Method for manufacturing low-cost three-dimensional-structure graphene-aluminum supercapacitor composite electrode material

A supercapacitor and three-dimensional structure technology, which is applied in the manufacture of hybrid/electric double layer capacitors, metal material coating technology, gaseous chemical plating, etc., can solve the problem of difficult to use graphene materials with high specific surface area and excellent electrical properties Problems such as the performance of olefin-based supercapacitors, low-density agglomeration and stacking of graphene materials can reduce the probability of electron annihilation, optimize the charge transport path, and improve the charge-discharge response rate.

Inactive Publication Date: 2014-09-24
HARBIN INST OF TECH
View PDF4 Cites 11 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims to solve the problem that most of the graphene materials used in existing graphene-based supercapacitors are graphene prepared by oxidation method, which has many structural defects and many oxygen-containing functional groups on the surface, which greatly deteriorates the performance of graphene-based supercapacitors, and due to The characteristics of graphene materials such as low density, easy agglomeration and stacking make supercapacitors have poor wettability with electrolyte during use, and the effective reaction area is low, making it difficult to exert the high specific surface area and excellent electrical properties of graphene materials. Preparation method of a low-cost three-dimensional structure graphene-aluminum supercapacitor composite electrode material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for manufacturing low-cost three-dimensional-structure graphene-aluminum supercapacitor composite electrode material
  • Method for manufacturing low-cost three-dimensional-structure graphene-aluminum supercapacitor composite electrode material

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0018] Specific embodiment one: the preparation method of a kind of low-cost three-dimensional structure graphene-aluminum supercapacitor composite electrode material described in this embodiment is specifically carried out according to the following steps:

[0019] 1. Place the base material in the plasma-enhanced chemical vapor deposition vacuum device, evacuate to a pressure below 5Pa, pass in argon gas, adjust the flow rate of the argon gas to 10sccm-40sccm, and adjust the plasma-enhanced chemical vapor deposition vacuum device The pressure is 100Pa~300Pa, and under the pressure of 100Pa~300Pa and argon atmosphere, the temperature is raised to 400℃~600℃ within 25min;

[0020] 2. Introduce methane gas, adjust the gas flow rate of methane to 5sccm~40sccm, adjust the gas flow rate of argon to 60sccm~95sccm, adjust the pressure in the plasma enhanced chemical vapor deposition vacuum device to 200Pa~700Pa, and then set the radio frequency power to 150W ~250W, the pressure is 20...

specific Embodiment approach 2

[0028] Embodiment 2: The difference between this embodiment and Embodiment 1 is that the matrix material described in step 1 is a three-dimensional structure aluminum matrix material. Others are the same as in the first embodiment.

specific Embodiment approach 3

[0029] Embodiment 3: This embodiment differs from Embodiment 1 or Embodiment 2 in that: the aluminum matrix material with a three-dimensional structure is foamed aluminum, porous aluminum or surface-corroded aluminum. Others are the same as in the first or second embodiment.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
Login to view more

Abstract

The invention discloses a method for manufacturing a low-cost three-dimensional-structure graphene-aluminum supercapacitor composite electrode material, and relates to a method for manufacturing a composite electrode material. The method solves the problems that due to the facts that most of graphene materials adopted by an existing graphene-based supercapacitor are graphene obtained through an oxidation method, the structural defects are many, many surface oxygen-containing functional groups exist, and the performance of the graphene-based supercapacitor is greatly worsened, in the use process of the supercapacitor, wettability between the supercapacitor and an electrolyte is poor, the effective reaction area is reduced, and the high specific surface area and the excellent electrical properties of the graphene materials are difficultly brought into play. The method comprises the steps that base materials are placed in a plasma enhanced chemical gas phase deposition vacuum device, argon enters the device, the temperature and the pressure are adjusted, the methane gas enters the device for deposition, and after deposition is finished, the three-dimensional-structure graphene-aluminum supercapacitor composite electrode material is obtained. The method is used for manufacturing the graphene-aluminum supercapacitor composite electrode material.

Description

technical field [0001] The invention relates to a preparation method of a composite electrode material. Background technique [0002] Supercapacitor is a new type of energy storage device, which has excellent characteristics such as high power density, long cycle life, fast charge and discharge rate, safety and environmental protection. Therefore, supercapacitors have broad application prospects in electric vehicles, power electronics industry, consumer electronics and other fields. However, traditional supercapacitors have problems such as low energy density and unstable performance, which have always plagued their practical applications in fields such as electric vehicles. Due to its unique two-dimensional nanostructure, graphene material has extremely high specific surface area, excellent electrical, mechanical and thermal properties, and has broad application prospects in many fields such as micro-nano electronics and composite materials. [0003] However, the current ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/86C23C16/513C23C16/26
CPCY02E60/13
Inventor 亓钧雷林景煌张夫王旭费维栋冯吉才
Owner HARBIN INST OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products