055] Take the nano-gold cluster methanol solution, add vitamin C magnesium phosphate, ultrasonic treatment, add TiCl 4 and ZnCl 2 , ultrasonic treatment to obtain the nano-antibacterial coating material based on nano-gold clusters....
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