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Photoresist composition, its coating method and method of forming photoresist pattern
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A technology of photoresist and coating method, applied in the field of photoresist composition, can solve the problems of difficult application of TFT substrate and the like
Inactive Publication Date: 2012-06-06
MERCK PATENT GMBH +1
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Summary
Abstract
Description
Claims
Application Information
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Problems solved by technology
Both vertical stripes and horizontal stripes can be reduced by increasing the film thickness of the photoresist, but it is difficult to apply it to the TFT substrate manufacturing process in recent years that strictly requires control of the amount of photoresist used.
Method used
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Embodiment
[0065] Hereinafter, Synthesis Examples, Examples, and Comparative Examples are given to describe the present invention in more detail, but the present invention is not limited by these descriptions.
Synthetic example 1
[0066] Synthesis Example 1 (Synthesis 1 of Surfactant)
[0067] Into a glass flask equipped with a stirring device, a condenser, a thermometer, and a dropping funnel, 133 parts by weight of methyl isobutyl ketone (MIBK) was charged as a polymerization solvent.
[0068] On the other hand, CH as the fluoroalkyl-containing monomer (m1) 2 =CHCOOCH 2 CH 2 C 8 f 17 (m1-1) 33 parts by weight, CH as polyoxypropylene chain-containing monomer (m2) 2 =CCH 3 COO(C 3 h 6 O) nH (the average of n is 5) (m2-1) 67 parts by weight, tert-butylperoxy-2-ethylhexanoate (Perbutyl O manufactured by NOF Corporation, hereinafter referred to as "P-O") as a polymerization initiator ”) 7 parts by weight and 100 parts by weight of MIBK were mixed in advance to form a uniform solution, which was put into a dropping funnel as a dripping liquid.
[0069] The dropping funnel filled with the dripping liquid was set on the above-mentioned glass flask, and the temperature was raised to 110° C. while inje...
Synthetic example 2~9
[0070] Synthesis Examples 2-9 (Synthesis 2-9 of Surfactant)
[0071] Copolymers P-2 to P-9 were synthesized under the same conditions as in Synthesis Example 1 except that the monomer composition and polymerization conditions in the dripping solution in Synthesis Example 1 were changed to the conditions shown in Table 1.
[0072] Table 1 shows not only the composition and polymerization conditions of the copolymer P, but also the weight average molecular weight of the obtained polymer.
[0073] In addition, m2'-1 described in Table 1 is the following monomer.
[0074] CH 2 =CCH 3COO(C 2 h 5 O) nH (the average of n is 8) (m2'-1)
[0075] Table 1
[0076] Synthesis example
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Abstract
The invention provides a discharge nozzle system coating method photoresist composition for manufacturing an LCD-TFT substrate that will not form streak spots, or the like, at coating. The discharge nozzle system coating method photoresist composition contains (A) an alkali-soluble resin; (B) a photosensitizing agent, and (C) a fluorochemical surfactant which is a copolymer (P) obtained by copolymerizing a monomer mixture (m), comprising a monomer (m1) containing a fluorinated alkyl group shown by general Expression (1): CH2=CR<1>COOCH2CH2C8F17(R<1> is a hydrogen atom or a methyl group) and a monomer (m2) containing a polyoxypropylene chain shown by general Expression (2): CH2=CR2COO(C3H6O)nH (R<2> is a hydrogen atom or a methyl group, and n is 4 to 7 as an average of the distribution). The mixing ratio (m1) / (m2) of the monomers (m1) and (m2) in the monomer mixture (m) is 25 / 75 to 46 / 60 (ratio by weight), and the weight-average molecular weight of the copolymer (P) is 3,000 to 10,000.
Description
technical field [0001] The present invention relates to a photoresist composition coated by a discharge nozzle coating method, in particular to a discharge nozzle coating method preferentially used in the manufacture of a flat panel display (FPD) represented by a liquid crystal display (LCD). A photoresist composition, a coating method of the photoresist composition, and a resist pattern forming method using the photoresist composition. Background technique [0002] The production of thin-film transistor (TFT) substrates for liquid crystal displays (LCDs) is considered from the viewpoint of increasing the screen size along with the development of television applications and improving productivity due to the increase in the number of chamfers from one mother glass substrate. Upsizing of mother glass substrates is progressing. Conventionally, in the manufacture of a TFT substrate, a photoresist is applied by spin coating or slot spin coating. Spin-coating or slit-spin-coatin...
Claims
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Application Information
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