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Modified honeycomb activated carbon with nitric oxide adsorption function and preparation method thereof

A honeycomb activated carbon, nitrogen oxide technology, applied in chemical instruments and methods, separation methods, other chemical processes, etc., can solve the problems of low cost and high conversion and adsorption rate of activated carbon NOx, and achieve improved adsorption efficiency, efficient adsorption, and adsorption. The effect of increased capacity

Inactive Publication Date: 2012-05-23
SHANGHAI NAT ENG RES CENT FORNANOTECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The obtained activated carbon has the characteristics of high NOx conversion adsorption rate and low cost

Method used

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  • Modified honeycomb activated carbon with nitric oxide adsorption function and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: The activated carbon with 200 holes / square inch was cut into a cylinder with a diameter of 16 mm and a height of 50 mm, and dried in an oven at 120° C. for 1 hour. Prepare 2.5ml of 5% copper nitrate solution. Take M n+ : CO(NH 2 ) 2 Weigh urea at a ratio of 1:2, and fully dissolve the urea in the copper nitrate solution.

[0027] The solution was dropped on the activated carbon and immersed for 1 hour, and then dried in an oven at 100°C for 1 hour.

[0028] The dried activated carbon is calcined at 300° C. for 2 hours under vacuum and nitrogen protection to obtain modified activated carbon.

Embodiment 2

[0029] Example 2: The activated carbon with 200 holes per square inch was cut into a cylinder with a diameter of 16 mm and a height of 50 mm, and dried in an oven at 120° C. for 1 hour. Prepare 2.5ml of 20% copper nitrate solution. Take M n+ : CO(NH 2 ) 2 Weigh urea at a ratio of 1:4, and fully dissolve the urea in the copper nitrate solution.

[0030] The solution was dropped on the activated carbon and immersed for 1 hour, and then dried in an oven at 100°C for 1 hour.

[0031] The dried activated carbon is calcined at 250° C. for 2 hours under vacuum and nitrogen protection to obtain modified activated carbon.

Embodiment 3

[0032] Example 3: The activated carbon with 200 holes / square inch was cut into a cylinder with a diameter of 16 mm and a height of 50 mm, and dried in an oven at 120° C. for 1 hour. Prepare 2.5 ml of a mixed solution of 10% copper nitrate and 10% cerium nitrate. Take M n+ : CO(NH 2 ) 2 Weigh urea at a ratio of 1:2, and fully dissolve the urea in the copper nitrate solution.

[0033] The solution was dropped on the activated carbon and immersed for 1 hour, and then dried in an oven at 100°C for 1 hour.

[0034] The dried activated carbon is calcined at 250° C. for 2 hours under vacuum and nitrogen protection to obtain modified activated carbon.

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Abstract

The invention relates to a modified honeycomb activated carbon with nitric oxide adsorption function and preparation method thereof. The activated carbon comprises the following components by weight percent: 87-99% of honeycomb activated carbon and 1-8% of copper oxide and 0-5% of other metallic oxide. Compared with the prior art, the invention adopts the combined technology of volumetric impregnation and metallic load to prepare activated carbon, and NOx gas adsorption efficiency and adsorption capacity are obviously improved. The adsorbing agent has high efficiency adsorption on SO2 and VOCS gases.

Description

Technical field [0001] The invention relates to a honeycomb activated carbon and a preparation method thereof, in particular to a modified honeycomb activated carbon with the function of adsorbing nitrogen oxides and a preparation method thereof. Background technique [0002] Among various air pollutants, NO X The pollution and its harm cannot be ignored. Most of NOx comes from fuel combustion, that is, automobile exhaust, industrial kiln emissions, etc. The main component of NOx is NO, which is slowly oxidized in the atmosphere to brown-red NO with a pungent odor 2 . NOx is the main pollutant that forms acid rain and acid fog. It can form photochemical smog with hydrocarbons and also participate in the destruction of the ozone layer. The harm of nitrogen oxides to the human body mainly invades the bronchioles and alveoli in the deep part of the respiratory tract, causing strong irritation and corrosion to lung tissues, causing pulmonary edema. High concentration of nitric oxi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/32B01D53/02
Inventor 张豪杰姚炜刘洋周洁眭艳辉金彩虹何丹农
Owner SHANGHAI NAT ENG RES CENT FORNANOTECH