Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Microgels in cross-linkable, organic media

A microgel, medium technology, used in the field of molded bodies or coatings

Active Publication Date: 2006-11-01
ARLANXEO DEUT GMBH
View PDF15 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the presence of such emulsifiers or dispersants is disruptive in many applications

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Microgels in cross-linkable, organic media
  • Microgels in cross-linkable, organic media
  • Microgels in cross-linkable, organic media

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0161] Example 1: Hydroxyl-modified SBR gel in Desmophen 1150 (RFL 403A)

[0162] In the following examples, it is shown that using a homogenizer, applying a pressure of 900-1000 bar, and using a microgel based on hydroxyl-modified SBR, the microgel composition according to the present invention with a particle size of ≤220 nm can be prepared.

[0163] The composition of the microgel composition according to the present invention is shown in the following table:

[0164] 1.Desmophen 1150 79.7

[0165] 2.RFL 403A 20

[0166] 3.Tego Airex 980 0.3

[0167] Total 100

[0168] Desmophen 1150 is a branched polyol carrying ester and ether groups from Bayer AG for the preparation of viscoelastic coatings.

[0169] Tego Airex 980, an organically modified polysiloxane, is a degassing agent from Tego Chemie ServiceGmbH.

[0170] RFL 403A is a cross-linked, surface-modified SBR-based rubber gel from RheinChemie Rheinau GmbH.

[0171] RFL 403A is composed of 70% butadiene, 22wt% styrene, 5wt% ...

preparation Embodiment 1

[0173] Hydroxyl-modified SBR-based microgels are prepared by direct emulsion polymerization using the crosslinking monomer ethylene glycol dimethacrylate.

[0174] 350 g of the sodium salt of long-chain alkyl sulfonic acid (368.4 g of Mersolat K30 / 95 from Bayer AG) and 27 g of the sodium salt of methylene bridged naphthalenesulfonic acid (Baykanol PQ from Bayer AG) were dissolved in 2.03kg of water was put into a 5L autoclave. The autoclave was evacuated three times and filled with nitrogen. Thereafter, 872 g butadiene, 274 g styrene, 69 g ethylene glycol dimethacrylate (90%), 38.5 g hydroxyethyl methacrylate (96%) were added. While stirring, the reaction mixture was heated to 30°C. Then metered in by 25g water, 180mg ethylenediaminetetraacetic acid (Merck-Schuchardt), 150mg ferrous (II) sulfate 7H 2 O, 400mg Rongalit C (Merck-Schuchardt) and 500mg trisodium phosphate 12H 2 O consists of an aqueous solution. The reaction is started by adding an aqueous solution of 350 mg p-menthan...

Embodiment 2

[0182] Example 2: Hydroxyl-modified SBR gel (RFL 403A) in Desmophen RC-PUR KE 8306

[0183] The following examples show that in the homogenizer, by applying a pressure of 900-1000 bar, the use of hydroxyl-modified SBR-based microgels can prepare particles with a particle size of mainly 50-500nm and an average particle size of about 250nm. The composition according to the invention of particles or agglomerates of particles.

[0184] The composition of the microgel paste is shown in the table below:

[0185] 1.RC-PUR KE8306 93.3

[0186] 2.Byk-LP X6331 0.2

[0187] 3.RFL 403A 6.5

[0188] Total 100

[0189] RC-PUR KE 8306 is an activated polyol blend from RheinChemie Rheinau GmbH for preparing PUR by a cold casting method.

[0190] The crosslinking component used was RC-DUR 120, an aromatic polyisocyanate from RheinChemie Rheinau GmbH.

[0191] Byk-LP X 6331 is a degassing agent for the PU system from Byk-Chemie GmbH.

[0192] RFL 403A is a cross-linked, surface-modified SBR-based r...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
glass transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention relates to a composition containing at least one specific organic, cross-linkable medium and at least one microgel that is not cross-linked by energy-rich beams. The invention also relates to methods for producing one such composition, to uses thereof, to microgel-containing polymers produced from said compositions, and to moulded bodies or coatings produced from the same.

Description

Technical field [0001] The present invention relates to a composition comprising at least one specific organic cross-linkable medium and at least one microgel that is not cross-linked with high-energy radiation, its preparation method, the use of the composition, and the composition prepared therefrom. The polymer of the microgel, and the molded body or coating produced therefrom. Background technique [0002] It is known to use rubber gels, including modified rubber gels, mixed with various rubbers, for example to improve rolling resistance in the manufacture of motor vehicle tires (for example, see DE 42 20563, GB-PS 10 78 400, EP 405 216 and EP 854 171). In these cases, the rubber gel is always incorporated into the solid matrix. [0003] It is also known to introduce printing ink pigments in highly dispersed form into suitable liquid media, ultimately for the preparation of printing inks (see, for example, EP 0 953 615A2, EP 0 953 615A3). As a result, a particle size as fine ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08J3/24C08J3/075C08J3/22C08K7/16C08L21/00C09D7/80C09D121/00C10M119/06
CPCC08G2220/00C08J3/075C08L75/04
Inventor T·齐泽尔T·弗吕L·赫利格W·奥布雷希特
Owner ARLANXEO DEUT GMBH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com