Method of forming trench isolation structure
A trench isolation and pre-drying technology, applied in electrical components, semiconductor/solid-state device manufacturing, circuits, etc., can solve problems such as changing the shape of grooves
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Embodiment 1
[0126] On the silicon substrate having the trench isolation grooves formed by the method described above, a trench isolation structure was formed by the following method.
[0127] (1) The polysilazane solution A was spin-coated on a silicon substrate under the coating conditions of a rotation speed of 1000 rpm and a rotation time of 30 seconds. When coating on a bare silicon substrate under the same conditions, the coating thickness is 600nm.
[0128] (2) Pre-baking the coated substrate by heating, 100°C, 150°C and 200°C in sequence, 2 minutes at each temperature.
[0129] (3) Place the pre-dried substrate in a curing furnace under a pure oxygen environment while maintaining the temperature at 200°C, wherein the pre-dried substrate is heated to 800°C in an oxygen environment with a water vapor concentration of 70%, and the temperature increase rate at 10°C / min, and reheating was carried out at this temperature for 30 minutes to cure the coating.
[0130] For a thin film form...
Embodiment 2
[0135] The steps of Example 1 were repeated, except that the polysilazane solution was changed to polysilazane solution B, the coating and curing of the polysilazane solution were divided into 3 times, and steps (1)-(3) were repeated 3 times.
Embodiment 3
[0137] The steps of Example 1 were repeated except that the polysilazane solution was changed to polysilazane solution B. After step (3), a 300 nm thick silicon dioxide film was formed by HDP-CVD.
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