Cathode active material, cathode and nonaqueous electrolyte battery
一种正极活性物质、正极的技术,应用在非水电解质蓄电池、活性物质电极、正电极等方向,能够解决很难生产具有平板型的电池、破裂或截断等问题,达到卷绕特性改进、气体产生抑制、改进循环特性的效果
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Embodiment 1
[0158] will have the average composition as Co 0.20 Ni 0.77 al 0.03 (OH) 2 and composite hydroxide particles with an average particle diameter (average particle diameter) of 12 μm (determined by laser light scattering method) and commercially available lithium hydroxide LiOH-H 2 O is Li / (Co+Ni+M)=0.98 (where M is selected from boron B, magnesium Mg, aluminum Al, silicon Si, phosphorus P, sulfur S, titanium Ti, chromium Cr, manganese Mn, iron Fe, copper One or more of the group consisting of Cu, zinc Zn, gallium Ga, germanium Ge, yttrium Y, zirconium Zr, molybdenum Mo, silver Ag, barium Ba, tungsten W, indium In, tin Sn, lead Pb, and antimony Sb Elements) are mixed in molar ratios.
[0159] Based on the total weight of the mixed powder, commercially available phosphorous acid (H 3 PO 3 ) was added in an amount of 0.5 wt%, and fully stirred and mixed. The resulting product was placed in an electric furnace and heated to 470° C. in an oxygen atmosphere (at a rate of 2° C. / ...
Embodiment 2
[0161] The positive electrode in Example 2 was obtained in the same manner as described in Example 1, except that 0.15 Ni 0.80 al 0.05 (OH) 2 composite hydroxide particles.
Embodiment 3
[0163] The positive electrode in Example 3 was obtained in the same manner as described in Example 1, except that 0.15 Ni 0.80 mn 0.05 (OH) 2 composite hydroxide particles.
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