The invention relates to modified
ammonium polyphosphate as well as a preparation method and application thereof, belongs to the technical field of fire extinguishing products, and is used for solving at least one of the problems that the
flame-retardant efficiency of
ammonium polyphosphate prepared by the existing method is reduced, the cost is high, long-acting anti-
caking cannot be realized, the
solubility is poor and the like. The modified
ammonium polyphosphate is prepared by
coating ammonium polyphosphate with a macromolecular
silane coupling agent, and after APP is coated with the macromolecular
silane coupling agent, the
caking rate is reduced, and the dissolving capacity is not affected. The hydrophobic
chain segment in the macromolecular
silane coupling agent synthesized by the invention is longer than that of monomolecular silane, so that the infiltration of small water drops on the surface of APP can be reduced, and the macromolecular
silane coupling agent has a better
hydrophobic effect; and a longer hydrophobic
chain segment has an interference effect on the formation of a
crystal bridge, so that the strength of the formed
crystal bridge is reduced, and the
caking of the APP
powder is more easily damaged. The dissolving capacity is improved, the combination of the macromolecular
silane coupling agent and the APP
powder is only limited to the combination site of the macromolecular
silane coupling agent and the APP
powder, dispersion in the APP powder is more uniform, and the dissolving capacity is improved.