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Transparent electric conductive base material, its mfg. method and coating liquid for forming transparent coating thereby and display device with said base material

A technology of transparent conductivity and transparent conductive layer, which is applied in conductive materials, conductive coatings, lighting devices dispersed in non-conductive inorganic materials, etc., can solve the problems of reduced picture quality and resolution, and improve UV resistance. Effect

Inactive Publication Date: 2002-02-06
SUMITOMO METAL MINING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of anti-glare treatment can also be achieved by setting fine bumps to increase the diffuse reflection of the surface. However, when using this method, the resolution is reduced and the picture quality is reduced. It cannot be said to be a good method.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0078] A colloidal dispersion of silver particles was prepared by the above-mentioned Carey-Lea method.

[0079] Specifically, to 9% silver nitrate aqueous solution 33g, after adding the mixed solution of 23% iron (II) sulfate aqueous solution 39g and 37.5% sodium citrate aqueous solution 48g, after filtering and washing the precipitate, add pure water to prepare silver Colloidal dispersion of microparticles (Ag: 0.15%).

[0080] In this silver particle colloidal dispersion liquid 60g, under stirring, add hydrazine hydrate (N 2 h 4 ·H 2 O) 1% aqueous solution 8.0g, potassium aurate [KAu(OH) 4 ]Aqueous solution (Au: 0.75%) 480g and 1% polymer dispersant aqueous solution 0.2g mixed solution, the colloidal dispersion liquid of the silver particle that is coated with precious metal is prepared.

[0081] The colloidal dispersion of silver particles coated with precious metals was desalted with an ion exchange resin (manufactured by Mitsubishi Chemical Corporation, trade name Di...

Embodiment 2

[0096] In addition to the coating solution for forming a transparent coating in Example 1, the inorganic binder (SiO 2 ) 100 parts (weight), the addition of n-decyltrimethoxysilane is 1.0 parts (weight), and the same operation as in Example 1 is made to obtain the bonding of silver particles and silicon oxide coated with noble metals of conductive particles. The transparent conductive layer composed of the agent matrix and the transparent coating layer composed of the silicate film mainly composed of silicon oxide containing long-chain alkyl groups constitute the glass plate to which the transparent two-layer film is attached, that is, the transparent conductive layer of embodiment 2. base material.

[0097] The above film properties of the transparent two-layer film formed on the glass substrate are shown in Table 1 below.

Embodiment 3

[0099] In addition to the coating solution for forming a transparent coating in Example 1, the inorganic binder (SiO 2 ) 100 parts (weight), add n-decyltrimethoxysilane to reach 5.0 parts (weight), and operate in the same way as in Example 1 to obtain a bonded silver particle coated with precious metal and silicon oxide as conductive particles. A transparent conductive layer composed of an agent matrix and a transparent coating layer composed of a silicate film containing long-chain alkyl silicon oxide as a main component constitute a glass substrate to which a transparent two-layer film is attached, that is, the transparent film of Example 3 is obtained. Conductive substrate.

[0100] The above film properties of the transparent two-layer film formed on the glass substrate are shown in Table 1 below.

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Abstract

A transparent conductive layered structure which has the functions of preventing electrostatic charging or shielding an electric field, and preventing reflection, the two-layered film of which has an excellent scratch strength, and with which a reduction in production cost is expected and a method of producing the same, and a transparent coat layer forming coating liquid used in the method of producing the same, and a display device to which the transparent conductive layered structure is applied, are provided. A transparent conductive layered structure of the present invention, comprises a transparent substrate and a transparent two-layered film being composed of a transparent conductive layer and a transparent coat layer being formed in succession on the transparent substrate, wherein the transparent conductive layer comprises, as its main components, conductive microparticles having a mean particle diameter of 1 to 100 nm and a binder matrix of silicon oxide, and wherein the transparent coat layer comprises, as its main component, a binder matrix of silicon oxide including one or more types of alkyl groups selected from long chain alkyl groups containing 7 to 30 carbon atoms.

Description

technical field [0001] The present invention relates to a transparent conductive base material having a transparent two-layer film formed of a transparent substrate and a transparent conductive layer and a transparent coating layer sequentially formed thereon, for example, it is used in a cathode ray tube (CRT), a plasma display screen (PDP ), fluorescent display tubes (VFD), liquid crystal displays (LCD) and other display devices, especially the front panels, etc., have the functions of antistatic or electric field shielding and anti-reflection, and the anti-scratch of the above-mentioned transparent two-layer film A transparent conductive substrate with excellent scratch strength and low production cost, a method for producing the same, a coating liquid for forming a transparent coating layer using the production method, and a display device to which the transparent conductive substrate is applied. Background technique [0002] In recent years, due to office automation (OA...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H05B33/28B32B7/02B32B17/06B32B27/18C03C17/34C03C17/36C09C1/00C09C1/62C09C3/06C09D5/24C09D7/12C09D183/00H01B1/20H01B1/22H01B5/00H01B5/14H01J29/88
CPCC03C2218/116B32B27/18C03C2217/479C03C2217/476C03C2217/76Y10T428/31663Y10T428/12007C03C2217/94C03C17/3411C03C2217/45C03C17/36Y10T428/252C03C2217/948C03C2217/78C03C2217/734Y10T428/25C03C2218/113H01J29/88
Inventor 东福淳司行延雅也
Owner SUMITOMO METAL MINING CO LTD
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