Lithographic printing plate precursor and lithographic printing method
一种平版印刷版、前体的技术,应用在平版印刷版前体领域,能够解决操作错误、印刷版不能识别等问题
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Embodiment 1
[0400]
[0401] A 0.3 mm-thick aluminum plate (mechanism material: JIS1050) was degreased at 50° C. for 30 seconds with a 10% by mass aqueous solution of sodium aluminate to remove roll oil on the surface of the plate. Then, by using three nylon brushes inserted with bundled bristles with a diameter of 0.3 mm and an aqueous suspension of pumice with a median diameter of 25 μm (specific gravity: 1.1 g / cm 3 ) to make the surface of the aluminum plate rough, and then wash it thoroughly with water. The plate was immersed in a 25% by mass sodium hydroxide aqueous solution at 45°C for 9 seconds, then washed with water, immersed in 20% by mass of nitric acid at 60°C for 20 seconds, and then washed with water. At this time, the amount of etching on the granular surface is about 3g / m 2 .
[0402] Then, the Al plates were subjected to continuous electrochemical surface roughening using AC at 60 Hz. The electrolytic solution used here is a 1% by mass nitric acid aqueous solution (co...
Embodiment 2
[0437] A coating solution (2) for a photosensitive-thermosensitive layer except having the following components was bar-coated and then dried in an oven at 100°C for 60 seconds to form 2 A lithographic printing plate precursor was obtained in the same manner as in Example 1 except for the dry coating amount of the photosensitive-thermosensitive layer.
[0438] Coating solutions for photo-thermo-sensitive layers (2):
[0439] Infrared absorber (1) 0.3g
[0440] Polymerization initiator (1) 0.9g
[0441] Binder polymer (1) shown below 2.5g
[0442] Polymerizable compound Isocyanuric acid EO-modified triacrylate, (NK Ester M-315, manufactured by Shin-Nakamura Chemical Co., Ltd.) 5.4 g
[0443] Triazine compound (1) 0.1g
[0444] Colorless crystal violet (manufactured by Tokyo Kasei Kogyo Co., Ltd.) 0.8 g
[0445] Fluorosurfactant (1) 0.1g
[0446] Methanol 4g
[0447] Methyl ethyl ketone 96g
[0448] Binder polymer (1):
[0449]
[0450] Weight average molecular weigh...
Embodiment 3
[0452] A coating solution (3) for a photosensitive-thermosensitive layer except having the following components was bar-coated and then dried in an oven at 80°C for 60 seconds to form 2 A lithographic printing plate precursor was obtained in the same manner as in Example 1 except for the dry coating amount of the photosensitive-thermosensitive layer.
[0453] Coating solution (3) for photo-thermosensitive layer:
[0454] Infrared absorber (2) shown below 0.3g
[0455] Polymerization initiator (1) 0.9g
[0456] Binder polymer (1) 2.5g
[0457] Polymerizable compound Pentaerythritol triacrylate (SR444, manufactured by Nippon Kayaku Co., Ltd.) 5.4 g
[0458] Microcapsules (2) (based on solid content) 2.5g
[0459] Fluorosurfactant (1) 0.1g
[0460] Methanol 10g
[0461] water 35g
[0462] Propylene Glycol Monomethyl Ether 50g
[0463] Infrared absorber (2):
[0464]
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