Urea-formaldehyde adhesive for particleboards and preparation method
An adhesive and particle board technology, applied in the direction of adhesives, aldehyde/ketone condensation polymer adhesives, adhesive types, etc., can solve the problems of high consumption of melamine, high price and high cost, and achieve precise and easy-to-master endpoint control. Effect
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Embodiment 1
[0037] 1. Formula:
[0038] The molar ratio of formaldehyde to urea is F / U=1.20, 550 parts of formaldehyde (concentration 37%), 346 parts of urea (purity 98%), and 67 parts of melamine.
[0039] 2. Preparation process:
[0040] 1) Put 480 parts of formaldehyde aqueous solution into the reaction kettle, start the agitator, heat up and heat up, and stop heating when the temperature rises to 40°C. , adjust the pH value to 7.5-8.0 with 25-30% aqueous sodium hydroxide solution.
[0041] 2) Add 165 parts of the first batch of urea, stop heating when the temperature rises to 70°C, and then naturally raise the temperature to 90°C. Detect pH (guarantee pH = 6.5-7.0) add 15 parts after incubating for 10 minutes, and stir for 15 minutes.
[0042] 3) Use 25-30% formic acid aqueous solution to adjust the pH between 4.8-5.2, and the temperature is 83±2°C, let it undergo polycondensation reaction (drop the reactant into 40-45°C water, the white cloud is the first end point) .
[0043] 4...
Embodiment 2
[0057] 1. Formula:
[0058] The molar ratio of formaldehyde to urea is F / U=1.22, 550 parts of formaldehyde (concentration 37%), 340 parts of urea (purity 98%), and 62 parts of melamine.
[0059] 2. Preparation process:
[0060] 1) Put 480 parts of formaldehyde aqueous solution into the reaction kettle, start the agitator, start heating and heating, and stop heating when the temperature reaches 40°C. , adjust the pH value to 7.5-8.0 with 25-30% aqueous sodium hydroxide solution.
[0061] 2) Add 165 parts of the first batch of urea, stop heating when the temperature rises to 70°C, and then naturally raise the temperature to 90°C. After detecting the pH (guaranteed pH=6.5-7.0) and incubating for 10 minutes, add 13 parts of melamine and stir for 15 minutes.
[0062] 3) Use 25-30% formic acid aqueous solution to adjust the pH between 5.0-5.3, the temperature is 83±2°C, let it undergo polycondensation reaction (drop the reactant into 40-45°C water, the white cloud is the first en...
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