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Method of metallizing a silicone rubber substrate

A technology of metallizing silicon and silicon rubber, which is used in the improvement of metal adhesion of insulating substrates, metal material coating process, circuit substrate materials, etc.

Inactive Publication Date: 2006-12-13
DOW CORNING CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, unlike conventional methods that use primers such as chrome that are too brittle and cause cracks in metal surface coatings, there is still a need for methods of improving metal-to-silicone rubber adhesion that reduce cracking

Method used

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Examples

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Embodiment Construction

[0009] According to the present invention, a method of metallizing a silicone rubber substrate comprises the steps of (i) depositing a primer layer of aluminum on the surface of the silicone rubber substrate, and (ii) depositing a ductile metal layer on the primer layer of aluminum, wherein The ductile metal is selected from gold, platinum, palladium, copper, silver, aluminum and indium.

[0010] In step (i) of the method of the invention, a primer layer of aluminum is deposited on the surface of the silicone rubber substrate. The silicone rubber substrate may comprise any silicone rubber known in the art, filled or unfilled. Furthermore, the silicone rubber substrate can have any desired shape. The term "silicone rubber" as used herein refers to a product prepared by curing (vulcanizing or crosslinking) an organopolysiloxane polymer. The mechanical and chemical properties of silicone rubber substrates depend on the type of polymer, the nature and amount of other components ...

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Abstract

A method of metallizing a silicone rubber substrate, the method comprising the steps of (i) depositing a primer layer of aluminum on a surface of a silicone rubber substrate, and (ii) depositing a layer of a ductile metal on the primer layer of aluminum, wherein the ductile metal is selected from gold, platinum, palladium, copper, silver, aluminum, and indium.

Description

technical field [0001] The present invention relates to methods of metallizing silicone rubber substrates, and more particularly, to methods of metallizing silicone rubber substrates using a primer layer of aluminum on the surface of the substrate. Background technique [0002] Ductile metals such as gold often exhibit poor adhesion to glass or resin substrates. One method of improving adhesion involves depositing a primer layer of metals, such as chromium, nickel, platinum, palladium, and titanium, to nanometer-scale thicknesses on the substrate prior to depositing gold. Although these metals can improve the adhesion of gold to hard materials with low thermal expansion, such as epoxy resins, they are often too brittle to be used on materials with high thermal expansion, such as silicone rubber. As a result, using these metals as a primer layer over silicone rubber often results in the formation of cracks within the gold layer. [0003] Another method of improving adhesion...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/02C23C14/20B05D7/16B29C39/00C23C14/18C23C14/58H05K1/03H05K3/38
CPCH05K2201/0133H05K2201/0162C23C14/025H05K3/388H05K1/032H05K1/0283C23C14/20C08L83/04C08J2383/04C08J7/06C08J7/043C08K3/08C08K2003/0812C08K2003/0831
Inventor 西田文人T·劳尔U·佩尔尼茨
Owner DOW CORNING CORP