Multilayer Ceramic Capacitor and Production Method of the Same

a multi-layer ceramic and production method technology, applied in the direction of fixed capacitors, domestic applications, electrical equipment, etc., can solve the problems of reducing difficult production of fine particles of barium titanate crystals, and affecting the production efficiency of fixed capacitors, so as to reduce the property as ferroelectric materials, reduce the insulating property of grain boundary phases, and improve the properties of multi-layer ceramic capacitors. , the effect of increasing the yield of mass production

a multi-layer ceramic and production method technology, applied in the direction of fixed capacitors, domestic applications, electrical equipment, etc., can solve the problems of reducing difficult production of fine particles of barium titanate crystals, and affecting the production efficiency of fixed capacitors, so as to reduce the property as ferroelectric materials, reduce the insulating property of grain boundary phases, and improve the properties of multi-layer ceramic capacitors. , the effect of increasing the yield of mass production

US20090059471A1Active Publication Date: 2009-03-05KYOCERA CORP

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  • Multilayer Ceramic Capacitor and Production Method of the Same
  • Multilayer Ceramic Capacitor and Production Method of the Same
  • Multilayer Ceramic Capacitor and Production Method of the Same

Examples

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Effect test

example 1

Production of Multilayer Ceramic Capacitor

[0084]A multilayer ceramic capacitor was produced as follows. Herein, BT powder and BCT powder with 1.003 A / B site ratio of BT powder and BCT powder were employed. The particle size of the BT and BCT powders employed was 0.2 to 0.4 μm. The BT powder and the BCT powder employed here were respectively coated with Mg, Y and Mn. The coating amounts were MgO=0.022 parts by mass, Y2O3=0.122 parts by mass and MnO=0.023 parts by mass to 100 parts by mass of the BT powder, and MgO=0.065 parts by mass, Y2O3=0.37 parts by mass and MnO=0.069 parts by mass to 100 parts by mass of the BCT powder.

[0085]The glass powder had a composition of SiO2=50, BaO=20, CaO=20 and Li2O=10 (% by mole) and a mean particle size of 0.5 μm, and the addition amount of the glass powder was 1.2 parts by mass to 100 parts by mass of the dielectric powders. In this case, the alumina content in the glass powder employed here was as shown in Table 1. The amount of added barium carb...

example 2

[0106]Multilayer ceramic capacitors (samples No. 8 to 12 in Table 2) were produced in the same manner as the above-mentioned Example 1, except that barium carbonate with the specific surface area shown in Table 2 was used. The results of ABT / ABCT measurement carried out in the same manner as Example I for the obtained multilayer ceramic capacitors were in a range of 0.8 to 1.2. The concentration gradation was 0.05% by atom / nm or higher.

[0107]Next, for these multilayer ceramic capacitors (samples No. 8 to 12 in Table 2), the electrostatic capacity, the relative permittivity, the temperature property of the relative permittivity, the dielectric breakdown voltage, X7R standard, highly accelerated life test (MTTF impedance method), the mean particle size (average value and D90) of the BT type crystal particles and BCT type crystal particles composing the dielectric layers, the evaluation of grain boundary phases (existence of Si—Ba—O compound in triple point grain boundaries 11b and ele...

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Abstract

The invention provides a multilayer ceramic capacitor comprising a capacitor body composed by alternately layering dielectric layers and inner electrode layers, and each of the above mentioned dielectric layers contains a plurality of crystal particles, and grain boundary phases comprising interfacial grain boundaries and triple point grain boundaries formed among a plurality of the crystal particles adjacent to one another, and Si—Ba—O compound being formed in 5% or more of the triple point grain boundaries in the entire triple point grain boundaries per unit surface area of the dielectric layer. Accordingly, the multilayer ceramic capacitor has high relative permittivity and is high the temperature property and highly accelerated life test property.

Description

TECHNICAL FIELD[0001]The invention relates to a multilayer ceramic capacitor and a production method of the capacitor, particularly to a multilayer ceramic capacitor comprising a dielectric layer formed by adding a glass component to a dielectric material and having a compact size and high capacity and high reliability, and a production method of the capacitor.BACKGROUND ART[0002]In recent years, along with wide spread of mobile appliances such as cell phones and high speed and high frequency of semiconductor devices which are main parts of personal computers, a multilayer ceramic capacitor to be disposed in such electronic appliances has been required to be smaller and have higher capacities. Therefore, a dielectric layer composing the multilayer ceramic capacitor has been made thinner and to have higher lamination.[0003]For example, with respect to a dielectric powder composing a dielectric ceramic, Patent Document No. 1 discloses that a barium titanate powder (BCT (Barium Calcium...

Claims

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Application Information

Patent Timeline
05 Mar 2009
Publication
US20090059471A1
IPC
H01G4/12; C04B35/64
CPC
C04B2235/663; Y10T29/435; C04B2235/762; C04B2235/765; C04B2235/784; C04B2235/785; C04B2235/79; C04B2235/80
Inventors
FUKUDA, DAISUKE; MATSUBARA, KIYOSHI