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Combined catalytic conversion method for biological oil and fat and mineral oil

A catalytic conversion method and bio-oil technology, which are applied in the field of combined catalytic conversion of bio-oil and mineral oil, can solve problems such as insufficient and effective use of straight-chain hydrocarbon groups, and achieve high bio-oil conversion capacity, improved flexibility, and high low-carbon olefins. The effect of yield

Active Publication Date: 2008-12-03
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new combination catalysis technology described for converting biomass into liquid fuel has several benefits compared to traditional methods like gasoline production. It uses special types of molecular sieve called beta zeolenes (BZ) that have certain modifications made from their crystal lattice. These BzS's help increase its effectiveness at producing lower carbons such as ethylene while also improving energy efficiency when used alone. Overall this results in improved yields of desired products.

Problems solved by technology

This patented describes methods that convert plant or animal fats (or greases) into liquid transportation substances called biofucls. These liquids have specific properties like being able to absorb water vapor when heated up at different temperatures depending on their chemical composition. Additionally, these liquors may also include various compounds found naturally within them.

Method used

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  • Combined catalytic conversion method for biological oil and fat and mineral oil
  • Combined catalytic conversion method for biological oil and fat and mineral oil
  • Combined catalytic conversion method for biological oil and fat and mineral oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0047] Examples 1 to 4 illustrate the effect of using the combined catalytic conversion method of bio-grease and mineral oil provided by the present invention.

[0048] The catalyst (containing 7% by weight of USY zeolite, 8% by weight of zeolite beta, 20% by weight of ZSM-5 zeolite, and the balance as a carrier, all based on the total weight of the catalyst) was aged at 800°C with 100% steam for 10 hours, Using a medium-scale pilot plant, the catalyst loading in the composite reactor was 60 kg.

Embodiment 1

[0049] In embodiment 1, 80% palm oil and 20% atmospheric residue only enter riser reactor 1;

Embodiment 2

[0050] In embodiment 2, 40% palm oil and 20% atmospheric residue enter the bottom of riser reactor 1, and 40% palm oil enters the middle and lower part of riser reactor 1;

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Abstract

A method for catalytically transforming bio-oil and mineral oil combination comprises the following steps: contacting bio-oil and mineral oil with catalyst containing modified beta-zeolite in a compound reactor to carry out catalytic cracking reaction, separating the reaction resultant with the spent catalyst, processing the spent catalyst by stripping and burning and adding into the reactor for recycling, introducing the separated resultant from the reactor, and distilling to obtain target product low-carbon alkenes, gasoline, diesel and heavy oil. By adopting the catalyst containing modified beta-zeolite and zeolite with MFT structure as the necessary active component, the method can achieve higher yield of low-carbon alkenes, particularly propylene, wherein the total yield of C2 to C4 alkenes based on carbon balance is larger than 40wt percent, and the yield of propylene is above 21wt percent.

Description

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Claims

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Application Information

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Owner CHINA PETROLEUM & CHEM CORP
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