Cationic polymer nanoparticles encapsulating an active ingredients, and the cosmetic composition containing the same
A cationic polymer and nanocapsule technology, applied in cosmetic preparations, nanotechnology for materials and surface science, nanotechnology, etc., can solve human safety problems, reduce the stability of oil-soluble active components, increase the oil content Problems such as the relative surface area of the soluble component capsules, etc., to achieve the effect of a simple method
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[0025] Hereinafter, each step of an example of the preparation method of the cationic polymer nanocapsules with surface potential of the present invention will be described in detail.
[0026] 1) The step of preparing a hydrophobic functional polymer with a cationic functional group capable of absorbing active components:
[0027] In the present invention, the preparation of the polymer having cationic functional groups is carried out using an emulsifier-free emulsion polymerization method.
[0028]In the present invention, in order to impart cationic properties to the polymer, it is preferable to use a radical polymerizable cationic monomer, or a low molecular weight polymer having a molecular weight of 400-800. Specific examples of such monomers and polymers may include 2-vinylpyridine, 3-vinylpyridine, 4-vinylpyridine, acrylamide, (meth)acrylamide, vinylpyrrolidone, vinyl-N-methyl Pyridine chloride, 3-methacryloyl-2-ethyl-tetraalkylammonium chloride (3-methacryloyl-2-ethyl...
Embodiment 1
[0051] A butyl methacrylate random copolymer was prepared in the following manner. Based on the weight of the polymer, 75% by weight of butyl methacrylate was mixed with 25% by weight of (methacryloyl)ethyl diethylamine. The mixture was added to 0.5% 2,2′-azobis(2-methylpropylamidine) dihydrochloride aqueous solution, and polymerized at 70° C. under a nitrogen atmosphere for 4 hours under stirring at 250 rpm, Thus, a polymer latex was obtained. The prepared polymer was precipitated with sodium chloride to obtain a powder. The powder was recrystallized from acetone / water to remove unreacted monomer and reprecipitated with sodium chloride to give a powder. The powder was filtered and washed with water, and this filtering and washing process was repeated several times. The resulting material was dried in a vacuum oven, whereby powdered capsules were obtained.
[0052] To prepare nanocapsules encapsulating Coenzyme Q-10, 2 g of the polymer having cationic functional groups pre...
Embodiment 2
[0054] Polymers and capsules were prepared according to the method of Example 1, except that methyl methacrylate was used to prepare a random copolymer of methyl methacrylate with cationic functional groups.
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