The invention discloses a preparation method and application of a carbon-doped
boron nitride catalyst for
acetylene hydrochlorination. The method comprises the following steps: 1) mixing: heating in an
oil bath, and dissolving a
boron source, a
nitrogen source and a
carbon source in a mixed
solvent of
ethanol and water; 2)
drying:
drying the solution obtained in the step 1) to obtain a precursor; and 3) calcining: calcining the precursor obtained in the step 2) in an
inert atmosphere to obtain the carbon-doped
boron nitride catalyst. The prepared catalyst has the characteristics of ultrahigh specific surface area, rich porous structure and defect sites, controllable
conductivity and the like, and can be applied to the process of efficiently preparing
vinyl chloride through
acetylene hydrochlorination. The preparation method is simple, the cost is low, the performance is excellent, the industrialization difficulty is small, the process
repeatability is good, a mercury catalyst in an existing
calcium carbide process is expected to be replaced, the problem of mercury emission
pollution is solved, and a new technical
route is provided for mercury replacement of the catalyst in the
acetylene hydrochlorination process.