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Silane-modified biopolymeric, biooligomeric, oxidic or siliceous filler, process for its production and its use

a technology of biopolymer and silane, which is applied in the direction of silicon oxides, chemistry apparatus and processes, and silanemodified biopolymer, can solve the problems of poor dynamic rubber properties, poor storage stability, and poor stability of product properties, so as to improve the dynamic properties of rubber, improve the coverage of the surface, and improve the effect of dynamic rubber

Inactive Publication Date: 2007-04-24
EVONIK DEGUSSA GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0021]It is an object of the present invention to produce a silane-modified biopolymeric, biooligomeric, oxidic or siliceous filler which displays an improved coverage of the surface with the corresponding rubber-reactive silanes and which therefore has comparable dynamic properties in rubber to known silane-filler blends produced in situ and displays better dynamic properties in rubber than known silane-filler blends produced ex situ.

Problems solved by technology

The disadvantages of these blends, which do not undergo any thermal pretreatment, lie in their storage stability and hence in the stability of the product properties.
The known fillers modified ex situ with silane have the disadvantage that the dynamic rubber properties tend to be worse rather than the same as or better than those of fillers and silanes mixed together in situ.
In the case of fillers with a large specific surface area or a raised surface texture, impregnation is not homogenous but instead is mostly confined to a thin surface layer and is therefore unsatisfactory.
The water-insoluble, rubber-typical silanes can only be converted into hydrocarbon-based solvents, which are generally toxic and highly flammable.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0198]In Example 1 the reference compound (A) mixed in situ with 6.4 phr of the coupling reagent Si 69 is compared with compound (B) with the silane-modified silicic acid according to the invention. The formulations used for compounds (A) and (B) are set out in Table 2, and the mixing instructions used are shown in Table 3. The results of the rubber tests are set out in Table 5.

[0199]

TABLE 5Results for Example 1Compound(A)(B)ML (1 + 4)[ME]6367Dmax–Dmin[dNm]16.618.4t10%[min]1.81.3t90%[min]28.231.7Shore-A hardness[SH]6361Tensile strength[MPa]15.515.9Modulus at 100%[MPa]1.61.7Modulus at 300%[MPa]7.88.4RF 300% / 100%[ ]4.94.9Elongation at break[%]450440DIN abrasion[mm3]7782Ball rebound, 60° C.[%]5962E* (0° C.)[MPa]14.314.1tanδ (0° C.)[ ]0.4830.461E* (60° C.)[MPa]6.46.4tanδ (60° C.)[ ]0.1460.144

[0200]As can be seen from the data in Table 5, the viscosities ML (1+4) for compounds (A) and (B) are at a comparable level and the vulcanisation characteristics are also similar. The static and dyn...

example 2

[0201]Example 2 shows that the rubber properties obtained by using the commercial pre-silanised silicic acid VP Coupsil 8108 (D) decline in comparison to the in-situ reference compound (C). Compounds (C) and (D) are based on the formulations given in Table 2. In a change from the mixing instructions used in Example 1 and set out in Table 2, in this example the first mixing stage is mixed at a speed of 70 rpm and a flow temperature of 70° C. and the second mixing stage at an initial speed of 80 rpm and a flow temperature of 80° C. The results are shown in Table 6.

[0202]

TABLE 6Results for Example 2Compound(C)(D)ML (1 + 4)[ME]6082Dmax–Dmin[dNm]18.922.1t10%[min]1.61.1t90%[min]23.236.0Shore-A hardness[SH]6269Tensile strength[MPa]13.013.0Modulus at 100%[MPa]1.92.3Modulus at 300%[MPa]8.99.1RF 300% / 100%[ ]4.74.0Elongation at break[%]380380DIN abrasion[mm3]9188Ball rebound, 23° C.[%]3233E* (0° C.)[MPa]15.420.5Tanδ (0° C.)[ ]0.4860.502E* (60° C.)[MPa]6.57.7Tanδ (60° C.)[ ]0.1380.144

[0203]The ...

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Abstract

Silane-modified biopolymeric, biooligomeric, oxidic or siliceous filler obtainable by reacting at least one biopolymeric, biooligomeric, oxidic or siliceous filler in a compressed gas with at least one silane. The silane-modified biopolymeric, biooligomeric, oxidic or siliceous fillers are used in rubber compounds.

Description

[0001]This application is a Continuation of U.S. application Ser. No. 10 / 140,041, filed on May 8, 2002, now U.S. Pat. No. 6,893,495.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The present invention relates to a silane-modified biopolymeric, biooligomeric, oxidic or siliceous filler, a process for its production and its use.[0004]2. Description of the Background[0005]The treatment of oxidic or siliceous compounds with organosilicon compounds in order by means of this treatment to strengthen the bond between the inorganic filler and the organic polymer used in filler-reinforced elastomers, and hence to improve the properties of the fillers in the polymers, is known.[0006]It is known from DE 2141159, DE 2212239 and U.S. Pat. No. 3,978,103 that sulfur-containing organosilicon compounds such as bis(3-triethoxysilylpropyl) tetrasulfane or 3-mercaptopropyltriethoxysilane are used as silane bonding agent or reinforcing filler in oxidically filled rubber compounds, for ti...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C08K3/34C08K9/06C09C1/00C09C3/04C09C3/12C08J5/00C01B33/18C08K3/04C08L21/00C09C1/30C09C1/42
CPCC08K9/06C09C1/3081C09C1/42C09C3/12C08L21/00C01P2006/10C01P2006/12C01P2006/14C01P2006/16
Inventor KORTH, KARSTENLUGINSLAND, HANS-DETLEFHASSE, ANDREKIEFER, INGOHEIDLAS, JUERGEN
Owner EVONIK DEGUSSA GMBH
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