Prepn process of paraffin hydrofining catalyst

A technology for hydrorefining and catalyst, applied in the refining of petroleum wax, etc., can solve the problems of easy crushing, poor thermal stability, unable to meet product quality requirements, etc., and achieve the effect of improving the activity and improving the activity of the catalyst.

Inactive Publication Date: 2003-06-04
BC P INC CHINA NAT PETROLEUM CORP
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  • Summary
  • Abstract
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AI Technical Summary

Problems solved by technology

Judging from the current situation of domestic catalysts, the total amount of active metals is relatively high, the shape of catalysts is mostly spherical, and the mechanical strength is low (see Table 1 for details). The pressure drop is large and rises quickly, which becomes the bottleneck restricting the production capacity of the device to meet the standard
The current process of catalyst preparation is to neutralize the gel with aluminum salt solution and precipitant, separate the prepared wet gel through mother liquor, wash and filter, shape, dry and roast to make a carrier, and the carrier is carried out with the active metal solution. Co-impregnation, followed by drying and roasting to obtain the finished catalyst, the control of the pore structure is only controlled by neutralization and gelling, and the pore size distribution is not concentrated, resulting in low catalyst activity and poor thermal stability, which cannot reach the quality of product export Require

Method used

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  • Prepn process of paraffin hydrofining catalyst

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Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0021] specific implementation

[0022] (1) Determination of the load of active components

[0023] The activity of the hydrotreating catalyst is closely related to the content of its active components. Within a certain range, the higher the active component, the better the activity of the catalyst, but its manufacturing cost also increases. Therefore, we prepared several catalysts with different metal contents for evaluation, and the evaluation results are shown in Table 3. The results show that the metal content value is MoO 3 15.5%, NiO 4.5%.

[0024] Catalyst number

B-1

B-2

B-3

B-4

metal content

MoO 3 %

NiO%

13.08

3.55

14.12

4.36

15.27

4.52

18.64

6.71

Create wax shades

25

28

30

30

[0025] operating conditions

Alumina Pore Size Distribution

water / oxygen

Aluminum

acid / oxygen

Al...

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Abstract

The present invention relates to one kind of catalyst used in petroleum refining equipment and is especially the preparation process of one kind of paraffin hydrofining catalyst. The preparation process of the paraffin hydrofining catalyst includes modification with alumina, compounding of active component solution, soaking and forming. The catalyst prepared through the process has lower content of active component, low cost, high strength, optimized alumina pore distribution and high stability.

Description

Technical field: [0001] The present invention relates to a kind of catalyst used in petroleum refinery unit, specifically, it is the preparation method of paraffin hydrorefining catalyst. Background technique: [0002] my country has abundant paraffin resources, accounting for nearly 1 / 3 of the global paraffin production, ranking first in the world. my country's paraffin production was mainly based on the clay method and the sulfuric acid-clay method in the early days. Good, high yield, flexible operation and other advantages can be developed rapidly. Judging from the current situation of domestic catalysts, the total amount of active metals is relatively high, the shape of catalysts is mostly spherical, and the mechanical strength is low (see Table 1 for details). The large pressure drop and rapid rise have become the bottleneck restricting the production capacity of the device to reach the standard. At present, the process of catalyst preparation is to neutralize the alum...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G73/42
Inventor 冯振学霍东亮阎菊刘闯蹇瑞红
Owner BC P INC CHINA NAT PETROLEUM CORP
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